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Biopotential electrodes

Biopotential electrodes. A complex interface. Summer School Timisoara 2002 R. Hinz. the interface problem . To sense a signal a current I must flow !. But no electron e - is passing the interface!. metal cation. leaving into the electrolyte. No current.

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Biopotential electrodes

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  1. Biopotential electrodes A complex interface Summer School Timisoara 2002R. Hinz

  2. the interface problem To sense a signala currentImust flow ! But no electron e- ispassing the interface!

  3. metal cation leaving into the electrolyte No current One atom M out of the metal is oxidized to form one cation M+and giving off one free electron e-to the metal.

  4. metal cation joining the metal No current One cation M+out of the electrolyte becomes one neutral atom M taking off one free electron from the metal.

  5. metal: Li Al Fe Pb H Ag/AgCl Cu Ag Pt Au Vh / Volt -3,0negativ 00,223positiv1,68 half-cell voltage No current

  6. electrode double layer No current

  7. concentration (change in double layer) ohmic (voltage drop) current influence • withcurrent flowing the half-cell voltage changes • this voltage change is calledoverpotential orpolarization: Vp = Vr + Vc + Va activation, depends on direction of reaction

  8. polarizable electrode • “perfectly” polarizable electrode:- only displacement current, electrode behave like a capacitor • example: noble metals like platinum Pt

  9. nonpolarizable electrode • “perfectly” nonpolarizable electrode:- current passes freely across interface,- no overpotential • examples: - silver/silver chloride (Ag/AgCl),- mercury/mercurous chloride (Hg/Hg2Cl2) (calomel)

  10. chemical reactions silver / silver chloride

  11. electrical behaviour equivalent circuit

  12. equivalent circuit electrode-electrolyte

  13. again el. behaviour the skin: an additional interface!

  14. total equivalent circuit simplified

  15. results • high impedance ZE:... • changing half-cell voltage Vh*:...

  16. high impedance • interference with main power-lines (!!) • potential devider with Rinput • frequency dependant. c

  17. changing half-cell voltage • influenced by local concentration • saturation of amplifier • motion artefacts by changing the the gel-skin potential (Vep). simulation:

  18. body-surface electrode half-cell voltage drift simulated

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