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Variables. Units. MOLA L ITY – Ch 13, p. 416. Quantifies the concentration of a solution. Molality ( m ) = mol solute = n = mol mass solvent m kg Read as “moles solute per kilogram solvent”. MOLALITY – Ch 13.
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Variables Units MOLALITY – Ch 13, p. 416 Quantifies the concentration of a solution. Molality (m) = mol solute = n = mol mass solvent m kg Read as “moles solute per kilogram solvent”
MOLALITY – Ch 13 Example 1: “If 80.0 g sodium hydroxide, which is 2 mol, is dissolved in 1 kg water, a 2.00m solution of NaOH is produced.” p.416
MOLALITY – Ch 13 Example 1: “If 80.0 g sodium hydroxide, which is 2 mol, is dissolved in 1 kg water, a 2.00m solution of NaOH is produced.” p.416 Why use molality? Its value does not change with temperature changes. As opposed to molarity M = mol L
MOLALITY – Ch 13 Example 2: Determine the molal concentration of a solution containing 8.13 g ethylene glycol, HOCH2CH2OH, dissolved in 166 g water.
Example 2: Determine the molal concentration of a solution containing 8.13 g ethylene glycol, HOCH2CH2OH, dissolved in 166 g water. Given:
Example 2: Determine the molal concentration of a solution containing 8.13 g ethylene glycol, HOCH2CH2OH, dissolved in 166 g water. Given: mass solute = 8.13 g
Example 2: Determine the molal concentration of a solution containing 8.13 g ethylene glycol, HOCH2CH2OH, dissolved in 166 g water. Given: mass solute = 8.13 g mass solvent = 166 g
Example 2: Determine the molal concentration of a solution containing 8.13 g ethylene glycol, HOCH2CH2OH, dissolved in 166 g water. Given: mass solute = 8.13 g mass solvent = 166 g Unknown:
Example 2: Determine the molal concentration of a solution containing 8.13 g ethylene glycol, HOCH2CH2OH, dissolved in 166 g water. Given: mass solute = 8.13 g mass solvent = 166 g Unknown: m
Example 2: Determine the molal concentration of a solution containing 8.13 g ethylene glycol, HOCH2CH2OH, dissolved in 166 g water. Given: mass solute = 8.13 g mass solvent = 166 g Unknown:m Need:
Example 2: Determine the molal concentration of a solution containing 8.13 g ethylene glycol, HOCH2CH2OH, dissolved in 166 g water. Given: mass solute = 8.13 g mass solvent = 166 g Unknown: m Need: molar mass ethylene glycol
Example 2: Given: mass solute = 8.13 g mass solvent = 166 g Unknown: m Need: molar mass = 62.068 g ethylene glycol mol m = n m
Example 2: Given: mass solute = 8.13 g mass solvent = 166 g Unknown: m Need: molar mass = 62.068 g mol m = n = 8.13 g m
Example 2: Given: mass solute = 8.13 g mass solvent = 166 g Unknown: m Need: molar mass = 62.068 g mol m = n = 8.13 g mol m 62.068 g
Example 2: Given: mass solute = 8.13 g mass solvent = 166 g Unknown: m Need: molar mass = 62.068 g mol m = n = 8.13 g mol m 62.068 g
Example 2: Given: mass solute = 8.13 g mass solvent = 166 g = .166 kgUnknown: m Need: molar mass = 62.068 g mol m = n = 8.13 g mol m 62.068 g
Example 2: Given: mass solute = 8.13 g mass solvent = 166 g = .166 kg Unknown: m Need: molar mass = 62.068 g mol m = n = 8.13 g mol m .166 kg H2O 62.068 g
Example 2: Given: mass solute = 8.13 g mass solvent = 166 g = .166 kg Unknown: m Need: molar mass = 62.068 g mol m = n = 8.13 g mol .789 mol m .166 kg H2O 62.068 g kg
Example 2: Given: mass solute = 8.13 g mass solvent = 166 g = .166 kg Unknown: m Need: molar mass = 62.068 g mol m = n = 8.13 g mol .789 m m .166 kg H2O 62.068 g
Example 3: A solution of iodine, I2, in carbon tetrachloride, CCl4, is needed for a chemical test. How much iodine must be added to prepare a 0.480 m solution of iodine in CCl4 if 100.0 g of CCl4 is used?
Example 3: A solution of iodine, I2, in carbon tetrachloride, CCl4, is needed for a chemical test. How much iodine must be added to prepare a 0.480 m solution of iodine in CCl4 if 100.0 g of CCl4 is used? Given:
Example 3: A solution of iodine, I2, in carbon tetrachloride, CCl4, is needed for a chemical test. How much iodine must be added to prepare a 0.480 m solution of iodine in CCl4 if 100.0 g of CCl4 is used? Given: molality = 0.480 m
Example 3: A solution of iodine, I2, in carbon tetrachloride, CCl4, is needed for a chemical test. How much iodine must be added to prepare a 0.480 m solution of iodine in CCl4 if 100.0 g of CCl4 is used? Given: molality = 0.480 m mass solvent = 100.0 g CCl4
Example 3: A solution of iodine, I2, in carbon tetrachloride, CCl4, is needed for a chemical test. How much iodine must be added to prepare a 0.480 m solution of iodine in CCl4 if 100.0 g of CCl4 is used? Given: molality = 0.480 m mass solvent = 100.0 g CCl4 Unknown:
Example 3: A solution of iodine, I2, in carbon tetrachloride, CCl4, is needed for a chemical test. How much iodine must be added to prepare a 0.480 m solution of iodine in CCl4 if 100.0 g of CCl4 is used? Given: molality = 0.480 m mass solvent = 100.0 g CCl4 Unknown: mass solute I2
Example 3: A solution of iodine, I2, in carbon tetrachloride, CCl4, is needed for a chemical test. How much iodine must be added to prepare a 0.480 m solution of iodine in CCl4 if 100.0 g of CCl4 is used? Given: molality = 0.480 m mass solvent = 100.0 g CCl4 Unknown: mass solute I2 Need:
Example 3: A solution of iodine, I2, in carbon tetrachloride, CCl4, is needed for a chemical test. How much iodine must be added to prepare a 0.480 m solution of iodine in CCl4 if 100.0 g of CCl4 is used? Given: molality = 0.480 m mass solvent = 100.0 g CCl4 Unknown: mass solute I2 Need: molar mass I2
Example 3: Given: molality = 0.480 m mass solvent = 100.0 g CCl4 Unknown: mass solute I2 Need: molar mass I2 =
Example 3: Given: molality = 0.480 m mass solvent = 100.0 g CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol
Example 3: Given: molality = 0.480 m mass solvent = 100.0 g CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol m = n m
Example 3: Given: molality = 0.480 m mass solvent = 100.0 g CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol m = n n = m•m m
Example 3: Given: molality = 0.480 m mass solvent = 100.0 g CCl4 = 0.1000 kg Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol m = n n = m•m m
Example 3: Given: molality = 0.480 m mass solvent = 0.1000 kg CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol n = m•m0.480 m
Example 3: Given: molality = 0.480 m mass solvent = 0.1000 kg CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol n = m•m0.480 mol kg CCl4
Example 3: Given: molality = 0.480 m mass solvent = 0.1000 kg CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol n = m•m0.480 mol0.1000 kg CCl4 kg CCl4
Example 3: Given: molality = 0.480 m mass solvent = 0.1000 kg CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol n = m•m0.480 mol0.1000 kg CCl4 kg CCl4
Example 3: Given: molality = 0.480 m mass solvent = 0.1000 kg CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol n = m•m0.480 mol0.1000 kg CCl4 .0480 mol I2 kg CCl4
Example 3: Given: molality = 0.480 m mass solvent = 0.1000 kg CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol n = m•m0.480 mol0.1000 kg CCl4 .0480 mol I2 kg CCl4
Example 3: Given: molality = 0.480 m mass solvent = 0.1000 kg CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol 0.0480 mol I2 253.808 g I2 mol I2
Example 3: Given: molality = 0.480 m mass solvent = 0.1000 kg CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol 0.0480 mol I2 253.808 g I2 mol I2
Example 3: Given: molality = 0.480 m mass solvent = 0.1000 kg CCl4 Unknown: mass solute I2 Need: molar mass I2 = 253.808 g/mol 0.0480 mol I2 253.808 g I2 12.2 g I2 mol I2
Example 4: What is the molality of a solution containing 18.2 g HCl and 250. g water?
Example 4: What is the molality of a solution containing 18.2 g HCl and 250. g water? 2.00 m