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Ionic and Metallic Bonding. Chapter 7. Valence Electrons. The ________________in an atom Their arrangement determines the bonding prosperities and activities of an atom S-Block– they are the same as the group number Na= 1 valence electron
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Ionic and Metallic Bonding Chapter 7
Valence Electrons • The ________________in an atom • Their arrangement determines the bonding prosperities and activities of an atom • S-Block– they are the same as the group number Na= 1 valence electron • P-Block– They are ____________ ______________________ C= 4 valence electrons F= 7 valence electrons Iodine… 7 valence electrons
Electron Dot Notation: Instead of drawing the orbital diagram, which can be long & complex, there is an easier way to represent the atoms. Electron Dot Notation: is an electron notation in which ____________________________ __________________, and are represented by dots around the element’s symbol. Lots and lots of examples… Valence electrons Dot notation
Ions Ion: atom that has lost or gained an electron Cation: atom that has a +ve charge (A+). i.e. missing an e- Anion: atom that has a –ve charge (X-). i.e. has an extra e- Do the Lewis structure for Cl, Cl-, Na, Na+
Polyatomic Ions • Polyatomic ions are _______________________________ _____________________________________________. • Common Examples… • OH- (Hydroxide) • NO3- (Nitrate) • SO42- (Sulfate) • PO43- (Phosphate) (draw their Lewis structures) • There are more that you will need to memorize over thanksgiving break… maybe you should start now, lets look at them…
Ionic Bonding Most of Earth’s rocks & minerals are made up of compounds held together by ionic bonds. Ionic Compound:______________________ __________________________________ _________________________________ e.g. Na -> Na+ + e-&Cl + e- -> Cl- Na++Cl-->NaCl(#+’s = #-’s) e.g.2. Mg & Cl(show on board)
Most ionic compounds exist as a 3-D crystalline solid of alternating +’ve & -’ve ions (NaCldia) (Screen 3.9 Coulomb’s law, 3.10 NaCl, 3.10.SB KBr)
Ionic Compounds: atomic arrangement Formula Unit: is the ________________of atoms from which an ionic compounds formula can be established. Ionic compounds can be represented by Electron Dot diagrams. e.g. NaCl
Ionic Solid Structure • Ionic crystals combine in an ________________ ___________________________. • Crystalline solids at room temperature Rutile (crystal and model of lattice)
Ionic Solids: Characteristics -___ melting/boiling pts -very ___________ -when molten (or dissolved in H2O) they become _____ ____________________________
Metallic Bonding: • Metals have few valence e-’s (1,2or3) which roam freely as a “sea of electrons” throughout the metal. ____________________________ ________________. • The atoms themselves are arranged in a crystal like lattice. • The bonding between the metal atoms & this sea of electrons is called ______________. • ____________________________________________________.
Metal Solids Characteristics: • _____________________________ • Luster • __________ • Ductile Metals can only come together when they are in their _____________. _______________________ _____________________________________
Alloys Substitutional Alloy: ______________ _____________________________________________________________________. E.g’s: Brass: Copper (~2/3) & Zinc (~1/3) Bronze: Copper (~80%) & Tin (~20%) Sterling Silver: Silver (93%) & Copper (7%) 24 Karat Gold: Gold (100%) 18 Karat Gold: Gold (18/24 = 75%) & Silver
Interstitial Alloy: some of the holes (interstices) between the metal atoms are ________________. Makes the metal ___________ ______________________ ____________________ Ie. _______:Iron & Carbon (small %)