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Quality and Consumer acceptability. Prof. I.E.Psomas Laboratory of Food Hygiene School of Veterinary Medicine Aristotle University of Thessaloniki GREECE. Chemical contaminants in crop production. Pesticides Naturally occurring toxicants (mycotoxins, higher plant toxicants) Nitrate
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Quality and Consumer acceptability Prof. I.E.Psomas Laboratory of Food Hygiene School of Veterinary Medicine Aristotle University of Thessaloniki GREECE
Chemical contaminants in crop production • Pesticides • Naturally occurring toxicants (mycotoxins, higher plant toxicants) • Nitrate • Metals
Routes by which pesticides reach the food chain • Treatment of crops • Veterinary use • In food manufacture and retailing • In the general environment • In the home
EC Legislation governing pesticide MRLs in products of plant origin (Council Directive 2000/24/EC) • Council Directive 76/895/EEC • Council Directive 86/362/EEC • Council Directive 86/363/EEC • Council Directive 90/642/EEC
Control of pesticides according to the “Farm to Table” Approach Farming (1,2,3,4) Food manufacture (1,2,3,4) (1,2,3,4) Food retailing Food preparation in the home (1,2,5) Types of control: 1.Control the availability and/or use of pesticides 2. Limit contamination from the general environment 3. Halt the supply of contaminated food 4. Limit the concentrations of pesticides allowed in food 5. Advise consumers on how to avoid pesticide contamination of food in the home
General scheme for pesticide risk assessment Hazard evaluation (how dangerous is the pesticide?) Consumption estimation (how much of the food is eaten?) Occurrence assessment (what foods contain pesticides, at what levels?) Intake estimation (what is the high intake of consumers?) Risk estimation (how does the risk intake compare to acceptable level?)
Major mycotoxins in feed/foodstuffs • Aflatoxins • Ochratoxins • Fumonisins • Trichothecenes • Zearalenone
Phases of a food safety management programme for mycotoxins • Setting of regulatory limits • Establishment of a monitoring programme • Control through good agricultural practices • Control through processing • Decontamination through specific treatments • Consumer/Producer education
Pre-harvest control • Management of insect infestation (Integrated Pest Management control programmes) • Management of crop residues and crop rotation • Irrigation and soil condition • Development of resistant plant varieties
Post-harvest control and Decontamination • Physical methods of decontamination • Biological Decontamination • Chemical Inactivation
Physical methods of decontamination • Cleaning • Segregation and sorting • Thermal degradation • Microwave treatment • Solar degradation • Extrusion cooking (promising)
Microbiological Decontamination • Ethanol fermentation • Probiotic mixtures (Lactobacillus, Propionibacterium)
Chemical Inactivation • Nixtamalization/alkaline hydrolysis • Bisulfite • Ammoniation • Hydrogen peroxide/sodium bicarbonate • Ozonation • Activated charcoal
B1 in foodstuffs B1+B2+G1+G2 in foodstuffs B1 in feedstuffs B1+B2+G1+G2 in feedstuffs 0-50 (1987)-(29)* 0-30 (1996)-(33)* 0-50 (1987)-(30)* 0-50 (1996)-(48)* 5-1000 (1987)-(16)* 5-1000 (1996)-(19)* 10-1000-(8)* 0-1000-(21)* Ranges in 1987 and 1996 of maximum tolerated levels (ng/g) for some aflatoxins and countries that have regulations for these *countries with legislation for mycotoxins
Types of higher plant toxicants • Pyrrolizidine alkaloids (several plant species) • Psoralens (celery, legumes, citrus fruits) • “Bracken carcinogen” (bracken) • Glycoalkaloids (potatoes, tomatoes) • Glycosinolates (Brassicas,vegetables, rapeseed)
Factors that influence the levels of nitrate in crops • The season in which the crops are grown • Increased irrigation may decrease nitrate concentrations in crops • Storage of vegetables has unpredictable effects • Cooking may reduce levels of nitrite in vegetables • Lengthening the period between nitrogen fertiliser usage and crops harvesting may decrease nitrate levels in crops • The effects of organic farming on nitrate levels are not established
Heavy metals in plants • Lead • Cadmium • Mercury • Arsenic • Aluminium
References • Official Journal of the European Communities, Commission Directive 2000/24/EC of April 2000 (L 107/28, 4.5.2000) • European Commission, Opinion of the Scientific Committee on Plants regarding variable pesticide residues in fruit and vegetables (Opinion expressed by SCP on 14 July 1998) • Third Joint FAO/WHO/UNEP International Conference on mycotoxins (Tunis, Tunisia, 3-6 March 1999) • Safety of Chemicals in Food (chemical contaminants) Ed. David Watson, Ellis Horwood series in Food Science and Technology (1993)