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Properties of Water Topics covered in this lecture can be found in Chapters 6 and 7. Most of Earth’s water is in the oceans and seas. True False. 20. PLANET WATER. 70.8% OF EARTH IS COVERED BY WATER 97% in SW of oceans and seas 2% FW Lakes and rivers 1% snow and ice as glaciers
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Properties of Water Topics covered in this lecture can be found in Chapters 6 and 7
Most of Earth’s water is in the oceans and seas. • True • False 20
PLANET WATER • 70.8% OF EARTH IS COVERED BY WATER • 97% in SW of oceans and seas • 2% FW Lakes and rivers • 1% snow and ice as glaciers • 0.00057% - atmospheric water.
An ion is an atom or molecule where the total number of electrons is not equal to the total number of protons, giving it a net positive or negative electrical charge.
Types of Bonds Ionic – electrons are gained or lost Covalent – electrons are shared Hydrogen – intermolecular bond of H w/ an electronegative atom.
Figure A4.4 NaCl Sodium Chloride Na+ Cl-
Electron (–1 unit of charge) Nucleus (+1 unit of charge) Two hydrogen atoms... share their electrons with one oxygen atom... to form a water molecule held together by covalent bonds... which acts as if it has negative and positive ends. 105° 2 –
The Water Molecule Dipole or a polar molecule
Remember….. Weaker Hydrogen Bonds form BETWEEN water molecules…… Stronger Covalent Bonds form WITHIN water molecules……
Cohesion Makes the beading H Bonds are responsible for water molecules “sticking” together…..
Adhesion Makes the beads stay in place H Bonds are responsible for water molecules “stick” or “adhere” to solids…..
Matter exists as Liquid, Solid and Gas……. To change it from one form to another one must… Add or remove HEAT!
Is there a difference between temperature & heat? • Yes • No 25
Is there a difference between heat and temperature? YES! Heat– energy produced by the random vibration of atoms or molecules. Heat measures how many molecules are vibrating and how rapidly… Temperatureobject’s response to input or removal of heat
Calorie – the amount of heat required to raise temperature of one gram of water by 1°C
Heat Capacity – is the amount of heat required to raise the temperature of a substance by 1 degree centigrade. High heat capacity – then the substance can absorb or lose large quantities of heat with only a small change in temperature.
Latent Heat Quantity of heat gained or lost per unit of mass as a substance undergoes a change of state. Sweating cools you…… HOT STEAM – can burn!
Surface Water Moderates Global Temperature • Thermostatic properties – act to moderate temperature changes • Thermal inertia – tendency to resist change in temperature • Annual freeze/thaw of ice moderates Earth’s temperature • More than 18,000 cubic kilometers of ice thaws and refreezes in the Southern Hemisphere each year
Ocean Is Stratified by Density • Three zones • Surface zone / mixed layer • Pycnocline • Deep zone
“Day after day, day after day, We stuck, nor breath nor motion; As idle as a painted ship Upon a painted ocean. Water, water, everywhere, And all the boards did shrink; Water, water, everywhere, Nor any drop to drink.” - The Rime of the Ancient Mariner
Plants = 95% water jellyfish= 99% water Humans = 65% water Our blood = 83% water http://www.youtube.com/watch?v=paH97dYR6Lg
Water is the Universal Solvent - it can dissolve nearly everything!
This matters in oceanography because….. Salinity • Is the total amount of solid material dissolved in water (not including dissolved organic substances; it is the ratio of the mass of dissolved substances to the mass of the water sample. • It does not include fine particles in suspension.
Rain dissolves rocks http://brianingraham.com/wp-content/uploads/2007/08/rain.jpg
http://jerusalemperspective.com/images/Photo_Essays/sea_of_galilee/Jordan_River_entering_Sea_of_Galilee_aerial.jpghttp://jerusalemperspective.com/images/Photo_Essays/sea_of_galilee/Jordan_River_entering_Sea_of_Galilee_aerial.jpg Dissolved compounds (ions) accumulate in ocean basins
Ocean salinity based on balance between input and output of ions
We express salinity in….. • Parts per thousand • ‰ • Example: 35‰ - • is equal to 35 grams of salt in every 1000 grams of seawater.
How do we measure Salinity? Principle of Constant Proportion – The major dissolved constituents responsible for the salinity of seawater occur nearly everywhere in the ocean in exact same proportions, regardless of salinity. Salinity = 1.80655 x chlorinity (‰)