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Formulas, Equations, and Moles

Chapter 3. Formulas, Equations, and Moles. 3 ways of representing the reaction of H 2 with O 2 to form H 2 O. reactants. products. A process in which one or more substances is changed into one or more new substances is a chemical reaction.

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Formulas, Equations, and Moles

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  1. Chapter 3 Formulas, Equations, and Moles

  2. 3 ways of representing the reaction of H2 with O2 to form H2O reactants products A process in which one or more substances is changed into one or more new substances is a chemical reaction A chemical equation uses chemical symbols to show what happens during a chemical reaction 3.7

  3. Conservation of Mass • Antoine Lavoisier (1743–1794): Showed that mass of products is exactly equal to the mass of reactants.

  4. Balancing Chemical Equations 01 • A balanced chemical equation represents the conversion of the reactants to products such that the number of atoms of each element is conserved. reactants  products limestone  quicklime + gas Calcium carbonate  calcium oxide + carbon dioxide CaCO3(s)  CaO(s) + CO2(g)

  5. C2H6 + O2 CO2 + H2O Balance the following equation

  6. C2H6 + O2 CO2 + H2O NOT 2CO2 C2O4 Balancing Chemical Equations • Write the correct formula(s) for the reactants on the left side and the correct formula(s) for the product(s) on the right side of the equation. Ethane reacts with oxygen to form carbon dioxide and water • Change the numbers in front of the formulas (coefficients) to make the number of atoms of each element the same on both sides of the equation. Do not change the subscripts. 3.7

  7. 1 carbon on right 6 hydrogen on left 2 hydrogen on right 2 carbon on left C2H6 + O2 C2H6 + O2 C2H6 + O2 CO2 + H2O 2CO2 + H2O 2CO2 + 3H2O Balancing Chemical Equations • Start by balancing those elements that appear in only one reactant and one product. start with C or H but not O multiply CO2 by 2 multiply H2O by 3 3.7

  8. multiply O2 by 4 oxygen (2x2) + 3 oxygen (3x1) 2 oxygen on left C2H6 + O2 2CO2 + 3H2O C2H6 + O2 2CO2 + 3H2O 2C2H6 + 7O2 4CO2 + 6H2O 7 7 2 2 Balancing Chemical Equations • Balance those elements that appear in two or more reactants or products. = 7 oxygen on right remove fraction multiply both sides by 2 3.7

  9. 4 C (2 x 2) 4 C Reactants Products 12 H (2 x 6) 12 H (6 x 2) 14 O (7 x 2) 14 O (4 x 2 + 6) 4 C 4 C 12 H 12 H 14 O 14 O 2C2H6 + 7O2 4CO2 + 6H2O Balancing Chemical Equations • Check to make sure that you have the same number of each type of atom on both sides of the equation. 3.7

  10. Mass Relationships in Chemical Reactions

  11. Micro World atoms & molecules Macro World grams Atomic mass is the mass of an atom in atomic mass units (amu) By definition: 1 atom 12C “weighs” 12 amu On this scale 1H = 1.008 amu 16O = 16.00 amu 1amu = 1.660539 X 10 -24 g 3.1

  12. Atomic and Molecular Mass 02 • The atomic masses as tabulated in the periodic table are the averages of the naturally occurring isotopes. • Mass of C = average of 12C (98.89%) and • 13C (1.11%) • = 0.9889 x 12 amu + 0.0111 x 13.0034 amu • = 12.011 amu

  13. 7.42 x 6.015 + 92.58 x 7.016 100 Natural lithium is: 7.42% 6Li (6.015 amu) 92.58% 7Li (7.016 amu) Average atomic mass of lithium: = 6.94 amu 3.1

  14. Average atomic mass (6.941)

  15. Dozen = 12 Pair = 2 The mole (mol) is the amount of a substance that contains as many elementary entities as there are atoms in exactly 12.00 grams of 12C 1 mol = NA = 6.0221367 x 1023 Avogadro’s number (NA) 3.2

  16. eggs shoes Molar mass is the mass of 1 mole of in grams marbles atoms 1 mole 12C atoms = 6.022 x 1023 atoms = 12.00 g 1 12C atom = 12.00 amu 1 mole 12C atoms = 12.00 g 12C 1 mole lithium atoms = 6.941 g of Li For any element atomic mass (amu) = molar mass (grams) 3.2

  17. 1 amu = ?g 1 12C atom 12.00 g 1.66 x 10-24 g = 12.00 amu 6.022 x 102312C atoms 1 amu = molar mass in g/mol M x 1 amu = 1.66 x 10-24 g or 1 g = 6.022 x 1023 amu 1.660539 x 10-24 g NA= Avogadro’s number 3.2

  18. Do You Understand Molar Mass? 1 mol K 6.022 x 1023 atoms K x x = 1 mol K 39.10 g K How many atoms are in 0.551 g of potassium (K) ? 1 mol K = 39.10 g K 1 mol K = 6.022 x 1023 atoms K 0.551 g K 8.49 x 1021 atoms K 3.2

  19. Atomic and Molecular Mass • The mass of a molecule is just the sum of the masses of the atoms making up the molecule. • m(C2H4O2) = 2·mC + 4·mH + 2·mO • = 2·(12.01 amu) + 4·(1.01 amu) + 2·(16.00 amu) • = 60.06 amu

  20. 1S 32.07 amu 2O + 2 x 16.00 amu SO2 SO2 64.07 amu Molecular mass (or molecular weight) is the sum of the atomic masses (in amu) in a molecule. For any molecule molecular mass (amu) = molar mass (grams) 1 molecule SO2 = 64.07 amu 1 mole SO2 = 64.07 g SO2 3.3

  21. Do You Understand Molecular Mass? 8 mol H atoms 6.022 x 1023 H atoms 1 mol C3H8O x x x = 1 mol C3H8O 1 mol H atoms 60 g C3H8O How many H atoms are in 72.5 g of C3H8O ? 1 mol C3H8O = (3 x 12) + (8 x 1) + 16 = 60 g C3H8O 1 mol C3H8O molecules = 8 mol H atoms 1 mol H = 6.022 x 1023 atoms H 72.5 g C3H8O 5.82 x 1024 atoms H 3.3

  22. Methionine, an amino acid used by organisms to make proteins, is represented below. Write the formula for methionine and calculate its molar mass. (red = O; gray = C; blue = N; yellow = S; ivory = H) Molar Mass

  23. Stoichiometry 01 • Stoichiometry: Relates the moles of products and reactants to each other and to measurable quantities.

  24. Yields of Chemical Reactions:If the actual amount of product formed in a reaction is less than the theoretical amount, we can calculate apercentage yield: Stoichiometry

  25. Limiting Reactant How Many Cookies Can I Make? • You can make cookies until you run out of one of the ingredients • Once this family runs out of sugar, they will stop making cookies (at least any cookies you would want to eat)

  26. How Many Cookies Can I Make? • In this example the sugar would be the limiting reactant, because it will limit the amount of cookies you can make

  27. 6 green used up 6 red left over Limiting Reagents 3.9

  28. In this figure, what is the limiting reagent? Stoichiometry

  29. Do You Understand Limiting Reagents? 2Al + Fe2O3 Al2O3 + 2Fe g Al mol Al mol Fe2O3 needed g Fe2O3 needed OR g Fe2O3 mol Fe2O3 mol Al needed g Al needed 1 mol Fe2O3 160. g Fe2O3 1 mol Al = x x x 27.0 g Al 2 mol Al 1 mol Fe2O3 Start with 124 g Al need 367 g Fe2O3 In one process, 124 g of Al are reacted with 601 g of Fe2O3 Calculate the mass of Al2O3 formed. 367 g Fe2O3 124 g Al Have more Fe2O3 (601 g) so Al is limiting reagent 3.9

  30. 2Al + Fe2O3 Al2O3 + 2Fe g Al mol Al mol Al2O3 g Al2O3 1 mol Al x 27.0 g Al 1 mol Al2O3 102. g Al2O3 = x x 2 mol Al 1 mol Al2O3 Use limiting reagent (Al) to calculate amount of product that can be formed. 234 g Al2O3 124 g Al 3.9

  31. Solution Concentrations 01 • Concentration allow us to measure out a specific number of moles of a compound by measuring the mass or volume of a solution.

  32. What mass of KI is required to make 500. mL of a 2.80 M KI solution? moles of solute M = molarity = liters of solution volume KI moles KI grams KI 1 L 2.80 mol KI 166 g KI x x x 1000 mL 1 L soln 1 mol KI Solution Stoichiometry The concentration of a solution is the amount of solute present in a given quantity of solvent or solution. M KI M KI 500. mL = 232 g KI 4.5

  33. 4.5

  34. Solution Concentrations 04 • Dilution: • Is the process of reducing a solution’s concentration by adding more solvent.

  35. Moles of solute before dilution (i) Moles of solute after dilution (f) = Dilution Add Solvent = MfVf MiVi Dilution is the procedure for preparing a less concentrated solution from a more concentrated solution. 4.5

  36. How would you prepare 60.0 mL of 0.2 M HNO3 from a stock solution of 4.00 M HNO3? MfVf 0.200 x 0.06 Vi = = 4.00 Mi MiVi = MfVf Mi = 4.00 Vi = ? L Mf = 0.200 Vf = 0.06 L = 0.003 L = 3 mL 57 mL of water 3 mL of acid = 60 mL of solution +

  37. Solution Stoichiometry uses molarity as a conversion factor between volume and moles of a substance in a solution.

  38. Titrations In a titration a solution of accurately known concentration is added gradually added to another solution of unknown concentration until the chemical reaction between the two solutions is complete. Equivalence point – the point at which the reaction is complete Indicator – substance that changes color at (or near) the equivalence point Slowly add base to acid with unknown concentration UNTIL the indicator changes color 4.7

  39. WRITE THE CHEMICAL EQUATION! What volume of a 1.420 M NaOH solution is Required to titrate 25.00 mL of a 4.50 M H2SO4 solution? H2SO4 + 2NaOH 2H2O + Na2SO4 M M rx volume acid moles acid moles base volume base base acid coef. 4.50 mol H2SO4 2 mol NaOH 1000 ml soln x x x 1000 mL soln 1 mol H2SO4 1.420 mol NaOH 25.00 mL = 158 mL

  40. Percent Composition: Identifies the elements present in a compound as a mass percent of the total compound mass. The mass percent is obtained by dividing the mass of each element by the total mass of a compound and converting to percentage. Percentage Composition 01

  41. 2 x (12.01 g) 6 x (1.008 g) 1 x (16.00 g) %C = %H = %O = x 100% = 52.14% x 100% = 13.13% x 100% = 34.73% 46.07 g 46.07 g 46.07 g C2H6O Percent composition of an element in a compound 52.14% + 13.13% + 34.73% = 100.0%

  42. Empirical Formula 01 • Theempirical formula gives the ratio of the number of atoms of each element in a compound. CompoundFormulaEmpirical Formula Hydrogen peroxide H2O2 OH Benzene C6H6 CH Ethylene C2H4 CH2 Propane C3H8 C3H8

  43. A compound’s empirical formula can be determined from its percent composition. A compound’s molecular formula is determined from the molar mass and empirical formula. Empirical Formula 02

  44. Empirical Formula 03 • Combustion analysis is one of the most common methods for determining empirical formulas. • A weighed compound is burned in oxygen and its products analyzed by a gas chromatogram. • It is particularly useful for analysis of hydrocarbons.

  45. g CO2 g H2O mol CO2 mol H2O mol C mol H g C g H Combust 11.5 g ethanol Collect 22.0 g CO2 and 13.5 g H2O 6.0 g C = 0.5 mol C 1.5 g H = 1.5 mol H g of O = g of sample – (g of C + g of H) 4.0 g O = 0.25 mol O Empirical formula C0.5H1.5O0.25 Divide by smallest subscript (0.25) Empirical formula C2H6O

  46. IS NOT How to “Read” Chemical Equations 2 Mg + O2 2 MgO 2 atoms Mg + 1 molecule O2 makes 2 formula units MgO 2 moles Mg + 1 mole O2 makes 2 moles MgO 48.6 grams Mg + 32.0 grams O2 makes 80.6 g MgO 2 grams Mg + 1 gram O2 makes 2 g MgO 3.7

  47. 2CH3OH + 3O2 2CO2 + 4H2O grams CH3OH moles CH3OH moles H2O grams H2O 4 mol H2O 18.0 g H2O 1 mol CH3OH x = x x 2 mol CH3OH 32.0 g CH3OH 1 mol H2O Methanol burns in air according to the equation If 209 g of methanol are used up in the combustion, what mass of water is produced? molar mass CH3OH molar mass H2O coefficients chemical equation 209 g CH3OH 235 g H2O 3.8

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