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Lesson 8. Flexible Packaging Laminates. 第 8 课 软包装复合材料. Contents:. Laminates Aluminum Foil Vacuum Metallizing Other Inorganic Coating Laminate Structural and Physical Properties Flexible Bags, Pouches and Sachets Sealability Barrier Properties Laminating Processes
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Lesson 8 Flexible Packaging Laminates 第8课 软包装复合材料
Contents: • Laminates • Aluminum Foil • Vacuum Metallizing • Other Inorganic Coating • Laminate Structural and Physical Properties • Flexible Bags, Pouches and Sachets • Sealability • Barrier Properties • Laminating Processes • Specifying Laminates • Examples of Laminates
Three-layer Extrusion Blow Mold Cut-away view film bubble material 1 material 2 material 3
Aluminum Foil Household foil is typically 17.5 mm (0.0007 inches) Available in gauges as low as 7 mm (0.00028 inches) Pin holing is present below 12 mm (0.0005 inches) Foil is susceptible to flex cracking Most foils are supported with plastic and/or paper Unsupported foil used for some lid-stock & tablet push-through packaging
Aluminum Foil Characteristics Intact foil is a 100% barrier to all gases Best deadfold properties Easily punctured (tamper evidence) Reflective of radiant heat Conductive (induction sealing) Decorative appeal: all reflective metallics are aluminum
Foil Packaging Applications Unsupported foil, non-sealable e.g. confection and cheese wraps Unsupported foil, heat sealable e.g. lidding stock, pharmaceutical tablet backing material Supported foil, non heat sealable e.g. decorative wraps, label stock Supported foil, heat sealable e.g. high barrier pouches and sachets lidding stock, retort pouches
Aluminum Metallized Film Provides reflective metallic appearance Improves moisture, aroma, light and oxygen barrier Oxygen barrier improved: up to fifty times for OPP, up to ten times for PET Static dissipative applications OPP, PET, & PA (nylon) most common packaging films
Why Laminate? Laminate: A product made by bonding together two or more materials There is no perfect, universal packaging material Laminates assemble materials with individually desirable properties to create an optimum material
Laminate Properties Mechanical properties tensile strength stiffness coefficient of friction use temperatures elongation formability Barrier properties as required oxygen barrier essential oil barrier water vapor barrier light barrier
Laminate Properties Sealability most flexible packaging is heat sealed most heat seals are polyethylene based other polymers used more critical applications Aesthetic appearance clarity surface gloss reflective metallics
Describing Packaging Laminate Note: Packaging laminate plies are always listed from the outside to the inside
Solventless Laminating Solventless laminating uses catalyzed or or two-part reactive adhesives
Hot Tack The bond strength of the seal while still hot Critical for most form-fill-seal machines Determines how quickly product can be dropped into a pouch
Common Heat- Seal Materials ionomer (e.g. Surlyn, seals through contaminants ) acid copolymer (good foil bond, chemical resistance) metallocene polyethylene (low temp, fast seal) LLDPE (good hot tack, tough, wide seal temp.) PE/EVA (soft film, low seal temperature) medium-density polyethylene (stiffer, better barrier) cast polypropylene (stands higher temperatures) low-density polyethylene cost bond quality
Example Laminations polyethylene poly(ethylene terephthalate) printed paper foil foil sealing medium sealing medium Retort pouch Aseptic box printed polypropylene saran-coated nylon metallized polypropylene sealing medium sealing medium (Surlyn) Snack food bag Luncheon meat tray
overlacquer printed foil polyethylene poly(ethylene terephthalate) sealing medium (vinyl) Single-service lidding stock Example Laminations printed polyethylene surface print Ethylene-vinyl alcohol paper polyethylene polyethylene High oxygen barrier foil sealing medium Basic food pouch laminate (For barrier applications foil to the inside)
Clear LDPE Printed white PE paper EAA Foil Sealing medium Laminated Collapsible Tube Construction Finished tube1 Injected molded tip Formed body High barrier insert Laminate roll stock
Vertical Form-Fill-Seal (VFFS) CoF is critical!
VFFS Pouch Seals Compared Fin seal Lap Seal Seals inside surfaces Uses more material Don’t cover UPC! Seals outside to inside Both surfaces need sealing medium Use less material
Three-side sealed pouch Gusseted designs Common HFFS Pouch Styles Conventional pouch has three-side seal Can be made into various stand-up designs Some stand-up pouches are pre-made in a separate operation
Film Thickness Measurement Inch Gauge Mil Micrometre 0.001inch = 100 gauge = 1 mil = 25 mm 0.0005 inch = 50 gauge = 1/2 mil = 13 mm ISO metric notes: “Micron” is a depreciated term for micrometre one inch = 25.4 millimetres and 0.001 inch = 25.4 micrometres
Early Universal Barriers PVDC is original high universal barrier polymers EVOH laminated between high moisture barrier polymers can also provide good universal barrier But not high enough barrier for critical applications Metallizing also produces a high universal barrier But aluminum metallized films are not transparent
Recent Advances in Achieving Barrier Monolayer polymers poly(ethylene naphthalate) ($) liquid crystal polymer ($$$) Multilayered constructions PET/PA/PET PET/EVOH/PET PET/MXD6/PET/ MXD6/PET
Recent Advances in Achieving Barrier Interior coatings SiOx (glass) coating (Glaskin) AlOx aluminum oxide coating carbon coating (DLC and Actis) Exterior coatings and interior laminates epoxy-amine coating (Sealica and Bairocade) copolyester (Amosorb: interior layer) Nanocomposites extremely fine mineral additions