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Department of Hydro Sciences, Institute for Urban Water Management. Global water aspects Introduction to urban water management Basics for systems description Water transport Matter transport Introduction to water supply Water extraction Water purification Water distribution
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Department of Hydro Sciences, Institute for Urban Water Management • Global water aspects • Introduction to urban water management • Basics for systems description • Water transport • Matter transport • Introduction to water supply • Water extraction • Water purification • Water distribution • Introduction to wastewater disposal • Urban drainage • Wastewater treatment • Sludge treatment Urban Water Peter Krebs Dresden, 2010
Peter Krebs Department of Hydro Sciences, Institute for Urban Water Management Urban Water 4 Matter transport 4.1 Introduction to transport phenomena 4.2 Transport processes 4.3 Reactor approach 4.4 Advection-dispersion approach
Peter Krebs Department of Hydro Sciences, Institute for Urban Water Management Urban Water 4 Matter transport 4.1 Introduction to transport phenomena 4.2 Transport processes 4.3 Reactor approach 4.4 Advection-dispersion approach
Characteristics of compounds Passive solubles Travel ~ with water Often used to indicate velocity and residence-time distribution Solids Transport decoupled from flow Suspended solids and gravel Sedimentation and Erosion Reactive matter Can be solubles or solids Residence time and conditions in reactor important Reaction must be known for balancing
Quiescent conditions Stirring Milk and sugar in a cup of coffee Molecular diffusion Turbulent diffusion
L, t Tracer in a full pipe • Transport with flow • Longitudinal extension of tracer cloud • Decrease of peak concentration
Peter Krebs Department of Hydro Sciences, Institute for Urban Water Management Urban Water 4 Matter transport 4.1 Introduction to transport phenomena 4.2 Transport processes 4.3 Reactor approach 4.4 Advection-dispersion approach
Example: Transport of compound with constant concentration C in a tube with cross section A: Advection Transport with water flow no relative movement Flux
Molecular diffusion Transport in the direction of decreasing concentration 1st Fick law • 1D approach; it also applies in a 2D or 3D system • Dmd,M is a specific value for a certain compound M • Dmd,M is a function of temperature
C Diffusive flux x Turbulent diffusion Process similar to molecular diffusion, but some orders of magnitude more efficient • Dtd is dependant on flow and state of turbulence, not on the compound itself • Concentration gradients decrease !!
Dispersion Dispersion is not transport relative to water, but inhomogeneous advection In 1D formulation, dispersion “collapses on diffusion”
v Sedimentation flux vS Sedimentation • Suspended particles have a transport component in gravity direction • In reactors this effect is used for particle separation • In transport systems, a sink or source term - depending on the operation conditions - is needed Examples: - 1D clarifier model - Sewer sediments
Peter Krebs Department of Hydro Sciences, Institute for Urban Water Management Urban Water 4 Matter transport 4.1 Introduction to transport phenomena 4.2 Transport processes 4.3 Reactor approach CSTR Plug-flow reactor CSTR in series 4.4 Advection-dispersion approach
Q Q V C Cin C r Mass balance Continuously stirred tank reactor (CSTR) • Constant volume • Immediate mixing • Complete mixing no concentration gradients • CReactor = COutlet
0-order reaction 1st-order reaction CSTR: steady state Mass balance
Mass balance No input, no reaction CSTR: residence-time distribution (RTD) Tracer pulse is introduced to the inlet tracer concentration is measured in the outlet
Peter Krebs Department of Hydro Sciences, Institute for Urban Water Management Urban Water 4 Matter transport 4.1 Introduction to transport phenomena 4.2 Transport processes 4.3 Reactor approach CSTR Plug-flow reactor CSTR in series 4.4 Advection-dispersion approach
A x dx Mass balance Plug-flow reactor • Constant volume • Constant cross section • No mixing (ev. lateral) • Concentration gradients along flow axes
Plug-flow reactor: steady state Outlet concentrations: with x = L L/v = Mass balance 0-order 1st order
Plug-flow reactor: RTD Tracer pulse is introduced to the inlet tracer pulse appears in the outlet unchanged !!
Peter Krebs Department of Hydro Sciences, Institute for Urban Water Management Urban Water 4 Matter transport 4.1 Introduction to transport phenomena 4.2 Transport processes 4.3 Reactor approach CSTR Plug-flow reactor CSTR in series 4.4 Advection-dispersion approach
Q Q Q Q Q r r r C2 Ci-1 Ci Cn-1 Cn V2 C2 Vi Ci Vn Cn 1st order reaction Reactor i CSTR cascade Q Q r Cin C1 V1 C1
2 Reactors n Reactors CSTR cascade: 1st order reaction (i) n = number of reactors Total volume
n Reactors CSTR cascade: 1st order reaction (ii)
2nd reactor i-th reactor CSTR cascade: RTD (i) Initial condition in 1st reactor c0,1 as reference concentration 1st reactor
Mean value Variance Peak value at time CSTR cascade: RTD (ii) Solving the coupled equations with Laplace transformation yields
Peter Krebs Department of Hydro Sciences, Institute for Urban Water Management Urban Water 4 Matter transport 4.1 Introduction to transport phenomena 4.2 Transport processes 4.3 Reactor approach 4.4 Advection-dispersion approach
Analytical solution for a tracer pulse u = mean velocity Ddisp = dispersion coefficient m = total amount of tracer introduced A = cross-section area t = time from dosage Advection-dispersion approach (i)
Advection-dispersion approach (ii) Standard deviation Dispersion coefficient Shear velocity cf = Fischer coefficient = 0.011 (-) b = width of water surface h = water depth Sf = friction slope
Advection Dispersion, estimated by diffusion approach Standard deviation A-D approach: effect of dispersion/diffusion
1 tracer model 2 3 4 5 0 50 100 150 200 250 300 350 400 450 Time (minutes) A-D approach: dispersion in a river Boeije (1999)
Peclet number A-D approach: reactor approximation (i) Normalisation by length L of reactor Pe large Advection dominant plug flow behaviour Pe small Diffusion dominant CSTR behaviour small < Pe < large CSTR cascade or A-D approach
A-D approach: reactor approximation (ii) Relation of turbulence/dispersion and standard deviation Simplification for Pe > 100 (applies to conditions in sewers and rivers) CSTR approximation, „hydrologic model“ Turbulence can be estimated from RTD (i.e. )