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Lewis Structures electron dot structures for molecules. 5 rules for Lewis Structures Find the total # of valence electrons for the molecule Find the center atom (the element with the least # of atoms)
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5 rules for Lewis Structures Find the total # of valence electrons for the molecule Find the center atom (the element with the least # of atoms) Draw bonds. Connect the other atoms to the center atom. Then subtract 2 electrons from the total # of valence electrons for each bond drawn. ( when we do an example this will become clear)
5 rules for Lewis Structures Distribute electrons around each atom to give a total of 8 electrons except H, Al, B, & Be If there are not enough electrons to give 8 around each atom, create double & triple bonds.
Example 1:CF4 1. Total valence electrons = C + F 4 + 4(7) = 32 valence electrons 2. Center atom (least # of atoms) = C write C in the middle draw bonds (lines) to connect four F atoms F F C F F 3. Subtract 2 times (# of bonds)- each bond uses 2 electrons 32 – 2(4) = 24 electrons 24 electrons left to distribute around the F atoms one line means 2 electrons
4. Distribute left over 24 electrons to F F F — C — F F C needs no electrons because it has 4 bonds (octet) Now each F has 8 electrons around it (octet) This is the Lewis structure of CF4 It shows how many bonds and where e- are located Lone pairs of e- not involved in bonding
Example 2: NH3 5 + 3(1) = 8 electrons H can have 2 e- (H is one of the exceptions) 8 – 2(3 bonds) = 2 electrons left for N H H N H
Example 3: H2S 2(1) + 6 = 8 electrons H can have 2 e- (H is one of the exceptions) 8 – 2(2 bonds) = 4 electrons left for S H H S
Ions • With Ions we add or take away electrons Example 4: PO43- Gained 3e- 5 + 4(6) + 3 = 32 electrons 32-2(4 bonds) = 24 electrons to distribute • Put ions in brackets and the charge on the outside 3- O O O P O
Double Bonds Example 5: CO2 - What’s wrong with Carbon? Carbon does not have 8 electrons, so electrons will bond differently O – C – O Now carbon and oxygen have 8 electrons O – C – O “Double Bond”
Incomplete Octet Example 6: BCl3 3 + 3(7) = 24 electrons 24 – 2(3 bonds) = 18 electrons left for Cl Boron does not have 8e- around it. It is incomplete but it is okay; it is one of our exceptions. Cl Cl B Cl
Triple Bond Example 8: CO 4 + 6 = 10 electrons 10 – 2(1 bond) = 8 electrons left for C or O If we try putting 4 electrons on C and 4 on O, then they will each only have 6 electrons. Try doubling or tripling the bonds if you do not have an octet. C – O