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High field chemical shifts - PowerPoint PPT Presentation

Metal carbonyls may be mononuclear or polynuclear

Metal carbonyls may be mononuclear or polynuclear . Characterization of metal carbonyls. IR spectroscopy. (C-O bond stretching modes). Effect of charge. u (free CO) 2143 cm -1. Lower frequency, weaker CO bond. Effect of other ligands. Increasing elec donating ability of phosphines.

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1.93k views • 48 slides

Elements of organometallic chemistry

Elements of organometallic chemistry. Elements of organometallic chemistry. Complexes containing M-C bonds Complexes with p -acceptor ligands Chemistry of lower oxidation states very important Soft-soft interactions very common Diamagnetic complexes dominant Catalytic applications.

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1.52k views • 45 slides

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High field chemical shifts - PowerPoint PPT Presentation

Metal carbonyls may be mononuclear or polynuclear

Elements of organometallic chemistry