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Berry Phase Phenomena Optical Hall effect and Ferroelectricity as quantum charge pumping. Naoto Nagaosa CREST, Dept. Applied Physics, The University of Tokyo. M. Onoda, S. Murakami, and N. Nagaosa, Phys. Rev. Lett. 93, 083901 (2004).
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Berry Phase PhenomenaOptical Hall effect and Ferroelectricity as quantum charge pumping Naoto Nagaosa CREST, Dept. Applied Physics, The University of Tokyo M. Onoda, S. Murakami, and N. Nagaosa, Phys. Rev. Lett. 93, 083901 (2004) S. Onoda, S. Murakami, and N. Nagaosa, Phys. Rev. Lett. 93, 167602 (2004)
Berry phaseM.V.Berry, Proc. R.Soc. Lond. A392, 45(1984) Hamiltonian, parametersadiabatic change eigenvalue and eigenstate for each parameter set X • Transitions between eigenstates are forbidden • during the adiabatic change • Projection to the sub-space of Hilbert space constrained quantum system Berry Phase Connection of the wavefunction in the parameter spaceBerry phase curvature
Electrons with ”constraint” doublydegeneratepositive energy states. Projection onto positive energy state Spin-orbit interaction asSU(2) gauge connection Dirac electrons Bloch electrons Projection onto each band Berry phase of Bloch wavefunction Spin Hall Effect (S.C.Zhang’s talk) Anomalous Hall Effect (Haldane’s talk)
Berry Phase Curvature in k-space Bloch wavefucntion Berry phase connection in k-space covariant derivative Curvature in k-space Anomalous Velocity and Anomalous Hall Effect Non-commutative Q.M.
Duality between Real and Momentum Spaces k- space curvature r- space curvature
SrRuO3 Z.Fang Degeneracy point Monopole in momentum space
Fermat’s principle and principle of least action Goal Path 5 Path 4 Path 3 Path 2 Start Path 1 Every path has a specific optical path length or action. Fermat:stationary optical path length → actual trajectoryLeast action : stationary action → actual trajectory Searching stationary value ~ Solving equations of motion
Trajectories of light and particle What determine the equations of motion?Historically,experiments and observationsAny fundamental principles?(Fermat’s principle, principle of least action)
Geometrical phase (Berry phase) Principle of least actionPhase factor → Equations of motion Berry phase“Wave functions with spin obtain geometrical phase in adiabatic motion.” Although light has spin, no effect of Berry phase in conventional geometrical optics. Topological effects (wave optics)in trajectory of light (geometrical optics)→ wave packet
Effective Lagrangian of wave packet R. Jackiw and A. Kerman,Phys. Lett. 71A, 581 (1979) A. Pattanayak and W.C. Schieve, Phys. Rev. E 50, 3601 (1994)
Equations of motion of optical packet Anomalous velocity Neglecting polarization→ Conventional geometrical optics
Berry Phase in Optics Propagation of light and rotation of polarization plane in the helical optical fiber Chiao-Wu, Tomita-Chiao, Haldane, Berry Spin 1 Berry phase
Reflection and refraction at an interface Shift perpendicular to both of incident axis and gradient of refractive index No polarization Circularly polarized
Conservation law of angular momentum EOM are derived under the condition of weak inhomogeneity.Application to the case with a sharp interface? Conservation of total angular momentum as a photon
Comparison with numerical simulation V0: light speed in lower mediumV1: light speed in upper mediumSolid and broken lines are derived by the conservation law.●and ■ are obtained by numerically solving Maxwell equations.
Photonic crystal and Berry phase Shift in reflection and refractionSmall Berry curvature→small shift of the order of wave length Knowledge about electrons in solidsPeriodic structure without a symmetry→Bloch wave with Berry phase Photonic crystal without a symmetry → Bloch wave of light with Berry phaseEnhancement of optical Hall effect ?! Example of 2D photonic crystal without inversion symmetry
Wave in periodic structure -- Bloch wave -- Bloch waveAn intermediate between traveling wave and standing wave Energy Meaning of the height of periodic structureElectron : electrical potentialLight : (phase) velocity of lightFor low energy Bloch waveLarge amplitude at low pointSmall amplitude at high point Strength of periodic structure Wave packet of Bloch wave (right Fig.)Red line= periodic structure + constant incline http://ppprs1.phy.tu-dresden.de/~rosam/kurzzeit/main/bloch/bo_sub.html
Dielectric function and photonic band We shall consider wave ribbons with kz=0.Note: Eigenmodes with kz=0 are classified into TE or TM mode.
Berry curvature of optical Bloch wave For simplicity, we consider the case in which the spin degeneracy is resolved due to periodic structure.
Berry curvature in photonic crystal Berry curvature is large at the region whereseparation between adjacent bands is small. c.f. Haldane-Raghu Edge mode
Trajectory of wave packet in photonic crystal Superimposed modulation around x = 0 instead of a boundaryNote:The figure is the top view of 2D photonic crystal. Periodic structure is not shown. Large shift of several dozens of lattice constant
classical theory of polarization Averaged polarization at r Charge determines pol. Ionicity is needed !! Polarization of a unit cell R + polarization due to displacements of rigid ions Ionic polarization • It is not well-defined in general. • It depends on the choice of a unit cell. • It is not a bulk polarization.
quantum theory of polarization Covalent ferroelectric: polarization without ionicity “r” is ill-defined for extended Bloch wavefunction P is given by the amount of the charge transfer due to the displacement of the atoms Integral of the polarization current along the path C determines P P is path dependent in general !!
Ferroelectricity in Hydrogen Bonded Supermolecular Chain S.Horiuchi et al 2004 Polarization is “huge” compared with the classical estimate Neutraland covalent
Ferroelectricity in Phz-H2ca S. Horiuchi @ CERC et al. With F. Ishii @ERATO-SSS First-principles calculation Isolated molecule → 0.1 μC/cm2 (too small !) Hydrogen bond ( covalency) Polarization as a Berry phase Bulk Isolated molecule Large polarizationwith covalency
Geometrical meaning of polarization in 1D two-band model dP : Solid angle of the ribon Generalized Born charge
Strings as trajectories of band-crossing points flux density: • only along strings (trajectories of band-crossing points)with k in [-p/a,p/a] d-function singularity along strings (monopoles in k space) 2. Divergence-free 3. Total flux of the string is quantized to be an integer (Pontryagin index, or wrapping number):[c.f. Thouless] C×[-p/a,p/a] B C Band-crossing point
Biot-Savart law, asymptotic behavior & charge pumping Transverse part of the polarization current A Biot-Savart law: L : strings string Asymptotic behavior (leading order in 1/Eg) Strength ~ 1/Eg Direction: same as a magnetic field created by an electric current Eg Quantum charge pumping due to cyclic change of Q around a string ne
Specific models Simplest physically relevant models Different choices of fand g Geometricallydifferent structures of strings B and polarization current A
Quantum Charge Pumping in Insulator or Pressure Electron(charge)flow Large polarization even in the neutral molecules
Dimerized charge-ordered systems TTF-CA (TMTTF)2PF6 (DI-DCNQI)2Ag TTF-CA: polarization perpendicular to displacement of molecules. D2 triggers the ferroelectricity.
Conclusions ・Generalized equation of motion for geometrical optics taking into account the Berry phase assoiciated with the polarization ・Optical Hall Effect and its enhancement in photonic crystal ・Covalent (quantum) ferroelectricity is due to Berry phase and associated dissipationless current ・Geometrical view for P in the parameter space - non-locality and Biot-Savart law ・Possible charge pumping and D.C. current in insulator Ferroelectricity is analogous to the quantum Hall effect
Motivation of this study Goal : dissipationless functionality of electrons in solidsKey concept : topological effects of wave phenomena of electrons Example of our studyTopological interpretation of quantization in quantum Hall effect↓Intrinsic anomalous Hall effect and spin Hall effect due to the geometrical phase of wave function What is corresponding phenomena in optics? Geometrical optics : simple and useful for designing optical devices Wave optics : complicated but capable of describing specific phenomena for wave Topological effects of wave phenomena Photonic crystals as media with eccentric refractive indices → Extended geometrical optics
Polarization and Angular momentum Rotation and angular momentum Rotation of center of gravity Rotation around center of gravity http://www.expocenter.or.jp/shiori/ ugoki/ugoki1/ugoki1.html Polarization and spin Linear S = 0 Right circular S = +1 Left circular S = -1 http://www.physics.gla.ac.uk/Optics/projects/singlePhotonOAM/
Action and quantum mechanics Quantum mechanics“Wave-particle duality”“Everything is described by a wave function.”“Action in classical mechanics ~ phase factor of wave function”Searching a trajectory of classical particle~ Solving a wave function approximately Similar relation holds between geometrical and wave optics.
“Wave and geometrical optics”, “Quantum and classical mechanics” Wave optics → Eikonal → Fermat’s principle → Geometrical optics Optical path, Action ~ Phase factor Quantum mechanics → Path integral → Principle of least action → Classical mechanics Roughly speaking,Trajectory is determined by the phase factor of a wave function.
Hall effect of 2DES in periodic potential M.-C. Chang and Q. Niu, Phys. Rev. B 53, 7010 (1996)
Optical path length and action Light in media with inhomogeneous refractive indexOptical path length= Sum of (refractive index x infinitesimal length) along a trajectory= Time from start to goalLight speed = 1/(refractive index)Time for infinitesimal length = (infinitesimal length) / (light speed) Particle in inhomogeneous potentialAction= Sum of (kinetic energy – potential) x (infinitesimal time) along a trajectory PointOptical path lengthandactioncan be defined for any trajectories,regardless of whether realistic or unrealistic.
Why is it interpreted as the optical Hall effect ? Transverse shift of light in reflection and refraction at an interfaceThe shift is originated by the anomalous velocity.(Light will turn in the case of moderate gradient of refractive index.) Hall effect of electronsClassical HE :Lorentz forceQHE :anomalous velocity (Berry phase effect)Intrinsic AHE :anomalous velocity (Berry phase effect)Intrinsic spin HE :anomalous velocity (Berry phase effect)[Spin HE by Murakami, Nagaosa, Zhang, Science 301, 1378 (2003)] QHE, AHE, spin HE ~ optical HENOTE: spin is not indispensable in QHE
Earlier Studies 1. Suggestion of lateral shift in total reflection (energy flux of evanescent light) F. I. Fedorov, Dokl. Akad. Nauk SSSR 105, 465 (1955) 2. Theory of total and partial reflection (stationary phase) H. Schilling, Ann. Physik (Leipzig) 16, 122 (1965) 3. Theory and experiment of total reflection (energy flux of evanescent light ) C. Imbert, Phys. Rev. D 5, 787 (1972) 4. Different opinions D. G. Boulware, Phys. Rev. D 7, 2375 (1973) N. Ashby and S. C. Miller Jr., Phys. Rev. D 7, 2383 (1973) V. G. Fedoseev, Opt. Spektrosk. 58, 491 (1985) Ref. 1 and 3 explain the transverse shift in analogy with Goos-Hanchen effect (due to evanescent light). However, Ref.2 says that the transverse shift can be observed in partial reflection.
Summary • Topological effects in wave phenomena of electrons → What are the corresponding phenomena of light? • Equations of motion of optical packet with internal rotation • Deflection of light due to anomalous velocity • QHE, Intrinsic AHE, Intrinsic spin HE ~ Optical HE • Photonic crystal without inversion symmetry → Optical Bloch wave with Berry curvature (internal rotation) • Enhancement and control of optical HE in photonic crystals
Future prospects and challenges • Tunable photonic crystal → optical switch? • Transverse shift in multilayer film → precise measurement • Optical Hall effect of packet with internal OAM (Sasada) • Localization in photonic band with Berry phase • Surface mode of photonic crystal and Berry curvature • Magnetic photonic crystal → Chiral edge state of light (Haldane) • Effect of absorption (relation with Rikken-van Tiggelen effect) • Quasi-photonic crystal (rotational symmetry) → rotation → Berry phase? (Sawada et al.) • Phononic crystal → sonic Hall effect
Internal Angular momentum of light Spin angular momentum Linear S=0 Right circular S=1 Left circular S=-1 Orbital angular momentum L=0 L=1 L=2 L=3 http://www.physics.gla.ac.uk/Optics/projects/singlePhotonOAM/ The above OAM is interpreted as internal angular momentum when optical packets are considered.More generally, Berry phase → internal rotation ?
Rotation of optical packet Non-zero Berry curvature ~ Rotation Periodic structure without inversion→ rotating wave packet
Molecular orbitals(extended Huckel) Transfer integral t is estimated by t = ES, E~10eV( S: overlap integral)
Transfer integrals along the stacking direction(b-axis) -2.2 (x10-3) Phz stack LUMO -1.4 1.5 HOMO -5.2 H2ca stack LUMO 2.7 -4.9 5.5 HOMO -1.6
Polarization is “huge” compared with the classical estimate neutral
Wave packet Image of wave : we cannot distinguish where it is.Image of particle: we can distinguish where it is.Wave packet : well-defined position of center + broadening. Wave packet (Green) in potential (Red) http://mamacass.ucsd.edu/people/pblanco/physics2d/lectures.html