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Enolate - PowerPoint PPT Presentation

Advanced Organic Chemistry

Advanced Organic Chemistry. Part B: Reactions and Synthesis 4 th Edition Francis A. Carey and Richard J. Sundberg Kluar Academic / Plenum Publishers. Chapter 1. Alkylation of Nucleophilic Carbon Intermediates. Introduction

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Chapter 18

Chapter 18. Reactions at the a Carbon of Carbonyl Compounds Enols and Enolates. Keto, enol and enolate structures:. What is a keto form ? A structure that contains a carbonyl. E.g. aldehyde, ketone, ester, acid, etc. What is an enol ?

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A library of the enol and enolate mediated carbonyl compound reactions:

A library of the enol and enolate mediated carbonyl compound reactions:. Intermolecular a -alkylation and acetoacetic and malonic ester synthesis via enolate anions Chapters 22 and 23. Intramolecular a -alkylation Favorskii rearrangement via enolate anions extra.

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1.07k views • 44 slides

Chapter 22 Carbonyl Alpha-Substitution Reactions

Chapter 22 Carbonyl Alpha-Substitution Reactions. The  Position. The carbon next to the carbonyl group is designated as being in the  position Electrophilic substitution occurs at this position through either an enolate or enol ion. Why this Chapter?.

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720 views • 34 slides

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Enolate - PowerPoint PPT Presentation

Advanced Organic Chemistry

Chapter 18

A library of the enol and enolate mediated carbonyl compound reactions:

Chapter 22 Carbonyl Alpha-Substitution Reactions