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Chapter 19 Heat and the First Law of Thermodynamics

Chapter 19 Heat and the First Law of Thermodynamics. 19-5 Latent Heat. Energy is required for a material to change phase , even though its temperature is not changing. Latent heat is the heat (energy) required to change 1kg of substance from solid to liquid. 19-5 Latent Heat.

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Chapter 19 Heat and the First Law of Thermodynamics

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  1. Chapter 19Heat and the First Law of Thermodynamics

  2. 19-5 Latent Heat • Energy is required for a material to change phase, even though its temperature is not changing. • Latent heat is the heat (energy) required to change 1kg of substance from solid to liquid

  3. 19-5 Latent Heat The total heat required for a phase change depends on the total mass and the latent heat:

  4. 19-5 Latent Heat Heat of fusion, LF: heat required to change 1.0 kg of material from solid to liquid Heat of vaporization, LV: heat required to change 1.0 kg of material from liquid to vapor

  5. 19-5 Latent Heat The latent heat of vaporization is relevant for evaporation as well as boiling. The heat of vaporization of water rises slightly as the temperature decreases. On a molecular level, the heat added during a change of state does not increase the kinetic energy of individual molecules, but rather break the close bonds between them so the next phase can occur.

  6. 19-5 Latent Heat Example 19-6: Determining a latent heat. The specific heat of liquid mercury is 140 J/kg·°C. When 1.0 kg of solid mercury at its melting point of -39°C is placed in a 0.50-kg aluminum calorimeter filled with 1.2 kg of water at 20.0°C, the mercury melts and the final temperature of the combination is found to be 16.5°C. What is the heat of fusion of mercury in J/kg?

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