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Ligand Substitution Reactivity of Coordinated Ligands

Ligand Substitution Reactivity of Coordinated Ligands

Ligand Substitution Reactivity of Coordinated Ligands. Peter H.M. Budzelaar. Why care about substitution ?. Basic premise about metal-catalyzed reactions: Reactions happen in the coordination sphere of the metal Reactants (substrates) come in, react, and leave again

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319 views • 25 slides
LECTURE 5: ORGANOMETALLIC REACTIONS I LIGAND SUBSTITUTION

LECTURE 5: ORGANOMETALLIC REACTIONS I LIGAND SUBSTITUTION

LECTURE 5: ORGANOMETALLIC REACTIONS I LIGAND SUBSTITUTION. LIGAND SUBSTITUTION. LIGAND SUBSTITUTION. Basic premise about metal-catalyzed reactions: Reactions happen in the coordination sphere of the metal Reactants (substrates) come in, react, and leave again

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794 views • 24 slides
LECTURE 5: ORGANOMETALLIC REACTIONS I LIGAND SUBSTITUTION

LECTURE 5: ORGANOMETALLIC REACTIONS I LIGAND SUBSTITUTION

LECTURE 5: ORGANOMETALLIC REACTIONS I LIGAND SUBSTITUTION. LIGAND SUBSTITUTION. LIGAND SUBSTITUTION. Basic premise about metal-catalyzed reactions: Reactions happen in the coordination sphere of the metal Reactants (substrates) come in, react, and leave again

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504 views • 24 slides
Ligand substitution reactions: dissociative

Ligand substitution reactions: dissociative

Ligand substitution reactions: dissociative. Example: Factors influencing ease of dissociation: 1 e row < 2 e row > 3 e row d 8 -ML 5 > d 10 -ML 4 > d 6 -ML 6 stable ligands (CO, olefins, Cl - ) dissociate easily (as opposed to e.g. CH 3 , Cp). Dissociative substitution in ML 6.

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1.14k views • 22 slides

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