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v’. J’= 5. 0. The selection rules for vibration rotation transitions are ∆v = ±1 ∆J = ±1. v”. J”= 5. 0. Rotational Structure. J’= 5. v’ = 0. 0. R(3). R(2). R(1). R(0). J”= 5. v” = 0. 0. R Branch. Rotational Structure. J’= 5. v’ = 0. 0. P(4). R(3). P(3). P(2). R(2).
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v’ J’= 5 0 The selection rules for vibration rotation transitions are ∆v = ±1 ∆J = ±1 v” J”= 5 0
Rotational Structure J’= 5 v’ = 0 0 R(3) R(2) R(1) R(0) J”= 5 v” = 0 0 R Branch
Rotational Structure J’= 5 v’ = 0 0 P(4) R(3) P(3) P(2) R(2) R(1) P(1) R(0) J”= 5 v” = 0 0 R Branch P Branch
J V’ J V”
J + 1 J V’ J – 1 J V”
J + 1 J B’ J (J+ 1) V’ J – 1 J B”J (J+ 1) V”
B’ (J+ 1)(J+2) J + 1 J B’ J (J+ 1) V’ J – 1 J B”J (J+ 1) V”
B’ (J+ 1)(J+2) J + 1 J B’ J (J+ 1) V’ J – 1 B’ (J – 1) J J B”J (J+ 1) V”
B’ (J+ 1)(J+2) J + 1 J B’ J (J+ 1) V’ J – 1 B’ (J – 1) J J B”J (J+ 1) V”
B’ (J+ 1)(J+2) J + 1 J B’ J (J+ 1) V’ J – 1 B’ (J – 1) J R(J) J B”J (J+ 1) V”
B’ (J+ 1)(J+2) J + 1 J B’ J (J+ 1) V’ J – 1 B’ (J – 1) J R(J) P(J) J B”J (J+ 1) V”
B’ (J+ 1)(J+2) J + 1 J J – 1 B’ (J – 1) J R(J) P(J) J B”J (J+ 1)
B’ (J+ 1)(J+2) J + 1 B’ (J2 + 3J +2) J J – 1 B’ (J – 1) J R(J) P(J) J B”J (J+ 1) V”
B’ (J+ 1)(J+2) J + 1 B’ (J2 + 3J +2) J J – 1 B’ (J – 1) J B’ (J2 – J) R(J) P(J) J B”J (J+ 1) V”
B’ (J+ 1)(J+2) J + 1 B’ (J2 + 3J +2) J J – 1 B’ (J – 1) J B’ (J2 – J) R(J) P(J) J B”J (J+ 1) V” Harry Kroto 2004
B’ (J+ 1)(J+2) J + 1 B’ (J2 + 3J +2) J J – 1 B’ (J – 1) J B’ (J2 – J) B’ (4J + 2) R(J) P(J) J B”J (J+ 1) V”
B’ (J+ 1)(J+2) J + 1 B’ (J2 + 3J +2) J J – 1 B’ (J – 1) J B’ (J2 – J) B’ (4J + 2) = 4B’(J + ½) R(J) P(J) J B”J (J+ 1) V”
Rotational Structure J’= 5 v’ = 0 0 P(4) R(3) P(3) P(2) R(2) R(1) P(1) R(0) J”= 5 v” = 0 0 R Branch P Branch Harry Kroto 2004
Rotational Structure J’= 5 v’ = 0 0 P(4) R(3) P(3) R(2) P(2) R(1) P(1) R(0) J”= 5 v” = 0 Central section of the CN 0-0 Band 0 R Branch P Branch Harry Kroto 2004
Rotational Structure J’= 5 v’ = 0 0 P(4) R(3) P(3) R(2) P(2) R(1) P(1) R(0) J”= 5 v” = 0 Central section of the CN 0-0 Band 0 R Branch P Branch Harry Kroto 2004
Rotational Structure J’= 5 v’ = 0 0 P(4) R(3) P(3) P(2) R(2) R(1) P(1) R(0) J”= 5 v” = 0 Central section of the CN 0-0 Band 0 R Branch P Branch Harry Kroto 2004
Rotational Structure J’= 5 v’ = 0 0 P(4) R(3) P(3) R(2) P(2) R(1) P(1) R(0) J”= 5 v” = 0 0 R Branch P Branch Harry Kroto 2004