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Unique additive information measures – Boltzmann-Gibbs-Shannon, Fisher and beyond

Unique additive information measures – Boltzmann-Gibbs-Shannon, Fisher and beyond. Peter Ván BME, Department of Chemical Physics Thermodynamic Research Group Hungary. Introduction – the observation of Jaynes Weakly nonlocal additive information measures Dynamics – quantum mechanics

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Unique additive information measures – Boltzmann-Gibbs-Shannon, Fisher and beyond

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  1. Unique additive information measures – Boltzmann-Gibbs-Shannon, Fisher and beyond Peter Ván BME, Department of Chemical Physics Thermodynamic Research Group Hungary • Introduction – the observation of Jaynes • Weakly nonlocal additive information measures • Dynamics – quantum mechanics • Power law tails • Microcanonical and canonical equilibrium distributions • Conclusions

  2. 1 Entropy in local statistical physics (information theoretical, predictive, bayesian) (Jaynes, 1957): The measure of information is unique under general physical conditions. (Shannon, 1948; Rényi, 1963) • Extensivity (density) • Additivity (unique solution)

  3. The importance of being unique: Robustness and stability: link to thermodynamics. • Why thermodynamics? • thermodynamics is not the theory of temperature • thermodynamics is not a generalized energetics • thermodynamics is a theory of STABILITY • (in contemporary nonequilibrium thermodynamics) • The most general well-posedness theorems use explicite thermodynamic methods • (generalizations of Lax idea) • The best numerical FEM programs offer an explicite thermodynamic structure • (balances, etc…) Link to statistical physics: universality (e.g. fluid dynamics)

  4. 2 Entropy in weakly nonlocal statistical physics (estimation theoretical, Fisher based) (Fisher, …., Frieden, Plastino, Hall, Reginatto, Garbaczewski, …): • Extensivity • Additivity • Isotropy

  5. (unique solution) Boltzmann-Gibbs-Shannon Fisher There is no estimation theory behind!

  6. What about higher order derivatives? • What is the physics behind the second term? What could be the value of k1? • What is the physics behind the combination of the two terms? Dimension dependence Dynamics - quantum systems Equilibrium distributions with power law tails

  7. Second order weakly nonlocal information measures • Extensivity • Additivity • Isotropy in 3D

  8. (unique solution) Depends on the dimension of the phase space.

  9. 3 Quantum systems – the meaning of k1 probability distribution Fisher Boltzmann-Gibbs-Shannon • Mass-scale invariance (particle interpretation)

  10. Why quantum? A Time independent Schrödinger equation B Probability conservation Momentum conservation + Second Law (entropy inequality) Equations of Korteweg fluids with a potential

  11. (Fisher entropy) Schrödinger-Madelung fluid Bernoulli equation Schrödinger equation

  12. Logarithmic and Fisher together? Nonlinear Schrödinger eqaution of Bialynicki-Birula and Mycielski (1976) (additivity is preserved): Stationary equation for the wave function: Existence of non dispersive free solutions – solutions with finite support - Gaussons

  13. 4 MaxEnt calculations – the interaction of the two terms (1D ideal gas)

  14. symmetry There is no analitic solution in general There is no partition function formalism Numerical normalization One free parameter: Js

  15. Conclusions • Corrections to equilibrium (?) distributions • Corrections to equations of motion • Unique = universal • Independence of micro details • General principles in background Thermodynamics Statistical physics Information theory?

  16. Concavity properties and stability: Positive definite If k is zero (pure Fisher): positive semidefinite!

  17. One component weakly nonlocal fluid basic state constitutive state constitutive functions Liu procedure (Farkas’s lemma):

  18. reversible pressure Potential form: Euler-Lagrange form Variational origin

  19. (Fisher entropy) Schrödinger-Madelung fluid Bernoulli equation Schrödinger equation

  20. Alternate fluid Korteweg fluids:

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