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PpAOS1 PpAOS2

18:3 (n-3). 20:4 (n-6). PpLOX1 PpLOX2. PpLOX1-7. 13 S -HPOTE. 12 S -HPETE. PpAOS1 PpAOS2. PpAOS1 PpAOS2. Non- enzymatic Hydrolysis and Cyclization. Non- enzymatic Hydrolysis and Cyclization. 12,13-EOT. 11,12-EETE. PpAOC1 PpAOC2. PpAOC2. α- ketols γ - ketols Racemic

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PpAOS1 PpAOS2

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  1. 18:3 (n-3) 20:4 (n-6) PpLOX1 PpLOX2 PpLOX1-7 13S-HPOTE 12S-HPETE PpAOS1 PpAOS2 PpAOS1 PpAOS2 Non-enzymatic Hydrolysis and Cyclization Non-enzymatic Hydrolysis and Cyclization 12,13-EOT 11,12-EETE PpAOC1 PpAOC2 PpAOC2 α-ketols γ-ketols Racemic cyclopentenone α-ketols γ-ketols Racemic cyclopentenone cis-(+)-OPDA 11-OPTA

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