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Materials Science and Nanosciences

PhoSciNet CM0802. Prof. Muriel Hissler WG Leader: Régis Réau WG Vice-Leader: Ian Manners WG1 Chair PhoSciNet Final Conference, Regensburg, 18-20 March 2013. Materials Science and Nanosciences. PhoSciNet. Régis Réau (WG leader) Ian Manners (WG vice-leader) . 1.

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Materials Science and Nanosciences

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  1. PhoSciNet CM0802 Prof. Muriel Hissler WG Leader: Régis Réau WG Vice-Leader: Ian Manners WG1 Chair PhoSciNet Final Conference, Regensburg, 18-20 March 2013 Materials Science and Nanosciences

  2. PhoSciNet RégisRéau (WG leader) Ian Manners (WG vice-leader) 1 Anne-Marie Caminade Koop Lammerstma Sasha Ott KolioTroev Eva-Marie Hey-Hawkins Rudolph Pietschnig Manfred Scheer Reiner Streubel Ulrich Zenneck 1 1 5 2 1 WG1 Group Leaders 2012

  3. Monomers for P-polymers • Nanosized Molecules • Functional materials • Dendrimers PhoSciNet Overlapwithother WGs. • Group 13/15 macromolecules and ceramics Reiner Streubel, Ian Manners,KolioTroev WG2 (catalysis) WG3 (biosciences) WG4 (new P compounds) • Spherical Nanosized Molecules by supramolecular synthesis Anne-Marie Caminade, Manfred Scheer • p-Conjugated materials • New building blocks WG 5 • Mixed P/metal oligomers Theory • OLEDs, WOLEDs R. Pietschnig, R. Réau, S. Ott, U. Zenneck, K. Lammertsma, E. Hey-Hawkins

  4. PhoSciNet Short TermScientific Missions (STSMs) involving WG1 members 2009 : 2 student‘sexchanges Group involved : Prof. Edwards (WG2,4; UK) - Prof. Manners (WG1,2; UK) - Prof. Scheer (WG1,4; DE) 2010 : 7 Student‘sexchanges Group involved : Prof. Hey Hawkins (WG1,2,4, DE) - Prof. Kostas (WG2, GR) – Prof. Lammertsma (WG1,2,4,5, NL) - Prof. Nyulaszi (WG5, HU) - Prof. Ott (WG1, SWE) – Prof. Peruzzini (WG2,3,4, IT) - Prof Pietschnig (WG1, AUT) - Prof. Réau (WG1,5, FR) – Prof. Russell (WG4, UK) - Prof. Scheer (WG1,4; DE) - Prof. Streubel (WG1,4) –- 2011: 11 Student‘sexchanges Group involved : Prof. Bourissou (WG2,4, FR) - Prof. Caminade (WG1,2,3) - Prof. Gilheany (WG2,3,5) - Prof. Hey Hawkins (WG1,2,4, DE) - Prof. Karasik (WG2, RU)- Prof. Kilian (WG4, UK) – Prof. Manners (WG1,2; UK) – Prof. Ott (WG1, SWE) - Prof Pietschnig (WG1, AUT) – Prof. Réau (WG1,5, FR) - Prof. Scheer (WG1,4; DE) - Prof. Streubel (WG1,4, DE) – Prof. Wright (WG4, UK) • 2012 : 5 Student‘sexchanges • Group involved : Prof. Espinosa (WG5; ESP) - Prof. Hey Hawkins (WG1,2,4, DE) – • Prof. Lammertsma (WG1,2,4,5, NL) - Prof. Ott (WG1, SWE) - Prof. Réau (WG1,5, FR) – • Prof. Scheer (WG1,4; DE) - Prof. Streubel (WG1,4, DE)- Prof. Woollins (WG3,4, UK) • -

  5. PhoSciNet Pertinent journal publications by WG1 members: 90 in total 40 PhoSciNetacknowledged 11 PhoSciNet collaborations Books • ANR-DFG Grant: DENDSWITCH • Caminade/Hey-Hawkins WG1 Outputs

  6. PhoSciNet WG1 Highlights: Monomers for P-polymers Ott’s group (SWE) Reactivity way beyond the classical phospha-Wittig-Horner reaction Talk 3 : A. I. Arkhypchuk : « Mechanism of the phospha-Wittig-HornerReaction: isPhosphorus more than a « carbon-copy »?

  7. PhoSciNet WG1 Highlights: Monomers for P-polymers Ott’s group (SWE) 3-2Phosphorus in Oligoacetylene Frameworks Geng, Ottet al., Chem. Eur. J.2011, 12153

  8. (X = Cl, Br) 1,1’ Ferrocenylene bridging phosphaalkene units PhoSciNet Pietschnig’s group (AUT- DE) 31P-NMR: „outer" Fe: 0.514 mm/sec "inner" Fe: 0.505 mm/sec q(Fe)(6-311G*// B3LYP): outer: +0.9646 inner: +0.9855 CV: two processes(DE1/2 = 270 mV), 2:1 ratio A. Orthaber, R. H. Herber, R. Pietschnig, J. Organomet. Chem. 2012, 719, 36. Talk 4 : D. Kargin: « Synthesis of [2]- and [3]- Ferrocenophanes containing trivalent phosphorus center” »

  9. PhoSciNet Spirooxaphosphiranecomplexes Streubel’s group (DE) Li-Cl phosphinidenoid complexes Chemcomm 2012, 48, 5986; Organometallics2011and Dalton Trans. 2013, submitted

  10. PhoSciNet Oxaphosphiranechemistry Streubel’s group (DE) Talk 2 : J. M. Villalba Franco: « Complexes with Novel N, P, C-heterocyclic Cage ligands derived from an azaphosphiridine complex »

  11. PhoSciNet WG1 Highlights: Monomers for P-polymers Troev’s group (Bul) Reactivity of Poly(alkylene H-phosphonate)s Macromolecules, 2012, 45 (14) 5698-5703

  12. PhoSciNet WG1 Highlights: Monomers for P-polymers Hey Hawkins’s group (DE) Strained rings for P-based polymers Phosphorus chemistry + 1,2-dicarba-closo-dodecaborane New 1,2-diphosphetanes ligands Precursors for phosphorus-based polymers • Angew. Chem. Int. Ed. 2011, 50, 4701-4703.

  13. WG1 Highlights: Nanosized Molecules PhoSciNet Scheer’s group (DE) Synthetic concept for generation of nano-sized molecules Ball-stick presentation of the novel nano-capsule [Cp*Fe(5-P5)]2@[{Cp*Fe(5-P5)}9{CuCl}10]. Series of 80-vertex (left and middle) and 90-vertex balls with Fullerene-like topology. • Angew. Chem. Int. Ed., 2011, 50, 11516-11519,Chem. Eur. J.2012,18, 1168-1179.

  14. PhoSciNet WG1 Highlights: Nanosized Molecules Scheer’s group (DE) Phosphanylborane PH2BH2NMe3 an excellent ethylene-like monomer Dehydrocoupling leading to P-P coupledoligomers Phosphanylborane catenae Angew. Chem. Int. Ed. 2013, 52, accepted. http://dx.doi.org/10.1002/anie.201209703

  15. WG1 Highlights: Nanosized Molecules PhoSciNet Caminade’s group (FR) Probing single molecule interactions by AFM single molecule interactions E. Jauvert, E. Dague, M. Séverac, L. Ressier, A.M. Caminade, J.P. Majoral, E. Trévisiol, Probing single molecule interactions using bio-functionalized dendritips, Sensors & Actuators: B. Chemical, 2012, 168, 436-441

  16. Molecular recognition of organic vapors by phosphorus dendrimers PhoSciNet Caminade’s group (FR) Quartz Crystal Microbalance sensor are coatedwith dendrimers G1, G2, G3, G4, or G9 (CHO terminal groups), thenvapors of variousguests (essentiallyorganicsolvents) are added. soluble 1: water 6: acetone 7: CH2Cl2 14: 1,4-dioxane 16: pyridine 19: n-pentane 21: CCl4 30: n-nonane Response of QCM sensor coated with dendrimers to methanol (a) and benzene (b). G4 G1 (a) (b) G1 ln DF for G4 G3 G2 G4 G3 G4 G9 DF / Hz DF / Hz not soluble G2 G9 ln DF for G1 Good correlationbetween the efficiency of absorption of the vaporwith the solubility of the dendrimer in the correspondingsolvent t / s t / s Coll. V. Gorbatchuk (Russia) J. Colloid Interface Sci. 2011 , 360, 204

  17. PhoSciNet WG1 Highlights: p-Conjugated materials Hissler - Réau’s group (FR) PolyaromaticHydrocarbon Helicoidal structure Planar structure • Strong modification of the physicalproperties by changing the substituant on the P-atom • Strongemissionproperties (Φ = 80-70%) • Emitters for OLEDs • Coordination chemistry for heliceneorganization: original helicates • High chiropticalproperties Hissler, Réau et al., J. Am. Chem. Soc. 2012, 134 (15), 6524-6527 • Crassous, Lescop, Réauet al., • Angew.Chem. Int. Ed. 2013, DOI: 10.1002/anie.201207251.

  18. WG1 Highlights: p-Conjugated materials PhoSciNet Phosphorus p-conjugated materials for lightning applications Hissler - Réau’s group (FR) + Blue emitter: DPVBi 2 - 4 % Orange emitter: P-dopant Dual emission from blue and orange emitters = white light !!! or (0.34, 0.34) Stable and reproducible White OLED for lightning Hissler, Réau et al., Angew. Chem. Int. Ed. Engl., 2012, 51, 214-217, Adv. Funct. Mater., 2012, 22, 567-576 Talk 1 : W. Delaunay : « New p-conjugated system used as functionalmaterial »

  19. Muriel Hissler WG1 Institute of "Sciences Chimiques de Rennes" University of Rennes1- CNRS France COST Action CM0802 www.phoscinet.org 19

  20. PhoSciNet H-terminated P-chains Pietschnig’s group (AUT- DE) 4 asymmetric centers  24 = 16 isomers possible restraint  23 = 8 isomers (4 diastereomers) Moser, C.; Belaj, F.; Pietschnig, R. Chem. Eur. J.2009, 15, 12589.

  21. PhoSciNet Spirooxaphosphiranecomplexes Streubel’s group (DE) Organometallics2011and Dalton Trans. 2013, submitted

  22. PhoSciNet Rearrangementofoxaphosphiranecomplexes Streubel’s group (DE) L. Abdrakhmanova, A. Espinosa, G. Schnakenburg, R. Streubel, 2013, submitted

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