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13/14 Spring Semester . Petrochemical Technology (TKK-2130). Instructor: Rama Oktavian Email: rama.oktavian86@gmail.com Office Hr.: M.13-15, Tu. 13-15, W. 13-15, Th. 13-15, F. 09-11. Outlines. 1. Polymer industry. 2. Polymerization process. 3. Polypropylene.
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13/14 Spring Semester Petrochemical Technology(TKK-2130) Instructor: Rama Oktavian Email: rama.oktavian86@gmail.com • Office Hr.: M.13-15, Tu. 13-15, W. 13-15, Th. 13-15, F. 09-11
Outlines 1. Polymer industry 2. Polymerization process 3. Polypropylene 4. Recent status and technology
Polymer industry Polymer industry in Indonesia Petrochemicals are chemical products derived from petroleum and other hydrocarbon sources. Polymers are substances containing a large number of structural units joined by the same type of linkage. Polymer consists of combination of monomer
Polymer industry Polymer industry in Indonesia There are mainly six polymer product comodities • Polyethylene • Polypropylene • Polyvinyl chloride • Polyethylene terephthalate • Polystyrene • Polycarbonate
Polymer industry Polymer industry in Indonesia Amoco Mitsui PTA Ind PT Products: Purified Teraphthalic Acid Asahimas Chemical PT Products: polyvinyl chloride Chandra Asri PT Products: LLDPE, HDPE, Polypropylene Dover Chemical PT Products: Polyvenil Acetate DOW Chemical Pacific Ltd PT Products: Polysterene Mitsubishi Chemical Indonesia PT Products: PET Resin
Polymer industry Polymer industry in Indonesia Pacific Indomas Plastic Ind (PIPI) PT Products: Polystrene PolypetKaryaPersada PT Products: Poly EthileneTerapthalic (PET) PolyprimaKaryaReksa PT Products: Pure Terepthalic Acid (PTA) Standar Toyo Polymer PT Products: PVC Resin Homo Polymer TITAN Petrokimia Nusantara PT Products: Polyethylene
Polymer raw materials Petroleum Hydrocarbon sources
Polymerization Polymerization reaction Initiation step Propagation step Termination step
Polymerization Initiation step First step reaction due to pressure and heat
Polymerization Propagation step Reaction of free radical with monomer
Polymerization Termination step Monomer chain aggregation
Polypropylene Polypropylene basic polypropylene is a valuable polymer and is used as plastic for making pipes, ropes, fibres, etc It is manufactured by catalytic reaction in a stirred tank reactor, where Ti and aluminium halides are used as catalysts at a temperature of 60°C−70°C and a pressure of 1−2 MPa
Polypropylene Petrochemical products demand in Indonesia
Polypropylene Petrochemical products demand in Indonesia
Polypropylene Polypropylene supply and demand
Polypropylene Polypropylene supply and demand
Polypropylene Polypropylene supply and demand
Polypropylene Polypropylene supply and demand
Polypropylene Polypropylene supply and demand
Polypropylene Polypropylene supply and demand
Polypropylene Polypropylene recent status and technology Methanol-to-Propylene Technology two reaction steps Methanol dehydration to DME on an aluminium catalyst Transforming DME or methanol into a variety of olefins. The use of ZSM-5 catalyst yields propylene. Propylene will be processed further into polypropylene
Polypropylene Polypropylene recent status and technology Methanol-to-Propylene Technology
Polypropylene Polypropylene recent status and technology Propylene Production via Propane Dehydrogenation