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Nuclear forces and Radioactivity. The nucleus is a competition between opposing forces Radioactivity is a result of imbalance between the forces. Learning objectives. Describe the basic forces and particles involved in nuclear structure
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Nuclear forces and Radioactivity The nucleus is a competition between opposing forces Radioactivity is a result of imbalance between the forces
Learning objectives • Describe the basic forces and particles involved in nuclear structure • Describe principles behind nuclear decay and radioactivity • Describe the particles emitted in nuclear decay • Define half-life and apply the concept to simple problems • Describe the relationship between energy and matter • Identify the differences between nuclear fission and fusion and their importance in generation of nuclear power
Forces act in opposing directions • Electrostatic repulsion: pushes protons apart • Strong nuclear force: pulls protons together • Nuclear force is much shorter range: protons must be close together
Neutrons only experience the strong nuclear force • Proton pair experiences both forces • Neutrons experience only the strong nuclear force • But: neutrons alone are unstable
Neutrons act like nuclear glue • Helium nucleus contains 2 protons and 2 neutrons – increase attractive forces • Overall nucleus is stable
As nuclear size increases, electrostatic repulsion builds up • There are electrostatic repulsions between protons that don’t have attractive forces • More neutrons required Long range repulsive force with no compensation from attraction
Neutron to proton ratio increases with atomic number Upper limit of stability
Upper limit to nuclear stability • Beyond atomic number 83, all nuclei are unstable and decay via radioactivity • Radioactive decay (Transmutation) – formation of new element Alpha particle emitted Mass number Atomic number Atomic number decreases
Stability is not achieved in one step: products also decay • Atomic number increases • Neutron:proton ratio decreases • Beta particle emission occurs with neutron-excess nuclei • Alpha particle emission occurs with proton-heavy nuclei Beta particle emitted
Radioactive series are complex The decay series from uranium-238 to lead-206 Each nuclide is radioactive and undergoes nuclear decay Left-pointing longer arrows (red) are alpha emissions M and Z decrease Right-pointing shorter arrows (blue) are beta emissions M constant, Z increases
Half-life measures rate of decay • Concentration of nuclide is halved after the same time interval regardless of the initial amount – Half-life • Can range from fractions of a second to millions of years
Fission and fusion: Radical nuclear engineering • Attempts to grow larger nuclei by bombardment with neutrons yielded smaller atoms instead. • Distorting the nucleus causes the repulsive forces to overwhelm the attractive • The foundation of nuclear energy and the atomic bomb
Nuclear fission • Nuclear fission produces nuclei with lower nucleon mass • One neutron produces three: the basis for a chain reaction – explosive potential • Neutrons must be obtained from other nuclear processes such as bombardment of aluminum with alpha particles
Chain reactions have the potential for nuclear explosions • Bomb requires creation of high rate of collisions in small volume • How to achieve this at the desired time in a controlled manner?
The importance of U-235 • U-235 is less than 1 % of naturally occurring uranium, but undergoes fission with much greater efficiency than U-238 • Fission can follow many paths: over 200 different isotopes have been observed • Each process produces more neutrons than it consumes
Enrichment of uranium • Weapons grade uranium requires a high concentration of U-235 • This is achieved by isotope separation • The lighter U-235 diffuses more rapidly than the heavier U-238 in the gas phase as UF6
Total of mass and energy is conserved but are inter-changeable • Fission: combined mass of smaller nuclei is less than the original nucleus A B + C MA > MB + MC • Loss in mass equals energy released: E = mc2 (Einstein’s relation) • Smaller nuclei are more stable • Fission of U-235: 0.08 % of mass is converted into energy
Comparison of nuclear and chemical energy sources • Conversion of tiny amount of matter into energy produces masses: 1 gram 1014 J • Chemical process: • 1 gram fuel produces 103 J • Nuclear process: • 1 gram uranium at 0.08 % produces 1011 J
Nuclear fusion: opposite of fission • Small nuclei fuse to yield larger ones • Nuclear mass is lost • Example is the deuterium – tritium reaction • About 0.7 % of the mass is converted into energy +E
The sun is a helium factory • The sun’s energy derives from the fusion of hydrogen atoms to give helium
Fusion would be the holy grail if... • The benefits: • High energy output (10 x more output than fission) • Clean products – no long-lived radioactive waste or toxic heavy metals • The challenge: • Providing enough energy to start the process – positive charges repel • Reproduce the center of the sun in the lab • Fusion is demonstrated but currently consumes rather than produces energy