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National Training Solutions W.H.M.I.S.

National Training Solutions W.H.M.I.S. Q: WHAT IS W.H.M.I.S.? WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM Q: WHAT ARE THE OBJECTIVES OF WHMIS? Q: WHY WAS WHMIS DEVELOPED? Q: WHO DEVELOPED WHMIS?. National Training Solutions W.H.M.I.S.

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National Training Solutions W.H.M.I.S.

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  1. National Training SolutionsW.H.M.I.S. • Q: WHAT IS W.H.M.I.S.? • WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM • Q: WHAT ARE THE OBJECTIVES OF WHMIS? • Q: WHY WAS WHMIS DEVELOPED? • Q: WHO DEVELOPED WHMIS? P.Duern 2004

  2. National Training SolutionsW.H.M.I.S. ANS: TO ENSURE THE EMPLOYEE HAS A BASIC UNDERSTANDING OF THE WHMIS REGULATIONS • TO INSTRUCT EMPLOYEES SO THEY UNDERSTAND: • INFORMATION LABELS • INFORMATION ON M. S. D. S. • INFORMATION ON ALTERNATIVE CLEANERS • INFORMATION ON HOW HAZARDOUS MATERIALS CAN ENTER YOUR BODY AND THE DAMAGE THAT CAN BE DONE P.Duern 2004

  3. National Training SolutionsW.H.M.I.S. • WHMIS = THE RIGHT TO KNOW • TO REDUCE ACCIDENTS/ INJURIES IN THE WORKPLACE & PROVIDE INFORMATION ABOUT THE HAZARDOUS MATERIALS YOU WORK WITH. • 3 WAYS INFORMATION IS PROVIDED: • LABELS • M.S.D.S • WORKER EDUCATION P.Duern 2004

  4. National Training SolutionsW.H.M.I.S. • Q: WHY WAS WHMIS DEVELOPED? • INFORMATION WAS INCOMPLETE, INCONSISTENT OR NOT AVAILABLE • EMPLOYEES/ EMPLOYERS NOT AWARE OF HAZARDS • TO PROVIDE ALL CANADIANS A UNIFORM AND APPROPRIATE QUANTITY OF INFO ABOUT HAZARDOUS MATERIALS P.Duern 2004

  5. National Training SolutionsW.H.M.I.S. • CHANGE CAME FROM KNOWLEDGE THAT SAFETY PAYS • CHANGE CAME FROM EMPLOYEES LESS WILLING TO TOLERATE POOR PRACTICES • CHANGE CAME FROM KNOWLEDGE OF DANGER TO WORKERS/ COMMUNITIES/ ENVIRONMENT P.Duern 2004

  6. National Training SolutionsW.H.M.I.S. • LABOUR, INDUSTRY AND GOVERNMENT DEVELOPED WHMIS AS AN AMENDMENT TO O.H.& S.A • LEVELS OF TRAINING: • GENERAL TRG FOR LABELS & MSDS • SPECIFIC ON THE JOB HAZARDOUS MATERIALS & THE HANDLING, STORAGE, USE AND EMERGENCIES- J.H.& S.C. P.Duern 2004

  7. National Training SolutionsW.H.M.I.S. • WHMIS AT WORK APPLIES EQUALLY AT HOME! • Q: WHAT IS THE MOST DANGEROUS SUBSTANCE AROUND YOUR HOUSE? • ANSWER: ALMOST ANYTHING YOU USE WITHOUT KNOWLEDGE OF ITS PROPERTIES………….. P.Duern 2004

  8. National Training SolutionsW.H.M.I.S. • DANGEROUS SUBSTANCES: • CARPETS/ FURNITURE- IN EVENT OF A FIRE • GLASS CLEANER- • VARSOL • MIXED CHEMICALS- TOILET BOWL CLEANER AND BLEACH………… P.Duern 2004

  9. National Training SolutionsW.H.M.I.S. • DANGEROUS SUBSTANCES- • GLUES, PAINT & VARNISH REMOVER • WHITE OUT • FANTASTIC • GASOLINE & PROPANE • PESTICIDES • WD40 P.Duern 2004

  10. National Training SolutionsW.H.M.I.S. W.H.M.I.S. VIDEO P.Duern 2004

  11. National Training SolutionsW.H.M.I.S. • EMPLOYEE RESPONSIBILITIES: • PARTICIPATE IN PROGRAM • USE THE INFORMATION • PROTECT THEMSELVES & THEIR COWORKERS • ASK QUESTIONS WHERE THEY DON’T UNDERSTAND P.Duern 2004

  12. National Training SolutionsW.H.M.I.S. • HAZARDOUS CLASSES AND SYMBOLS: • A CONTROLLED SUBSTANCE IS ANY PRODUCT, MATERIAL OR SUBSTANCE THAT IS INCLUDED IN ANY OF THE 6 CLASSES: P.Duern 2004

  13. National Training SolutionsW.H.M.I.S. • 6 CLASSES: • CLASS A COMPRESSED GAS P.Duern 2004

  14. National Training SolutionsW.H.M.I.S. • CLASS B: COMBUSTIBLE & FLAMMABLE: P.Duern 2004

  15. National Training SolutionsW.H.M.I.S. • CLASS C: OXIDIZING MATERIALS P.Duern 2004

  16. National Training SolutionsW.H.M.I.S. • CLASS D DIV 1: POISONOUS/ INFECTIOUS P.Duern 2004

  17. National Training SolutionsW.H.M.I.S. • CLASS D DIV. 2: INFECTIOUS P.Duern 2004

  18. National Training SolutionsW.H.M.I.S. • CLASS D DIV.3: BIOHAZARDOUS P.Duern 2004

  19. National Training SolutionsW.H.M.I.S. • CLASS E: CORROSIVE MATERIALS P.Duern 2004

  20. National Training SolutionsW.H.M.I.S. • CLASS F: DANGEROUSLY REACTIVE MATERIAL P.Duern 2004

  21. National Training SolutionsW.H.M.I.S • EXEMPTIONS: • EXPLOSIVES- EXPLOSIVES ACT • COSMETICS, DRUGS, DEVICES OR FOOD RE: FOOD AND DRUG ACT • HAZARDOUS WASTE BUT EMPLOYER MUST SECURE SAFE STORAGE AND HANDLING THROUGH I.D. & EDUCATION • CONSUMER PRODUCTS- MATERIALS PACKAGED AS A CONSUMER PRODUCT IN QUANTITIES NORMALLY PURCHASED BY THE PUBLIC P.Duern 2004

  22. National Training SolutionsW.H.M.I.S. • EXEMPTIONS: • PESTICIDES UNDER THE PEST CONTROL ACT • WOOD OR WOOD PRODUCTS • TOBACCO/ TOBACCO PRODUCTS • MANUFACTURED ARTICLES WHICH CONSUME CONTROLLED SUBSTANCES BUT DO NOT RELEASE A CONTROLLED PRODUCT WHEN FINISHED P.Duern 2004

  23. National Training SolutionsW.H.M.I.S. • HAZARD RECOGNITION- ALL CONTROLLED PRODUCTS MUST BE IDENTIFIED IN 4 WAYS: • SUPPLIER LABELS • WORKPLACE LABELS • PLACARDS • WORKPLACE IDENTIFIERS P.Duern 2004

  24. National Training SolutionsW.H.M.I.S. • LABELLING: • ANY MARK, SIGN, DEVICE ,STAMP, SEAL, STICKER, TICKET, TAG OR WRAPPER • 2 TYPES OF LABELS: • SUPPLIER LABELS AND WORKPLACE LABELS P.Duern 2004

  25. National Training SolutionsW.H.M.I.S. • W.H.M.I.S. SUPPLIER LABELS: • BOTH OFFICIAL LANGUAGES • 100ML OR GREATER REQUIRES: • PRODUCT IDENTIFIER • SUPPLIER IDENTIFIER • MSDS STATEMENT • HAZARD SYMBOL • RISK PHASES • PRECAUTIONARY MEASURES • FIRST AID MEASURES P.Duern 2004

  26. National Training Solutions P.Duern 2004

  27. National Training SolutionsW.H.M.I.S. • MATERIALS WITH < 100ML. REQUIRES THESE 4 SECTIONS: • PRODUCT IDENTIFIER • RISK PHRASES • 1ST AID MEASURES • PRECAUTIONARY MEASURES P.Duern 2004

  28. National Training SolutionsW.H.M.I.S. • WORKPLACE LABEL: • AVAILABLE FROM SUPERVISOR AND IS REQUIRED WHERE: • 1. CONTROLLED PRODUCT IS TRANSFERRED FROM A BULK TO A SMALLER CONTAINER • 2. A CONTROLLED PRODUCT IS MADE AND USED ON SITE…. P.Duern 2004

  29. National Training SolutionsW.H.M.I.S. • WORKPLACE LABELS: • 3. WHMIS SUPPLIER LABEL IS DAMAGED. IT MUST BE REPLACED BEFORE PRODUCT CAN BE USED • 4. BULK STORAGE CONTAINERS. IN THE EVENT THAT A SUPPLIER HASN’T SENT A SUPPLIER LABEL • 5. PRODUCTS HELD IN QUARANTINE REQUIRE A WP LABEL BEFORE USE P.Duern 2004

  30. National Training SolutionsW.H.M.I.S. • REQUIRED INFO ON WP LABELS: • PRODUCT IDENTIFIER-THE CHEMICAL, COMMON, GENERIC OR TRADE NAMES • SAFE HANDLING PROCEDURES • MSDS STATEMENT………… P.Duern 2004

  31. VARSOLUSE IN WELL VENTILATED ROOMRUBBER GLOVES MUST BE WORNWEAR SAFETY GOGGLESKEEP AWAY FROM SPARKS/ FLAMECAN CAUSE ORGAN DAMAGECAN IRRITATE EYES AND SKINFOR MORE INFORMATION SEEMATERIAL SAFETY DATA SHEET P.Duern 2004

  32. National Training SolutionsW.H.M.I.S. • PLACARDS: • AN IDENTIFICATION SIGN WHERE A SUPPLIER OR WP LABEL CAN’T BE USED • CONTAIN- • NAME OF PRODUCT • HAZARD INFO • REF. TO M.S.D.S. P.Duern 2004

  33. National Training SolutionsW.H.M.I.S. • PLACARDS: • LOOSE PRODUCTS NOT IN SHIPPING CONTAINERS • CONTROLLED PRODUCTS NOT YET SUPPLIER LABELLED • FOR CANADA • FOR SALE OUTSIDE CANADA • PRODUCTS IN QUARANTINE • FUGITIVE EMISSIONS/ HAZARDOUS WASTES…….. P.Duern 2004

  34. DANGER ASBESTOSCANCER AND LUNG DISEASE HAZARDDO NOT CREATE DUSTDO NOT DISTURB PIPE INSULATIONAUTHORIZED PERSONNEL ONLYRESPIRATORS AND PROTECTIVE CLOTHING ARE REQUIRED IN THIS AREASEE MATERIAL SAFETY DATA SHEET P.Duern 2004

  35. National Training SolutionsW.H.M.I.S. • Q: IF YOU RECEIVE A CONTROLLED PRODUCT WITHOUT A SUPPLIER LABEL, CAN YOU USE IT? • NO • REPORT INCIDENT TO SUPERVISOR • HOLD, QUARANTINE & REQUEST LABEL P.Duern 2004

  36. National Training SolutionsW.H.M.I.S • Q: WHEN ARE WHMIS LABELS NOT REQUIRED? • 1. WHEN A CONTROLLED PRODUCT IS BEING USED BY ONE PERSON IMMEDIATELY (EG. EPOXY RESIN & HARDENER) • 2. FUGITIVE EMISSIONS SUCH AS EXHAUST • 3. WHEN IT IS NOT A WHMIS CONTROLLED PRODUCT P.Duern 2004

  37. National Training SolutionsW.H.M.I.S. • WORKPLACE IDENTIFIERS: • LABELLING IS NOT PRACTICAL • METHOD OF BANDING, MARKING, NUMBERING • MUST BE STANDARDIZED AND CLEARLY UNDERSTOOD • EG. COLOURED TAPE & NAME OR NUMBER ON PROCESS PIPING P.Duern 2004

  38. National Training SolutionsW.H.M.I.S. • APPLICATIONS: • PROCESS PIPING, REACTION VESSELS TANKERS, CONVEYOR SYSTEMS • IN WORKPLACE CONTAINER USED BY ONE PERSON DURING THAT SHIFT • CONTROLLED PRODUCTS IN LAB • IN-HOUSE SAMPLES FOR ANALYSIS • TRANSFER OF CONTROLLED SUBSTANCES FROM QUARANTINE • HAZARDOUS WASTES P.Duern 2004

  39. National Training SolutionsW.H.M.I.S. • MATERIAL SAFETY DATA SHEETS: • EXTENSIVE INFORMATION • ACCESSIBLE AT ALL TIMES • KEPT CURRENT (3 YEAR EXPIRY) • SAFE USE, STORAGE, HANDLING, PPE, EMERGENCY MEASURES P.Duern 2004

  40. National Training SolutionsW.H.M.I.S. • EACH M.S.D.S. MUST PROVIDE: • 1. PRODUCT INFORMATION • 2. HAZARDOUS INGREDIENTS • 3. PHYSICAL PROPERTIES DATA • 4. FIRE & EXPLOSION DATA • 5. REACTIVITY DATA……………. P.Duern 2004

  41. National Training SolutionsW.H.M.I.S. • M.S.D.S. INFO……… • 6. HEALTH HAZARD INFORMATION • 7. PREVENTIVE MEASURES • 8. FIRST AID MEASURES • 9. PREPARATION INFORMATION P.Duern 2004

  42. Section 1 - Chemical Product and Company Identification Material Safety Data Sheet Acetone ACC# 00140 MSDS Name: Acetone Catalog Numbers: S70090, S70091-1, A11-1, A11-20, A11-200, A11-4, A11S-4, A16F-1GAL, A16P-4, A16S-20, A16S-4, A16S20001, A16S4LC, A18-1, A18-20, A18-200, A18-4, A18-500, A18200001, A18200LC, A1820LC, A1820LOT003, A184LC, A184LOT001, A18CU1300, A18J500, A18P-4, A18P4, A18RB115, A18RB19, A18RB200, A18RB50, A18RS115, A18RS200, A18RS28, A18RS50, A18S-4, A18SK-4, A18SK4LC, A18SS-115, A18SS-200, A18SS-30, A18SS-50, A19-1, A19-4, A20-1, A40-4, A404LOT007, A404LOT008, A404LOT009, A928-4, A929-1, A929-4, A9294LC, A9294LOT001, A9294LOT012, A9294LOT014, A9294LOT017, A9294LOT018, A9294LOT019, A9294LOT021, A9294LOT022, A9294LOT024, A929J4, A929RS-115, A929RS-19, A929RS-200, A929RS-28, A929RS-50, A929SS-115, A929SS-200, A929SS-28, A929SS-50, A930-4, A946-4, A946FB200, A946RB115, A946RB19, A946RB200, A946RB50, A949-1, A949-4, A9494LOT004, A949CU50, A949J4, A949LC, A949RS115, A949RS19, A949RS200, A949RS28, A949RS50, A949SK-1, A949SK-4, A949SS-11, A949SS-115, A949SS-20, A949SS-200, A949SS-30, A949SS-50, BP24011, BP240320, BP24034, BP2403500, BP2404, BPA18-4, BPA946RB-115, BPA946RB-19, BPA946RB-200, BPA946RB-50, HC 300 1GAL, HC3001GAL, NC9475452, NC9475553, NC9614315, NC9631882, NC9743229, S118016, S254CA4, S70091, S70091HPLC, S70091SPEC, XXA181LI, XXA949U200LI Synonyms: Dimethylformaldehyde; Dimethyl ketone; 2-Propanone; Pyroacetic acid; Pyroacetic ether. Company Identification:              Fisher Scientific              1 Reagent Lane              Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887 P.Duern 2004

  43. Section 2 - Composition, Information on Ingredients Section 3 - Hazards Identification CAS# Chemical Name Percent EINECS/ELINCS 67-64-1 Acetone 99.0 200-662-2 Hazard Symbols: XI F Risk Phrases: 11 36 66 67 EMERGENCY OVERVIEW Appearance: colourless. Flash Point: -4 deg F. Danger! Causes eye and skin irritation. May cause central nervous system depression. May cause liver and kidney damage. Causes respiratory tract irritation. Extremely flammable liquid and vapor. Vapor may cause flash fire. Target Organs: Kidneys, central nervous system, liver, respiratory system, eyes, skin. Section 4- First Aid Measures Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. Ingestion: Do NOT induce vomiting. If victim Section 4 - First Aid Measures is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Treat symptomatically and supportively P.Duern 2004

  44. Section 5 - Fire Fighting Measures Section 6 - Accidental Release Measures Section 7 - Handling and Storage Section 8 - Exposure Controls, Personal Protection Section 9 - Physical and Chemical Properties Section 10 - Stability and Reactivity Section 11 - Toxicological Information Section 12 - Ecological Information Section 13 - Disposal Considerations P.Duern 2004

  45. Section 14 - Transport Information Canada TDG Section 16 - Additional Information Shipping Name: ACETONE ACETONE Hazard Class: 3 3 UN Number: UN1090 UN1090 Packing Group: II II Additional Info: FLASHPOINT -20 US DOT IATA RID/ADR IMO Canada TDG Shipping Name: ACETONE ACETONE Hazard Class: 3 3 UN Number: UN1090 UN1090 Packing Group: II II Additional Info: FLASHPOINT -20 C Section 15 - Regulatory Information MSDS Creation Date: 7/26/1999 Revision #9 Date: 3/19/2001 P.Duern 2004

  46. National Training SolutionsW.H.M.I.S. • Q: HOW CAN HAZARDOUS SUBSTANCES ENTER YOUR BODY? • INHALATION- • ABSORPTION- • INGESTION- • INJECTION- P.Duern 2004

  47. National Training SolutionsW.H.M.I.S. • SUMMARY: • Q: WHAT DOES W.H.M.I.S. MEAN? • Q: WHAT IS A CONTROLLED PRODUCT? • Q: WHMIS LEGISLATION APPLIES TO WHOM? • Q: WHAT ARE THE 8 CLASSES OF WHMIS CLASSIFICATIONS?…… P.Duern 2004

  48. National Training SolutionsW.H.M.I.S. • SUMMARY: • Q: WHAT 4 TYPES OF LABELS OR IDENTIFICATION CAN BE USED FOR CONTROLLED SUBSTANCES? • WHAT 3 PIECES OF INFORMATION ARE ON EACH WORKPLACE LABEL? • WHAT DOES M.S.D.S. STAND FOR? P.Duern 2004

  49. National Training SolutionsW.H.M.I.S • SUMMARY: • HOW OFTEN MUST AN MSDS BE REPLACED OR UPDATED? • IS WHMIS A NORTH AMERICAN OR CANADIAN REQUIREMENT? P.Duern 2004

  50. National Training SolutionsW.H.M.I.S. CERTIFICATION TEST P.Duern 2004

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