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Chapter 5

Chapter 5. Gases. Volume liter milliliter cubic centimeters cubic meters Temperature Kelvin Celsius K = o C + 273.15 O C = K – 273.15. Units. Units. Pressure mm Hg atmosphere psi kilopascals 1 atm = 760 mm Hg = 760 torr = 101.3 kPa = 14.7 psi. PV = nRT P = pressure

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Chapter 5

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  1. Chapter 5 Gases

  2. Volume liter milliliter cubic centimeters cubic meters Temperature Kelvin Celsius K = oC + 273.15 OC = K – 273.15 Units

  3. Units • Pressure • mm Hg • atmosphere • psi • kilopascals • 1 atm = 760 mm Hg = 760 torr = 101.3 kPa = 14.7 psi

  4. PV = nRT P = pressure V = volume n = number of moles R = constant T = temperature (ALWAYS IN KELVIN) Ideal Gas Law

  5. R values 0.0821 atm*l moles*K 62.4 mm Hg*l moles*K 8.314 __J__ moles*K 8.314 l*kPa moles*K

  6. FormulasMolar Mass and Density MM= mRT PV D = MMP RT

  7. Density • Pressure • Compressing a gas increases its density. • Temperature • Increasing the temperature of a gas decreases its density.

  8. Gas Stoichiometry Law of Combining Volumes The volume ratio of any two gases in a reaction at constant temperature and pressure is the same as the reacting mole ratio.

  9. Combined Gas Law P1V1 = P2V2 T1 T2

  10. 2H2(g) + O2(g) 2H2O(l) What volume of H2(g) at 25oC and 1.00 atm is required to react with 1.00 L of O2(g) at the same temperature and pressure? What mass of H2O(l) is formed in a., assuming a yield of 85.2% a. 1.00 l O2 * 2 l H2 = 2.00 l H2 1 l O2 n = PV nO2 = (1.00atm)(1.00 l) = .0409 moles O2 RT (0.0821 atm*l )(298 K) moles*K .0409 moles O2 * 2 moles H2O = .0918 moles H2O 1 moles O2 .0918 moles H2O * 18.02 g H2O = 1.62 g H2O 1 mole H2O 1.62 g H2O * 85.2% = 1.26 g H2O

  11. Chapter 5 Assignment • Vocabulary p. 125 • Summary Problem p. 126 • Chapter 5 Questions and Problems beginning p. 126 • 4, 6, 12, 14, 15, 18 20, 22, 26, 32, 34, 36, 40

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