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Chemistry Today. Breathalyzers. When alcohol is consumed, 90% is metabolized. This occurs primarily in the liver. For an average adult male (5’8”, 160 lbs), drinking 4 or more beers in one hour can cause the legal intoxication. Fig 6.4. Breathalyzers (2).
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Breathalyzers • When alcohol is consumed, 90% is metabolized. This occurs primarily in the liver. • For an average adult male (5’8”, 160 lbs), drinking 4 or more beers in one hour can cause the legal intoxication. Fig 6.4
Breathalyzers (2) • A small percentage of alcohol is exhaled as gas through the lungs. The assumption is that the % alcohol content in the lungs is 2100 times lower than the % alcohol content in the blood. • The Blood Alcohol Content (BAC) legal limit is 0.08 = 0.08 g alcohol in 100 mL blood. When alcohol in the blood exceeds 0.08, a person is legally intoxicated.
How Does a Breathalyzer Work? • Dark R1 + Alcohol Light P1 • 2K2Cr2O7 [DARK reddish orange] + 3CH3CH2OH + 8H2SO4 2Cr2(SO4)3 [LIGHT green] + 2K2SO4 + 3CH3COOH + 11H2O • Catalyzed (speeded up) by AgNO3 • As Ethyl Alcohol or Ethanol,CH3CH2OH increases, the solution becomes lighter and transmits more light.
How Does a Breathalyzer Work? (2) • The amount of light transmitted through the alcohol detecting solution is measured yields a %BAC. • Calculate your BAC: • http://science.howstuffworks.com/breathalyzer6.htm
Other Applications for Breathlyzer Technology • In the 18th century, French chemist Lavoisier proved that the body produces CO2. 200 years later (1970's), Linus Pauling showed that the breath contains over 100 different organic compounds. • Preliminary studies are focused on detecting these compounds and seeking to link them with diseases for diagnostic purposes.
Examples • Predict if a heart transplant patient will reject a new organ. Hearts-breath test technology is similar to the breathalyzer but "a billions times more sensitive". The FDA approved it last year. • This test (few hundred $) can determine if an biopsy (thousands of $) is needed. • However, a biopsy is more sensitive and selective. More R&D is needed.
Examples (2) • Detect TB, lung cancer, diabetes before symptoms are observed. • Forensic detection of explosive-handling. • Consistent with increasing use of non-invasive medical procedures. • Good for children. • NY Times
What do these words have in common? • Mercury • Cobalt • Element • Ion • Fusion
What do these words have in common? • CHEMICAL TERMS AND CAR NAMES • Mercury • Chevy Cobalt • Honda Element • Saturn Ion • Honda Fusion
What's That Stuff • What's That Stuff? • http://pubs.acs.org/cen/whatstuff/stuff.html • Periodic Table of Comic Book Elements • http://www.uky.edu/Projects/Chemcomics/
HAVE A FUN AND SAFE SPRING BREAK • Exam 2 available March 20 along with another Reflection Project.