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CH3Br, 101209 “New” C atomic lines Summary of C atomic line observations and “nonobservations”

CH3Br, 101209 “New” C atomic lines Summary of C atomic line observations and “nonobservations” agust,heima,....Dec09/CH3BR-Overall (C)-081209km agust,www,...Dec09/PPT-101209aak.ppt agust,heima,...Dec09/XLS-101209ak.xls. New ??. ATH?. New 3 peaks. artifact. 71343.2474. 71349.2. 71353.3.

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CH3Br, 101209 “New” C atomic lines Summary of C atomic line observations and “nonobservations”

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  1. CH3Br, 101209 • “New” C atomic lines • Summary of C atomic line observations and “nonobservations” • agust,heima,....Dec09/CH3BR-Overall (C)-081209km • agust,www,...Dec09/PPT-101209aak.ppt • agust,heima,...Dec09/XLS-101209ak.xls

  2. New ?? ATH? New 3 peaks artifact

  3. 71343.2474 71349.2 71353.3

  4. http://physics.nist.gov/cgi-bin/ASD/energy1.pl : agust,heima,...Dec09/XLS-101209ak.xls:

  5. 69704.95668/ 69705.0 Check To be copaierd with lines in PPT-240809ak.ppt:

  6. http://physics.nist.gov/cgi-bin/ASD/energy1.pl 1D REMPI for C+ C I 69647.2 69668.9 Exp. Values: 69675.3 69705.0 69715.4 69697.7 69733.1 Measurements seem to have got lost

  7. Ergo: The lines are: 2s22p2 (3P) ->-> 2s22p(2P°)3p(3P), DJ =0: 71343.2474~71341.98 J’’=2 ->-> J´=2 71349.2 ~71348.5; J’’= 1 ->-> J´= 1 71353.3 ~ 71352.51; J’’=0 ->-> J´=0

  8. 77411.21 Does not seem to be C atomic line. (see: agust,heima,...Dec09/XLS-101209ak.xls) Could this be Br atomic line?...... NO, not according to ....PPT-201009aak.ppt

  9. Now lets check C atomic lines for • 2p2 ->-> np transitions • 3P ->> 3X • 1D ->-> 1X • :

  10. limit limit observed Not observed Observed New (101209) Not observed Not observed(?) limit

  11. Weak but Observable See below 1) Not observed observed

  12. Not observed Not observed observed Not observed

  13. Not observed Not observed Not observed Not observed : 91193:limit

  14. 1) 72061.4 (obs.) vs 72059.1 (predicted) 71577.6(obs.) vs 71577.16 (predicted)

  15. Agust,heima,...Dec09/AFSTODUMYND-190809hrh-101209ak.pxp

  16. agust,heima,...Dec09/AFSTODUMYND-190809hrh-101209ak.pxp H2 + C**(6p,1S) +HBr H2 + C**(6p,1D) +HBr H2 + C**(5p,1S) +HBr H2 + C**(5p,1D) +HBr (H2 + C**(4p,1S) +HBr) (H2 + C**(4p,1D) +HBr) H2 + C**(3P) +HBr H2 + C**(3D) +HBr 69689.48/2 3P->3D J’´=0 ->>J´=1 H2 + C*(1D) +HBr 69521.63 10360.48 69689.48/2 3P->3D J´´=0 ->>J´=1 H2 + C(3P) +HBr 59329

  17. agust,heima,...Dec09/AFSTODUMYND-190809hrh-101209ak.pxp H2 + C**(6p,1S) +HBr H2 + C**(6p,1D) +HBr H2 + C**(5p,1S) +HBr H2 + C**(5p,1D) +HBr (H2 + C**(4p,1S) +HBr) (H2 + C**(4p,1D) +HBr) H2 + C**(3P) +HBr H2 + C**(3D) +HBr 71352.51/2 3P->3P J’´=0 ->>J´=0 H2 + C*(1D) +HBr 69521.63 12023.51 H2 + C +HBr 59329 71352.51/2 3P->3P J’´=0 ->>J´=0

  18. agust,heima,...Dec09/AFSTODUMYND-190809hrh-101209ak.pxp H2 + C**(6p,1S) +HBr H2 + C**(6p,1D) +HBr H2 + C**(5p,1S) +HBr H2 + C**(5p,1D) +HBr (H2 + C**(4p,1S) +HBr) (H2 + C**(4p,1D) +HBr) H2 + C**(3P) +HBr H2 + C**(3D) +HBr 71577.16/21D->->4p, 1D Very week H2 + C*(1D) +HBr 69521.63 2055.52 H2 + C +HBr 59329 71577.16/2 1D->->4p, 1D

  19. agust,heima,...Dec09/AFSTODUMYND-190809hrh-101209ak.pxp H2 + C**(6p,1S) +HBr H2 + C**(6p,1D) +HBr H2 + C**(5p,1S) +HBr H2 + C**(5p,1D) +HBr (H2 + C**(4p,1S) +HBr) (H2 + C**(4p,1D) +HBr) H2 + C**(3P) +HBr H2 + C**(3D) +HBr 75207.18/2 1D->->5p, 1D H2 + C*(1D) +HBr 69521.63 5685.55 H2 + C +HBr 59329 75207.18/2 1D->->5p, 1D

  20. agust,heima,...Dec09/AFSTODUMYND-190809hrh-101209ak.pxp H2 + C**(6p,1S) +HBr H2 + C**(6p,1D) +HBr H2 + C**(5p,1S) +HBr H2 + C**(5p,1D) +HBr (H2 + C**(4p,1S) +HBr) (H2 + C**(4p,1D) +HBr) H2 + C**(3P) +HBr H2 + C**(3D) +HBr 77025.63/2 1D->->6p, 1D H2 + C*(1D) +HBr 69521.63 7504 H2 + C +HBr 59329 77025.63/2 1D->->6p, 1D

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