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Physical Properties. Due to the polar nature of water Hydrogen bond- weak attraction between hydrogen on adjacent molecules such as water. H H O. H H O. Hydrogen bond. Water and it’s importance to Life. Life evolved in water
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Physical Properties • Due to the polar nature of water • Hydrogen bond- weak attraction between hydrogen on adjacent molecules such as water H H O H H O Hydrogen bond
Water and it’s importance to Life • Life evolved in water • Water’s unique properties have made life as we know it possible
Physical Properties • Heat of vaporization- amount of energy that is released or gained when changing state from liquid to gas or back
Physical Properties • High Specific Heat- the amount of heat absorbed or released when water changes temperature by one degree C. ( 1 cal. )
Ice Floats • As a liquid water’s hydrogen bonds continuously break and reform • As a solid four molecules form hydrogen bonds creating crystals with open channels and thus fewer molecules per area.
Physical Properties • Water reaches maximum density at 4 degrees C. • Water is a universal solvent due to it’s polar nature
Evaluate the importance of the following and explain the property of water responsible. • Cytoplasm is 98 % water • Ice Floats • Lake effect temperature moderation • Evaporative Cooling • Spring-Fall Overturn
Most Abundant Chemicals in Life • Carbon • Oxygen • Hydrogen • Nitrogen • Ca, P, K, S, Na, Cl, Mg > 4 % 96 %
Carbon is special • Tetrahedral structure- four valence electrons shared • Covalent bonds - stability
Carbon is Special • Variations are possible in carbon molecules that provide diversity • Isomers are possible structural- differ in structure same chemical formula geometric-differ in spatial relationship enantiomers-mirror images of eachother
Condensation Synthesis A B A B + H2O + A and B could be monosaccharides or amino acids
Hydrolysis + + H2O Addition of water breaks the bond
Polymers Polymers are repeating units of monomers. They are very important to Biology. They are made or synthesized by the removal of water called CONDENSATION SYNTHESIS They are broken down by the addition of water or HYDROLYSIS
Classes of Biomolecules • Carbohydrates- used for energy and structures( building living organisms) • Lipids- used for energy storage, communication and structures • Proteins- used for a variety of life functions • Nucleic Acids-the instructions for building life
Carbohydrates • Three common forms • Monosaccharides • Disaccharides • Polysaccharides
Carbohydrates • Monosaccharides- single sugars or simple sugars,ex. Glucose ( C6H12O6) • Disaccharides- double sugar, ex. Sucrose • Polysaccharides- polymers of glucose such as: 1. Starch 2. Cellulose 3. Glycogen 4. Chitin
Review • What will happen here? AOH + HB = ? And here: CH2OH CH2OH O O OH OH H OH OH H OH OH OH H2O OH
Dehydration Synthesisor a Condensation Reaction A + B = AB + H2O CH2OH CH2OH O O OH O OH OH OH H2O OH OH
Review • What will happen here? AB + H2O = ? And here: CH2OH CH2OH H2O O O OH O OH OH OH OH OH
Hydrolysis or Reaction AB + H2O = AOH + HB Molecules have been HYDROLIZED! CH2OH CH2OH O O OH OH OH OH OH OH OH OH
Glucose CH2OH Glucose has a chemical formula of C6H12O6 C O H OH OH C C H OH H H C C H OH
FRUCTOSE O CH2OH CH2OH C C H H HO H C C OH OH
Disaccharides • Sucrose and Lactose • 2 monosaccharides bonded together Alpha or Beta? CH2OH CH2OH O O O OH OH OH OH OH OH
Polysaccharides • 3 or more Monosaccharides bonded together CH2OH CH2OH CH2OH O O OH O O OH OH OH O OH OH OH OH
Polysaccharide • Starch-storage in plants • Cellulose-structural part of plant cell wall • Glycogen- storage in animals, liver • Chitin – structural component for arthropods, exoskeleton. Also found in fungi.
Polysaccharides – Starch • Plants use it as energy storage • Difficult for humans to break down • Ex. Avoid a high starch diet
polysaccharides Glucose monomers
Polysaccharides – Cellulose(B 1, 4 linkage) • Long fibers • Up to 15,000 Glucose units per strand • Most abundant biological substance on earth • Ex. Cotton, Trees, Paper • Why is cellulose so strong? • Why can’t humans breakdown cellulose and cows can?
Polysaccharides – Glycogen • Animals use it as energy storage • Lots and lots of it in the liver • Forms huge branched storage units which allow for easy break down for energy
Other polysaccharides • Chitin • Found in the exoskeleton of insects, and arthropods • Ex. Crabs, lobsters, grasshoppers • Pectin • Found in plant cell walls • Provides rigidity • Heteropolymers • Glycoproteins and peptidoglycans
Protein Polymers of amino acids With 20 natural amino acids there are a variety of proteins
Amino AcidsThe building blocks of protein H O H N -C - C H OH R R- there are twenty different R groups possible
Alanine NH2-CH-COOH Glycine NH2-CH2-COOH CH3
Peptide bond- is a bond between amino acids a molecule of water is removed
Protein Structure 1. Primary- order of the amino acids 2. Secondary- hydrogen bonds cause pleats and helix 3. Tertiary- folds and loops create shape by R Group bonds 4. Quaternary-interaction of several proteins
Lipids • Large molecules that do NOT have an affinity for water; not soluble in. • May have hydrophobic-water fearing and hydrophilic-water loving parts.
Triglycerides hydrophilic hydrophobic
Types of Lipids • Made of hydrocarbons - • Triglycerides- fats, waxes, and oils(saturated all single bonds C-C, unsaturated have double C=C bonds • Phospholipids- attached phosphate replaces one of the hydrocarbon tails • Steroids- Ring Forms of Hydrocarbons cholesterol and some hormones
Triglycerides • Saturated fats- single bonds make this a solid at room temperature and more difficult to digest.
Unsatured Fats • Triglycerides that contain double bonds ( dehydrogenated) are liquids at room temp and more digestable
Nucleic Acids • Made of monomers called nucleotides • DNA- deoxyribonucleicacid • RNA- ribonucleic acid • These molecules carry all the hereditary information of living things
DNA Basic Composition • DNA is made up of nucleotides • Nucleotides are made of …………...Deoxyribose sugar ……………Phosphate ……………Base bases are guanine,cytosine, thymine and adenine
RESPIRATION SYNTHESIS C A T A B O L I S M A N A B O L I S M ATP SYNTHESIS FROM ADP + Pi
Free Energy • Ability to do work in the cell or ecosystem.
ATP formation + G ENDERGONIC Stores energy in phosphate bond ATP breakdown - G EXERGONIC Releases energy between phosphates Energy Transfer