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Chapter 6

Chemical Kinetics and Reaction Mechanisms. Chapter 6. Deduction of Reaction Mechanisms. Prof. Kyoung -Ho Park. Chapter 6. Deduction of Reaction Mechanism. Key words;

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Chapter 6

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  1. Chemical Kinetics and Reaction Mechanisms Chapter 6 Deductionof Reaction Mechanisms Prof. Kyoung-Ho Park

  2. Chapter 6. Deduction of Reaction Mechanism • Key words; • The first step is to convert the concentration-time measurements to a differential rate equation that gives the rate as a function of one or more concentration. • The second step is to formulate a reaction scheme. • This chapter also considers concentration variables that do not themselves necessarily play a role in the mechanism; pH variations

  3. 6.2 Mechanistic Interpretation of Rate Laws

  4. Consider the oxidation of oxalic acid by chlorine according to the equations

  5. 6.4 Kinetically Indistinguishable Schemes

  6. 6.5 pH-Rate Profiles and Downward Bends

  7. 6.6 pH-Rate Profiles and Upward Bends

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