What is the law of conservation of mass?

1. Burning is a chemical change. When a substance undergoes a chemical change, a chemical reaction is said to take place.

2. Chemical Equations What is the law of conservation of mass? The law of conservation of mass states that mass is neither created nor destroyed in a chemical reaction.

3. Chemical Equations A useful description of a chemical reaction tells you the substances present before and after the reaction. • The substances that undergo change are called reactants. • The new substances formed as a result of that change are called products.

4. Chemical Equations Using Equations to Represent Reactions During a chemical reaction, the reactants change into products. You can summarize this process with a word equation.Reactants  Products

5. Chemical Equations To describe the burning of charcoal, you can write reactants and products of the reaction in the following word equation. Carbon +Oxygen  Carbon dioxide Write the reactants and products as chemical formulas. C +O2CO2

6. Chemical Equations A chemical equation is a representation of a chemical reaction in which the reactants and products are expressed as formulas. You can read the equation C +O2CO2 as • “ Carbon and oxygen react and form carbon dioxide,” or, • “The reaction of carbon and oxygen yields carbon dioxide.”

7. Chemical Equations Conservation of Mass During chemical reactions, the mass of the products is always equal to the mass of the reactants. This principle is the law of conservation of mass. When charcoal burns, the mass of the carbon dioxide produced is equal to the mass of the charcoal and oxygen that reacted.

8. Chemical Equations Whether you burn one carbon atom or six carbon atoms, the equation used to describe the reaction is always the same.

9. Chemical Equations Whether you burn one carbon atom or six carbon atoms, the equation used to describe the reaction is always the same.

10. Balancing Equations Why must chemical equations be balanced? In order to show that mass is conserved during a reaction, a chemical equation must be balanced.

11. Balancing Equations You can balance a chemical equation by changing the coefficients, the numbers that appear before the formulas. When you change a coefficient, you change the amount of that reactant or product represented in the chemical equation.

12. Balancing Equations

13. Balancing Equations

14. Balancing Equations Balancing Chemical Equations Write a balanced equation for the reaction between copper and oxygen to produce copper(II) oxide, CuO.

15. Balancing Equations Read and Understand What information are you given? Reactants: Cu, O2 Product: CuO

16. Balancing Equations Plan and Solve Write a chemical equation with the reactants on the left side and the product on the right. Cu + O2 CuO

17. Balancing Equations Cu + O2 CuO This equation is not balanced. Change the coefficient of CuO in order to balance the number of oxygen atoms.

18. Balancing Equations Cu + O2 CuO This equation is not balanced. Change the coefficient of CuO in order to balance the number of oxygen atoms. Cu + O2 2CuO

19. Balancing Equations Cu + O2 CuO This equation is not balanced. Change the coefficient of CuO in order to balance the number of oxygen atoms. Cu + O2 2CuO Change the coefficient of Cu in order to balance the number of copper atoms.

20. Balancing Equations Cu + O2 CuO This equation is not balanced. Change the coefficient of CuO in order to balance the number of oxygen atoms. Cu + O2 2CuO Change the coefficient of Cu in order to balance the number of copper atoms. 2Cu + O2 2CuO

21. Describing Ionic Compounds 1. Hydrogen chloride, or HCl, is an important industrial chemical. Write a balanced equation for the production of hydrogen chloride from hydrogen and chlorine. Answer: H2 + Cl2 2HCl

22. Describing Ionic Compounds 2. Balance the following chemical equations. a. H2O2H2O + O2 b. Mg +HCl H2 +MgCl2

23. Describing Ionic Compounds 2. Balance the following chemical equations. a. H2O2H2O + O2 b. Mg +HCl H2 +MgCl2 Answer: a. 2H2O2 2H2O + O2 b. Mg + 2HCl H2 +MgCl2

24. Describing Ionic Compounds 3. Ethylene, C2H4, burns in the presence of oxygen to produce carbon dioxide and water vapor. Write a balanced equation for this reaction.

25. Describing Ionic Compounds 3. Ethylene, C2H4, burns in the presence of oxygen to produce carbon dioxide and water vapor. Write a balanced equation for this reaction. Answer: C2H4 + 3O2 2CO2 + 2 H2O

26. Counting With Moles Why do chemists use the mole? Because chemical reactions often involve large numbers of small particles, chemists use a counting unit called the mole to measure amounts of a substance. A mole (mol) is an amount of a substance that contains approximately 6.02 × 1023 particles. For instance, a mole of iron is 6.02 × 1023 atoms of iron. This number is known as Avogadro’s number.

27. Counting With Moles You might count shoes by the pair, eggs by the dozen, or paper by the ream (500 sheets). To count particles of a substance, chemists use the mole (6.02 × 1023 particles).

28. Counting With Moles Molar Mass The mass of one mole of a substance is called a molar mass. For an element, the molar mass is the same as its atomic mass expressed in grams. • The molar mass of carbon is 12.0 grams. • The molar mass of sulfur is 32.1 grams.

29. Counting With Moles You calculate the molar mass of a compound by adding up the atomic masses of its component atoms and then expressing this sum in grams. • A carbon dioxide molecule is composed of one carbon atom (12.0 amu) and two oxygen atoms (2 ×16.0 amu =32.0 amu). • Carbon dioxide has a molar mass of 44.0 grams.

30. Counting With Moles Mole-Mass Conversions Once you know the molar mass of a substance, you can convert moles of that substance into mass, or a mass of that substance into moles. The molar mass of CO2 is 44.0 grams, which means that one mole of CO2 has a mass of 44.0 grams. This relationship yields the following conversion factors.

31. Counting With Moles Suppose you have 55.0 grams of CO2. To calculate how many moles of CO2 you have, multiply the mass by a conversion factor. You can check your answer.

32. Chemical Calculations How can you calculate the mass of a reactant or product in a chemical reaction? In chemical reactions, the mass of a reactant or product can be calculated by using a balanced chemical equation and molar masses of the reactants and products.

33. Chemical Calculations A cake recipe tells you how much of each ingredient to use for each cake.Chemical equations can be read as recipes for making new substances.

34. Chemical Calculations In a balanced chemical equation, the number of atoms of each element on the left equals the number of atoms of each element on the right.

35. Chemical Calculations In a balanced chemical equation, the number of atoms of each element on the left equals the number of atoms of each element on the right.

36. Chemical Calculations In a balanced chemical equation, the number of atoms of each element on the left equals the number of atoms of each element on the right.

37. Chemical Calculations In a balanced chemical equation, the number of atoms of each element on the left equals the number of atoms of each element on the right.

38. Chemical Calculations Converting Mass to Moles To calculate how much oxygen is required to make 144 grams of water, begin with a balanced chemical equation for the reaction. 2H2 +O22H2O • Determine how many moles of water you are trying to make. • Convert the given mass of water into moles.

39. Chemical Calculations Using Mole Ratios • Write the conversion factors, or mole ratios. • Calculate how many moles of oxygen are required to produce eight moles of water.

40. Chemical Calculations Converting Moles to Mass • Convert moles of O2 to grams of O2 by using the molar mass of O2 as a conversion factor. • To produce 144 grams of H2O, you must supply 128 grams of O2.

41. Assessment Questions • Which of the following is a balanced chemical equation for the reaction of aluminium and ammonium perchlorate? • Al + NH4ClO4 —› Al2O3 + NH4Cl • 4Al + 3NH4ClO4 —› 4Al2O3 + 3NH4Cl • 8Al + NH4ClO4 —› 4Al2O3 + NH4Cl • 8Al + 3NH4ClO4 —› 4Al2O3 + 3NH4Cl

42. Assessment Questions • Which of the following is a balanced chemical equation for the reaction of aluminium and ammonium perchlorate? • Al + NH4ClO4 —› Al2O3 + NH4Cl • 4Al + 3NH4ClO4 —› 4Al2O3 + 3NH4Cl • 8Al + NH4ClO4 —› 4Al2O3 + NH4Cl • 8Al + 3NH4ClO4 —› 4Al2O3 + 3NH4ClANS: D

43. Assessment Questions • How many moles of NaCl (molar mass = 58.5) are there in a 10-gram sample? • 58 mol • 5.8 mol • 0.17 mol • 0.28 mol

44. Assessment Questions • How many moles of NaCl (molar mass = 58.5) are there in a 10-gram sample? • 58 mol • 5.8 mol • 0.17 mol • 0.28 molANS: C

45. Assessment Questions • In the reaction shown below, how many grams of hydrogen are produced when 10 moles of potassium react with water?2K + 2H2O —› 2KOH + H2 • 2.5 g • 5 g • 10 g • 20 g

46. Assessment Questions • In the reaction shown below, how many grams of hydrogen are produced when 10 moles of potassium react with water?2K + 2H2O —› 2KOH + H2 • 2.5 g • 5 g • 10 g • 20 gANS: C

47. Assessment Questions • In the chemical equation below, the reactants are carbon dioxide and water.CH4 + 2O2 —› CO2 +2H2OTrueFalse

48. Assessment Questions • In the chemical equation below, the reactants are carbon dioxide and water.CH4 + 2O2 —› CO2 +2H2OTrueFalse ANS: F, products