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What Happens to Fish as it Freezes?

What Happens to Fish as it Freezes?. Nature of Raw Material. Fish/Shellfish Composition Protein 15-25% Fat 1-15% Minerals 1-2% Water 65-80%. Water in Fish. Free – In Muscle Transport – Dissolved Minerals Bound –Attached to Proteins. Freezing. Change State of Water

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What Happens to Fish as it Freezes?

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  1. What Happens to Fish as it Freezes?

  2. Nature of Raw Material • Fish/Shellfish Composition • Protein 15-25% • Fat 1-15% • Minerals 1-2% • Water 65-80%

  3. Water in Fish • Free – In Muscle • Transport – Dissolved Minerals • Bound –Attached to Proteins

  4. Freezing • Change State of Water • Liquid to Solid • Proteins aren’t changed • Fats aren’t changed • Minerals aren’t changed

  5. Freezing - Two Stages To Consider • Freezing Process • Cold Storage

  6. Freezing Process • What Occurs -Three Stages • First - Chilling/Removing Heat to the Transition Temperature

  7. Freezing Process • Second - Phase Change - Liquid to Solid - Over a Temperature Range – Fairly Complex • Third – Final Temperature Drop to Surroundings

  8. Freezing Curve

  9. Phase Change Happenings • As Temp Decreases Through “Critical” Zone • Pure Water Freezes in Crystals Starting Around 28F

  10. Phase Change Happenings • Salt/Solute Concentration Increases • Amount of Unfrozen Water Left

  11. Unfrozen Water

  12. Ice Crystals • Small Crystals - Fast Freezing • Large Crystals - Slow Freezing • Through the Phase Transition Zone

  13. Ice Crystal Size

  14. Freezing Time • Freezing Time - What is Fast? • Hours Vs. Days • Inches Per Hour

  15. Final Core Temp • Final Temperatures - What is Best? • -20F • -40F

  16. Other Things Happening During Freezing • Increased Enzyme Activity in Transition Zone • Glassy State Conditions

  17. Glassy State • Occurs Around 5 to 10 F • In Pockets – Hi Concentration of Salts/Enzymes • Ice Crystals Dissolve

  18. Glassy State • Ice Recrystallizes in Larger Chunks • Quality Changes • Avoid this Region

  19. Other Things Happening During Freezing • Moisture Loss in Freezing • Freezing in Rigor • Visual Quality Concerns

  20. Moisture Loss in Freezing • Depending on System, Can Lose Water From Surface • Sometimes Up to 1% or 2%

  21. Freezing in Rigor • Stiffening of the salmon muscle shortly after death • May last several hours to days depending on temperature

  22. Freezing in Rigor • Don't process/handle fish in rigor • Gaping, Drip Loss and Toughness

  23. Cold Storage • Severe Conditions • Dry Air • Temperature Fluctuations

  24. Cold Storage • Glassy State Deterioration • Freezer Burn • Protection

  25. Quality Changes • Moisture Migration and Recrystallization • Hydrolytic Enzyme Activity • Protein Denaturation

  26. Moisture Migration and Recrystallization • Freezer Burn • Temperature Fluctuations – Limit Shelf Life

  27. Quality Changes • Fat Oxidation • Microbial Changes

  28. Minimizing Quality Losses • Cryoprotectants - Glazing • Antioxidants

  29. Glazing • Options for Glaze • Salt • Sugar • Antioxidants

  30. Glazing • Glaze Water Temperature • How Much Glaze? • Cold Storage Effects

  31. Minimizing Quality Losses • Packaging • Bleeding

  32. Packaging • Critical Aspect of Shelf Life • As Much Protection As You Can Afford • Plastics/Boxes/Vac Pack

  33. Shelf Life • Time of Acceptable Quality • Limiting Factor is Often Fat Oxidation • Also Texture Changes

  34. Shelf Life • Depends on • Water Content • Fat Content • Packaging • Storage Temperature

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