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Titrings- bylgju- föll; Líkindaföll/ Vibrational wavefunctions and probability functions:

Titrings- bylgju- föll; Líkindaföll/ Vibrational wavefunctions and probability functions:. Orkutilfærslur / energy transfers:. Leyfilegar titringstilfærslur / allowed transitions:. Titr.tilf. Yfirtónar / overtones:. +. -. +. +. +. +. +. n h n. -. n AB. n AB = n h n. E.

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Titrings- bylgju- föll; Líkindaföll/ Vibrational wavefunctions and probability functions:

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  1. Titrings- bylgju- föll; Líkindaföll/ Vibrational wavefunctions and probability functions:

  2. Orkutilfærslur / energy transfers: Leyfilegar titringstilfærslur /allowed transitions: Titr.tilf. Yfirtónar / overtones:

  3. + -

  4. + + + + + nhn - nAB nAB = nhn E

  5. Útl.rófa(1) Útlit rófa vs Upplausn / Spectra structures vs, resolution:

  6. Titr.þrep Skammtaþrep efnatengja / quantum levels: Snúnings-og titringsþrep/rotational and vibrational levels: Titringsþrep / vibrational levels:

  7. Tilurð IR rófa / Energy transitions: Útl.rófa(2) Útlit IR rófa / IR spectral structure

  8. HCl: H35Cl/H37Cl; IR róf/spectra (H.Í.): HCl(1)

  9. HCl(2)

  10. H2O : Samhverf teygja/ symmetric stretch; n1= 3652 cm-1 Ósamhverf teygja/unsymmetric stretch; n3 = 3756cm-1 Samhverf beygja/symmetric bending; n2 = 1595cm-1

  11. H2O H2O

  12. H20

  13. H2O tilfærslur: H2O tilf.

  14. CO2 Sjá NIST: http://webbook.nist.gov/cgi/cbook.cgi?ID=B4000020&Units=SI&Mask=800

  15. CO2 titringsorkuþrep / vibrational levels: CO2

  16. 2x 2x Samhverf CH-teygja/ symmetric CH- stretch; n1 =3374cm-1 Samhverf CC-teygja/ symmetric CC- stretchn2 =1974cm-1 Ósamhverf CH-teygja/unsymmetric CH-stretchn3 =3289cm-1 Samhverf beygja/symmetric bending; n4 =612cm-1 Samhverf beygja/ symmetric bending; n5 =730cm-1 3N-5 = 3x4 – 5 = 7

  17. IR róf línulegra sameindir / IR spectra for linear molecules: Línul. H-C=C-H: H-C=N:

  18. IR róf topsamhverfra sameinda / IR spectra for symmetric top molecules: Topsamhv. CH3I:

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