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Self-healing materials. Multidisciplinary project group 2. Self-healing materials. Introduction Concepts : Encapsulated healing agent Remendable cross-links Interdiffusion Biomimetic approach Opportunities How to continue. Introduction.
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Self-healing materials Multidisciplinary project group 2
Self-healing materials • Introduction • Concepts: • Encapsulated healing agent • Remendable cross-links • Interdiffusion • Biomimetic approach • Opportunities • How to continue
Introduction • Is it feasible to create a self-healing material? • Application?
Self-healing materials • Introduction • Concepts: • Encapsulated healing agent • Remendable cross-links • Interdiffusion • Biomimetic approach • Opportunities • How to continue
Concepts: Encapsulation Autonomic healing After reaction it is over
Concepts: Remendable cross-links • Diels Alder • U-py • Metal Complex • Combinations
Concepts: Remendable cross-links • Diels Alder • U-py • Metal Complex • Combinations
Concepts: Remendable cross-links • Diels Alder • U-py • Metal Complex • Combinations
Concepts: Remendable cross-links • Diels Alder • U-py • Metal Complex • Combinations • Multiple healing • Possibilities Not autonomically
Concepts: Interdiffusion Only amorphous polymer Competition between interdiffusion and crosslink Very slow
Biomimetic approach Autonomic healing It’s over when fibre breaks
Biomimetic approach Controlled release of growth-factors Hydrogel instead of microcapsules Site specific How to detect a crack?
Self-healing materials • Introduction • Concepts: • Encapsulated healing agent • Remendable cross-links • Interdiffusion • Biomimetic approach • Opportunities • How to continue
Opportunities • Microcapsules: finetuning • Interdiffusion: Low Tg Polymers • Biomimetic: Unbreakable porous hollow fibres. • Remendable Crosslinks: Dye a U-py
Self-healing materials • Introduction • Concepts: • Encapsulated healing agent • Remendable cross-links • Interdiffusion • Biomimetic approach • Opportunities • How to continue
Focus: • Cross-links with dyes • Detection systems
Why Dye? • Present research: a fluorescent dye on U-py • Our idea: Energy dissipating dye! • Also possible for Diels-Alder crosslinks
Detection Microcapsules detect – repair – capsule broken Crosslinks repair – repair again Weakest point multiple-healing-systems: no detection