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Learn about symbols, atomic numbers, isotopes, molecules, compounds, and bonding in chemistry. Understand the properties of water, pH scale, and mixtures.
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Symbols Atomic Number- No. of protons Atomic Mass – No. of protons and neutrons (electron mass negligible) Chemical symbols found on Periodic table
Definitions • Element- Substance consisting of one type of atom. • Isotope – Atom of an element with different number of neutrons. • Molecule – Smallest unit of substance. Retains chemical & physical properties of substance. Compose of 2 atoms held together by a bond. Atoms may be of same/different elements. • Compound- Substance composed by chemical combination of two or more elements in definite proportions.
Relationships • Work in groups of 4 and respond to the following questions. • Are N2, H2, and O2 elements or compounds? • Are N2, H2, and O2 atoms or elements? • Is C an atom or element? • Is H20 a molecule or a compound?
Organic Compounds • Carbohydrates (sugars) : Carbon, Oxygen, Hydrogen • Lipids (fats): Carbon, Oxygen, Hydrogen, and Phosphorus • Proteins: Carbon, Oxygen, Hydrogen, Nitrogen, and Sulfur • Nucleic Acids (DNA, RNA): Carbon, Oxygen, Hydrogen, Nitrogen, Phosphorus
Isotopes have a different # of neutrons.Isotopes have the same number of electrons and behave the same way chemically.
Radioisotopes • Valuable research tools. • Unstable nucleus; over time gives off subatomic particles & energy; results in stable nucleus. • Decay of radioisotopes occurs at constant rate called half life. • Use carbon isotopes to date fossils and minerals. • Use other radioisotopes in medical tests.
Isotopes Why is the atomic mass not exactly double the atomic number?
Bonding • Atoms – held together by chemical bonds. • Two types – Ionic bond and covalent bond. • Ionic bond – one or more electrons transferred from one atom to another. • Covalent bond – electrons shared between atoms. • Van der Waals Forces –Weak attractive force between molecules.
Bonding • Compounds are held together by chemical bonds. • Electrons are involved in chemical bonding. • The outer shell (orbital) of atom is called valence shell. • Electrons in this shell are valence electrons.
Bonding • Atoms with unfilled valence shells are chemically reactive. • Atoms seek to fill valence shell. • Bonding fills valence shell with electrons.
Bond Strength • Covalent bonds are strongest bond. Takes more energy to break bond. • Ionic bonds are weaker than covalent. • Van der Waals forces are weak attractions. Assignment: Create a graphic organizer. Compare and contrast ionic and covalent bonds. Work with a partner.
Properties of Water • Only substance on Earth found as solid, liquid, and gas. Solid less dense than liquid state. • Polarity • Cohesion • Adhesion • Capillary Action
Polarity Water is polar- uneven distribution of electrons between hydrogen and oxygen atoms. Hydrogen bonds- Attraction between + charged H and – charged O. One atom forms multiple H bonds. H bonds give water special properties.
Cohesion • Attraction between molecules of the same substance. • Surface tension – tension at surface of water is related to cohesion
Adhesion • Attraction between molecules of different substances.
Capillary Action Capillary action is responsible for water moving through a plant. Adhesion- water is attracted to roots, stems, and leaves. Cohesion – water column is held together as it rises.
Review • What do the numbers 11 and 23 near the sodium symbol represent? • Use the Bohr model on the right. How many • a. How many valence electrons are available? • b. What is the atomic mass of this element? • c. Is this element an isotope? Why? • What elements are present in a protein? • What type of bond is occurring between the Mg and Cl? • a. Which of the two elements has a higher • electro-negativity? • b. What would happen to this compound in an • aqueous solution? • 5. On the left is a drop of water. Why does • water make drops?
Mixture/Solutions/Suspensions • Mixture: Two or more elements/compounds physically mixed but not chemically mixed. • Solution: Homogeneous mixture in which one substance is dissolved (solute) in another (solvent) usually water. • Suspension: Mixture of water and non dissolved substance.
Solution • NaCl dissolves in water. • NaCl is the solute; water is the solvent. • Water surrounds the Na + and Cl-.
Suspensions • Blood is an example of a suspension. • Red blood cells are suspended in a liquid called plasma.
pH • A molecule of water can form ions • 1 molecule in 550 million will react to form ions. • Water has the same number of H+ and OH-; it is neutral. • Solutions that have a higher concentration of H+ than water are acidic. • Solutions that have a lower concentration of H+ that water are basic (or greater OH -)
pH Scale 7 = Neutral pH Below 7 = acidic pH Above 7 = basic pH Each pH change represents a 10 fold change in the level of H+. EX: pH of 4 has 10x more H+ than pH of 5 EX: pH of 5 has 10x less H+ than pH of 4
Organic Molecules • Are made of carbon. • Can be very small like CO2 to very large like a protein. • Living organisms are made of and use organic molecules.
Carbon • Is tetravalent; can form 4 bonds. • Bonds with many types of elements: H,N,O,P,S • Can form many types of structures.
Macromolecules • Macromolecule – Giant molecule made from smaller molecules. • Polymer- Large molecule consisting of similar or identical molecules linked together. • Monomer – Subunit of polymer. • Polymerization - Process of polymer creation
Organic Molecules • Carbohydrates, proteins, and nucleic acids are polymers (and macromolecules). • Lipids are macromolecules (but not polymers) • All are biomolecules.
Carbohydrates • Made of C, H, O in 1:2:1 ratio; (CH2O) • Used for energy by all organisms, plants & some animals use them for structures. • Monosaccharides- single sugar (monomer) • Glucose is a monosaccharide used for energy.
Carbohydrates • Disaccharides - Two sugars • Table sugar sucrose is a disaccharide composed of two monosaccharides glucose and fructose (fruit sugar).
Carbohydrates • Polysaccharides are polymers made of many monosaccharides. • Examples: - Plant starch – used to store energy - Glycogen (animal starch) – used to strore energy. - Cellulose – used by plants for structure. Cellulose
Lipids • Made from C, H mostly. • Used to store energy, for cell membranes, water proof coverings, some hormones. • Three types of lipids - Triglycerides - Phospholipids - Cholesterol
Triglycerides • Made of 2 components - glycerol - fatty acid chains (3) • Used to store energy (2x energy in a polysaccharide)
Saturated vs. Unsaturated • Saturated Lipid- • Single bonds between Cs in carbon skeleton. • Each C single bonded to H. (i.e. saturated with H) • Chain straight / pack tightly /solids at RT. • Unsaturated Lipid – • Some Cs double bonded • Makes kink in chain • Chains can’t pack as tightly/ oils at RT.
Figure 5.11 Examples of saturated and unsaturated fats and fatty acids
Saturated vs. Unsaturated • Saturated fats - Animal fats - Raise LDL or bad cholesterol levels. • Unsaturated fats -Vegetable fats - either help to raise HDL or good cholesterol levels or decrease LDL levels.
Phospholipids • Phospholipids- glycerol, • 2 fatty acid chains, & phosphate group. • Function – to make up cell membranes.
Cholesterol • Steroids- lipids with 4 fused carbon rings. • Cholesterol is a steroid. • Function- component of animal cell membranes. • Precursor from which other steroids are made including hormones. • High levels contribute to atherosclerosis
Nucleic Acids • Made of C, H, O, N, P • Used to store and transmit genetic information. • Two types: DNA & RNA • Monomer: Nucleotide
Nucleotides • Nucleotides • Nitrogenous base • Pentose (5C) sugar/ Deoxyribose in DNA • Ribose in RNA • -Phosphate group
DNA DNA (polymer) is made by bonding nucleotides together. Phosphate of one nucleotide is bonded to sugar of the next nucleotide.
Proteins • Made of C, H, O, N • Have many functions: - Control chemical reaction rates – Enzymes - Form bones and muscles – Structural - Hemoglobin carries oxygen – Transport - Fight disease - Antibodies
Proteins • Are structurally diverse consistent with their many functions.