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Empirical & Molecular Formulas for Covalent Compounds. empirical formula: Lowest whole number ratio of atoms (EF) molecular formula: Shows the actual number of atoms (MF). Reduced formula. Compound MF EF water H 2 O H 2 O hydrogen H 2 O 2 HO peroxide
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Empirical & Molecular Formulas for Covalent Compounds • empirical formula: Lowest whole number ratio of atoms (EF) • molecular formula: Shows the actual number of atoms (MF) Reduced formula
Compound MF EF water H2O H2O hydrogen H2O2 HO peroxide sodium Na3N Na3N nitride dinitrogen N2S4 NS2 tetrasulfide
Calculate EMPIRICAL FORMULA from percent composition: 1. Convert percent to grams (assume 100 gram sample) 2. Convert grams to moles (mmpt & factor label) 3. Change moles to whole numbers (divide by smallest) 4. Use moles (whole #’s) as subscripts
If a compound has the following percent composition: 40.0% carbon, 6.71% hydrogen, and 53.3% oxygenDetermine its empirical formulas
Empirical Formula • Convert the percentage to grams and then mols • 40.0% C= 40.0 grams C = 3.33 mols • 6.71% H = 6.71 grams H = 6.71 mols • 53.3% O = 53.3 grams O = 3.33 mols
Empirical Formula • Determine the smallest number of mols and divide into each element to get a whole number. • Smallest no. of mols is 3.33 • Carbon 3.33/3.33 = 1 • Hydrogen 6.71/3.33 = 2 • Oxygen 3.33/3.33 =1 • Use the whole numbers as subscripts • CH2O
Calculate MOLECULAR FORMULAS 1. Calculate the molar mass for the EF 2.Dividemolar mass MF= whole # molar mass EF 3. Multiply whole # times the EF subscripts
If a compound has the following percent composition: 40.0% carbon, 6.71% hydrogen, and 53.3% oxygen and its molar mass is 180 g/molCalculate its empirical and molecular formulas?
Calculate MOLECULAR FORMULAS • Calculate the molar mass for the EF • CH2O-from the previous problem. 12 + 2 + 16 =30 g/mol • Dividemolar mass MF= Whole # molar mass EF • 180 / 30 = 5 • 3. Multiply Whole # times the EF subscripts • C5H10O5