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1. Uranyl Mesoporous Materials Alex Burum
Dr. Peter Burns
Ginger Sigmon
University of Notre Dame-Summer 2006 REU
2. Overview
Background
Synthesis
Results
3. Why mesoporous materials?
Mesoporous materials have pore sizes 20-500Ĺ
Zeolites are limited to ~15Ĺ pore sizes
Applications
Catalysts
Molecular Sieves
4. Why uranyl mesoporous materials?
Use of depleted uranium
Materials
New catalyst for environmental breakdown
Nuclear waste form
6. Synthesis Anions + uranyl nitrate + surfactant + urea + water = U mesoporous material
(1-x) : (x) : 2 : 30 : 60 (NH2)2CO + 3H2O = 2NH4+ + 2OH- + CO2
7. Synthesis Anions + uranyl nitrate + surfactant + urea + water = U mesoporous material
(1-x) : (x) : 2 : 30 : 60
8. Synthesis Anions + uranyl nitrate + surfactant + urea + water = U mesoporous material
(1-x) : (x) : 2 : 30 : 60
9. Results
10. Results
11. Future Work TEM – transmission electron microscopy
12. Acknowledgements: Thank you to:
Dr. Burns
Ginger Sigmon
Everyone in the Lab
University of Notre Dame – EMSI