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Ligand Substitution Reactivity of Coordinated Ligands

Ligand Substitution Reactivity of Coordinated Ligands

Ligand Substitution Reactivity of Coordinated Ligands. Peter H.M. Budzelaar. Why care about substitution ?. Basic premise about metal-catalyzed reactions: Reactions happen in the coordination sphere of the metal Reactants (substrates) come in, react, and leave again

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816 views • 25 slides
Ligand Substitution Reactivity of Coordinated Ligands

Ligand Substitution Reactivity of Coordinated Ligands

Ligand Substitution Reactivity of Coordinated Ligands. Peter H.M. Budzelaar. Why care about substitution ?. Basic premise about metal-catalyzed reactions: Reactions happen in the coordination sphere of the metal Reactants (substrates) come in, react, and leave again

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320 views • 25 slides
LECTURE 5: ORGANOMETALLIC REACTIONS I LIGAND SUBSTITUTION

LECTURE 5: ORGANOMETALLIC REACTIONS I LIGAND SUBSTITUTION

LECTURE 5: ORGANOMETALLIC REACTIONS I LIGAND SUBSTITUTION. LIGAND SUBSTITUTION. LIGAND SUBSTITUTION. Basic premise about metal-catalyzed reactions: Reactions happen in the coordination sphere of the metal Reactants (substrates) come in, react, and leave again

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504 views • 24 slides
Ligand substitution reactions: dissociative

Ligand substitution reactions: dissociative

Ligand substitution reactions: dissociative. Example: Factors influencing ease of dissociation: 1 e row < 2 e row > 3 e row d 8 -ML 5 > d 10 -ML 4 > d 6 -ML 6 stable ligands (CO, olefins, Cl - ) dissociate easily (as opposed to e.g. CH 3 , Cp). Dissociative substitution in ML 6.

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1.14k views • 22 slides

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