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Performance Benefits with Synthetics. Improved energy efficiency Wider operating temperature range Increased design ratings Reduced maintenance costs Better reliability, safer operation Enhanced environmental performance. Performance Benefits with Synthetics.
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Performance Benefits with Synthetics • Improved energy efficiency • Wider operating temperature range • Increased design ratings • Reduced maintenance costs • Better reliability, safer operation • Enhanced environmental performance
Performance Benefits with Synthetics • Internal Combustion Engines • Lower viscosity with low volatility • Improved oxidation stability, less viscosity increase with oil aging • Better short trip fuel economy due to lower viscosity at low temperatures • Reduced contact losses due to low traction and lower pressure-viscosity coefficient • Gears • Lower mesh losses due to reduced traction • Lower viscous losses at low temperature 1. Improved Energy Efficiency
30 Noack Polydecene Volatility Mineral (% Loss at 25 250C, 1 hr) 22% 20 15 13% 10 5 0 3 4 5 6 7 8 9 10 11 Kinematic Viscosity at 100C, cS Lower Viscosity with Low Volatility • Polydecene base stocks have lower volatility than mineral oils
Traction Force Mineral Oil Polydecene Slide-Roll Ratio +S -S Area between curves is energy saved with low traction synthetic lubes Range of Slide-Roll Ratio in Spur Gear Gear Mesh Loss Reduction with Low Traction Synthetics Polydecene-based synthetics can improve efficiency of spur/helical gears by 0.5%/mesh
-80 -40 0 200 400 600 Fahrenheit Mineral Oils Polydecenes Alkyl Aromatics Diesters Polyol Esters Polyglycols Phosphate esters Celsius -60 -40 -20 100 200 300 Limited by Starting Torque Continuous Service Intermittent Service Performance Benefits with Synthetics 2. Wider Operating Temperature Range • Better oxidative stability • Lower pour point, no wax • Less volatile • Higher VI
Pour Point°C 0 Mineral oil -10 -20 -30 -40 -50 Polydecene -60 -70 -80 2 4 6 8 10 20 30 40 50 KV at 100°C, cST Synthetics have Lower Pour Points
Viscosity Mineral Oil High VI Equivalentviscosity ISO VG Increased protection 40 Temperature, °C Increased Protection from High VI • High VI gives less viscosity loss as temperature increases
Performance Benefits with Synthetics • Higher power, same life • Same power, longer life • Smaller unit, same power, same life 3. Increased Design Ratings Enclosed - Low traction, higher loads before Gearboxes scuffing/scoring Traction Drives - Synthetic high traction fluids are an enabling technology Engines - Higher oxidative stability, less deposits, lower volatility Slow speed - High shear stable viscosity, still gears/bearings fluid at low temperature
Worm Gear Efficiency % 100 Lower Traction 90 80 Polydecene Mineral Oil 70 60 0 10 20 30 40 50 Reduction Ratio Traction and Worm Gear Efficiency • In worm gears, polydecene-based synthetics give 2-10% energy savings and permit increased thermal ratings
30 90C Traction Fluids 25 PAG 1 Naphthenic 20 IN OUT Paraffinic Maximum Shear Stress, kpsi 15 PAO SuperSyn 10 PAG 2 5 0 0 100 200 300 400 500 Peak Contact Pressure, kpsi Traction Drives and Traction Fluids Traction Drives need high shear strength fluids
Performance Benefits with Synthetics • Longer oil life • Extended drain intervals • Lower disposal costs • Longer component life • Reduced wear • Reduced pitting • Improved cleanliness • No seasonal oil changes needed • Lower oil consumption • Less make-up needed 4. Reduced Maintenance Costs
Performance Benefits with Synthetics • Aerospace needs, extreme conditions • Jet engines - high temperatures • Hydraulic systems - low temperatures • Space vehicles • vacuum • temperature extremes • inaccessible • Automobile racing • High loads and temperatures • Safety margin - coolant loss, low oil level • Fire-resistant hydraulic fluids 5. Better Reliability, Safer Operation
Performance Benefits with Synthetics • Biodegradable base stocks • wider temperature range • more predictable performance • Lubricants for refrigeration systems which use non-ozone depleting refrigerants • Reduced volume of waste oil through extended drain capability • Potential for recovery and recycle 6. Enhanced environmental performance
Conclusions • Mineral base stocks are average performers for many applications but not optimum. • Synthesis matches molecules plus the right additives with applications. • Synthetics must show an economic benefit or do what a mineral oil can not. • Economic benefits come from • Energy efficiency • Wider temperature range • Increased design ratings • Reduced maintenance • Reliability and safety. • Environmental performance. • Future developments will come from studies of structure-property relationships.