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Redox Neutral Reactions

Redox Neutral Reactions. Wang Chao 2011.3.12. Redox Economy and Redox Neutral Reactions:. Angew. Chem. Int. Ed. 2009, 48, 2854 – 2867. Developed by Noyori; Employed by Takasago in total synthesis of Menthol. Scheidt: J. AM. CHEM. SOC. 2009, 131 , 18028–18029. Hydride Shift Reactions:

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Redox Neutral Reactions

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  1. Redox Neutral Reactions Wang Chao 2011.3.12

  2. Redox Economy and Redox Neutral Reactions: Angew. Chem. Int. Ed. 2009, 48, 2854 – 2867

  3. Developed by Noyori; Employed by Takasago in total synthesis of Menthol

  4. Scheidt: J. AM. CHEM. SOC. 2009, 131, 18028–18029

  5. Hydride Shift Reactions: transition metals, lewis acids, organocatalysis recent examples: Akiyama:J. Am. Chem. Soc. 2011, 133, 2424–2426 Seidel:J. Am. Chem. Soc. 2011, 133, 2100–2103

  6. Borrowing Hydrogen: reduction and oxidation coupled Adv. Synth. Catal. 2007, 349, 1555 – 1575

  7. Breit: J. Am. Chem. Soc. 2011, 133, 2386–2389

  8. Transition metal mediated dehydrogenative activation Chem. Rev. 2010, 110, 681–703

  9. N-Alkylation of Amines by Alcohols: Alkylation of Activated Nucleophiles by Alcohols:

  10. Transfer Hydrogenative C-C Coupling: Krische: Angew. Chem. Int. Ed. 2009, 48, 34–46 J. Am. Chem. Soc. 2007, 129, 15134. Angew. Chem., Int. Ed. 2008, 47, 5220. J. Am. Chem. Soc. 2008, 130, 14891.

  11. Hydroacylation:

  12. Mechanism of activation of alcohol:

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