Chemical Hygiene Plan Implementation Training

1. Chemical Hygiene Plan Implementation Training April 18, 2008 Marlin Bryant Certified Hazardous Materials Manager Kleinfelder Facilities Excellence

2. San Mateo CountyCommunity College District • SMCCCD’s Hazardous Communication Program • Review Responsibilities • Vice-chancellor Of Facilities Planning, Maintenance And Operations • District Safety Committee • College Safety Committees • Departments • Individual Facilities Excellence

3. San Mateo County Community College District Safety Committee Members

4. San Mateo CountyCommunity College District • District’s Commitments: • Create a Hazardous Communication Program • Provide Employee Information and Training • Require Labeling of all Hazardous Chemicals • Require Annual Hazardous Chemical Inventory • Require Acquisition of Material Safety Data Sheets • Provide Chemical Hygiene Plan Template • Document Employee Hazard Communication Training • Coordinate Hazardous Waste Disposal Facilities Excellence

5. Hazard Communication Plan7.0 Chemical Hygiene PlanTemplate Cal/OSHA has promulgated a standard entitled Occupational Exposure to Hazardous Chemicals in Laboratories, 8CCR5191, which applies to all laboratories that use hazardous chemicals. It specifies that a written Chemical Hygiene Plan must be developed and implemented that includes the necessary work practices, procedures, and policies to provide that employees are protected from hazardous laboratory chemicals. In an effort to comply with this regulation, SMCCCD has developed a Chemical Hygiene Plan template. Each SMCCCD College Dean, Department Head, and/or Supervisor will be responsible for customizing the Chemical Hygiene Plan to appropriately address the chemical hygiene and safety issues specific to their respective laboratory, workshop and/or studio operation including, but not limited to: • Responsibilities under the Chemical Hygiene Plan; • Site map – depicting emergency equipment and exits; • Hazardous chemical inventory – current annual; • Control measures to reduce employee exposure to hazardous chemicals; • Chemical procurement, distribution, and storage; • Material safety data sheet for each chemical in inventory • Forms. Table 7-1 presents the number of laboratories, workshops, and studios, within the SMCCCD, their associated colleges, and whether or not these laboratories, workshops, or studios generate hazardous waste.

6. Hazard Communication PlanAttachment 1 Record of Hazard Communication Training San Mateo County Community College District Date: ____________ By signing below I certify that my Supervisor, ________________________, went over in detail with me the contents of the safety training checklists on Injury and Illness Prevention Program, HAZCOM, and Emergency Response. I am also certifying that my Supervisor provided me with an opportunity to ask questions during the training session and that I have a good understanding of the material presented. Name of Employee: __________________________ Employee's Signature: ________________________ Supervisor's Signature: ________________________

7. Department Specific Chemical Hygiene Plan Introduction • The San Mateo County Community College District (herein “SMCCCD” or “District”) has established a Hazard Communication Program (HAZCOM) Program. • The District’s HAZCOM Program, requires department-specific Chemical Hygiene Plans for each laboratory, workshop, and studio where hazardous chemicals are used or stored, in compliance with the California Occupational Safety and Health Administration (Cal/OSHA) Hazard Communication Standard (California Code of Regulations, Title 8, Section 5194). Responsibilities For The Chemical Hygiene Plan • This document is a summary of the main requirements of an SMCCCD Chemical Hygiene Plan, the individuals responsible for these requirements, and the specific procedures necessary to comply with District policies and Cal-OSHA standards. This document is to be used in conjunction with the SMCCCD HAZCOM Program document that explains these requirements in additional detail. Facilities Excellence

8. Hazard Communication PlanTable 2-4 Cañada College

9. Page 1 INSERT: Who is responsible? In accordance with the Cal-OSHA Hazard Communication Standard and SMCCCD procedures, the following Chemical Hygiene Plan has been developed for: The Dean, Department Head, and Supervisor are responsible for providing that each department-specific Chemical Hygiene Plan is complete and is understood and followed by the employees under their supervision.

10. Page 1 INSERT: Where is copy of HAZCOM and Chemical Hygiene Plan accessible to employees? While the Dean, Department Head, or Supervisor is responsible for implementing each of the elements described within this Chemical Hygiene Plan, it is permissible to delegate some tasks to other capable employees (e.g. designee), provided the roles are clearly documented and understood.

11. Page 2 INSERT: Who provides employee training? The Dean, Department Head, Supervisor, or designee is responsible for providing that each employee receive the appropriate HAZCOM training, including both general and department-specific training. Refer to the SMCCCD HAZCOM Program document for a description of the required content of department-specific training. Training records, such as training sign-in sheets or course certificates, must be maintained by the Dean, Department Head, Supervisor, or designee, as well as, documentation of the content of department-specific HAZCOM training.

12. LABELS • Labels provide an immediate warning of the hazards to which employees may be exposed and provide a link to more detailed information (i.e. MSDS). The Dean, Department Head, Supervisor, or designee will provide that every container entering the laboratory, workshop, and studio has the required label affixed to the container. • If a chemical is transferred to another container, then the new or secondary container must be labeled, as well. The label on the secondary container must contain the same information required for the label on the original or primary container. Refer to the SMCCCD HAZCOM Program document for details about what information must be on a label, as well as, suggested methods for labeling secondary containers. • It is not necessary to label the secondary container if the employee who performs the transfer is the only person who uses the entire chemical from the new container, during a single work shift.

13. Page 3 INSERT who is responsible for Hazardous Chemical Inventory and where available? The Dean, Department Head, Supervisor, or designee is responsible for identifying and listing all hazardous chemicals in the Hazard Chemical Inventory (HCI) that are stored, used or generated in their laboratory, workshop, and studio. Appendix C presents the HCI.

14. The Dean, Department Head, Supervisor, or designee will determine the method used to organize, store, and maintain the MSDSs as described below. Refer to the SMCCCD HAZCOM Program for details of MSDS accessibility requirements. Page 4 INSERT: Who is responsible for Material Safety Data Sheets and where available? The Dean, Department Head, Supervisor, or designee will provide that all MSDSs are available for every hazardous chemical used in each Department laboratory, workshop, and studio and are available to employees on all work shifts. Appendix D provides the current MSDSs.

15. WORKING WITH CONTRACTORS RECORDKEEPING The Department must develop a plan to provide the continuity of all recordkeeping when a Supervisor leaves or is reassigned. Training Records: Records of general and department-specific Chemical Hygiene Plan will be maintained by the Dean, Department Head, Supervisor, or designee. Records will be readily available for inspection by SMCCCD or Cal-OSHA representatives.

16. General Chemical SafetyAppendix B-1 • Do’s • Don’ts • Hazardous Materials • Material Safety Data Sheets • Laboratory, Workshop or Studio Safety • General Safety Rules • Hazardous Chemical Waste Disposal • Collection and Segregation • Identification and Labeling • Transferring Facilities Excellence Slide 1

17. General Chemical Safety Appendix B-1 continued • Fires and Explosions • Provisions for Medical Evaluation Consultation • Record Keeping • Employee Information and Training • Information • Training Facilities Excellence

18. General Chemical Safety Appendix B-1 continued • Engineering Controls and Personal Protective Equipment (PPE) • Emergency Procedures – Chemical Spills or Releases • Summary of Procedures • Accident and Emergency Reporting Facilities Excellence

19. General Chemical SafetyAppendix B-1 • ACTION ITEMS: • Hazardous Chemical Waste Disposal • Item B 1. Note collection station for waste solvents • Emergency Procedures - Chemical Spills or Releases • Item D 4. Note who to call in the event of a chemical spill • Item G. Note Campus Facilities Manager • Danny Glass – Canada • Diane Martinez – CSM • Richard Inokuchi – Skyline Facilities Excellence

20. General Chemical SafetyAppendix B-1 • Summary of Procedures • Item 4 Enter “Office of • Item 6 Enter “Office of • Add “Office of • And after hours/weekend info Facilities Excellence

21. Control Measures Appendix B-2 • Recommended Department Specific • General Safety Dos and Don’ts • General Chemical Safety • Control Measures Facilities Excellence

22. Control Measures Appendix B-2 General Protective Equipment Performance • Eye & Face Protection • Other Protective Clothing • Gloves • Fire Extinguishers • Eyewash & Safety Showers • Fire Blankets & First Aid Kits • Department Policy & Responsibility Facilities Excellence

23. ACTION ITEM: Items 1 – 38 Department should revise these General Requirements as appropriate Facilities Excellence

24. Chemical Procurement, Distribution & StorageAppendix E • Hazardous Chemical Inventories • Transporting Hazardous Chemicals • Labeling Chemicals • Labeling of Hazardous Chemicals • Labeling Requirements • Purchasing Chemicals • General Storage Guidelines • Secondary Containment Facilities Excellence

25. Chemical Procurement, Distribution & Storage Appendix E continued • Compatibility of Stored Chemicals • General Guidelines • Storage of Specific Classes of Chemicals • Flammable Liquid Storage • Definitions • General Guidelines Facilities Excellence

26. Chemical Procurement, Distribution & Storage Appendix E continued • Conditions for Storage & Use of Flammable Chemicals • General Guidelines • Glass Containers • Metal Containers • Storage Volume • Flammable Liquid Storage Cabinets Facilities Excellence

27. Chemical Procurement, Distribution & Storage Appendix E continued • Storage of Corrosive Chemicals • General Guidelines • Storage & Handling of Compressed Gasses • General Guidelines • Secure Gas Cylinders to Prevent them from Falling Over Facilities Excellence

28. Chemical Procurement, Distribution & Storage Appendix E • ACTION ITEMS: • Awareness of Procurement • Awareness of Distribution • Awareness of Storage • Awareness of Inventories • Methods of Transporting • Ensure Proper Labeling Facilities Excellence

29. DefinitionsAppendix F-1

30. Industrial Toxicology OverviewAppendix F-2 • Chemical Toxicology • Dose-Response Relationships • Routes of Entry Into the Body • Types of Effects • Acute Poisoning • Chronic Poisoning • Local • Systemic • Cumulative Poisons • Substances in Combination Facilities Excellence

31. Industrial Toxicology OverviewAppendix F-2 • Other Factors Affecting Toxicity • Physical Classifications of Toxic Materials • Gas ▪ Solubility • Vapor ▪ Aerosol Physiological Classifications of Toxic Materials ▪ Irritants ▪ Asphyxiates ▪ Primary Irritant ▪ Primary Anesthetics ▪ Secondary Irritants ▪ Hepatotoxic Agents ▪ Corrosives ▪ Nephrotoxic Agents Facilities Excellence

32. Industrial Toxicology OverviewAppendix F-2 • Neurotoxic Agents • Some Toxic Agents Act on Blood • Toxic Agents that Damage Pulmonary Tissue • Carcinogen • Mutagen • Teratogen • Sensitizer • Target Organ Effects ▪ Hepatotoxics ▪ Pulmonary Agents ▪ Nephrotoxics ▪ Reproductive Toxins ▪ Neurotoxins ▪ Skin Hazards ▪ Hematopoietic ▪ Eye Hazards Facilities Excellence

33. Prop 65 ChemicalsAppendix F-3 State of California Environmental Protection Agency Office of Environmental Health Hazard Assessment Safe Drinking Water & Toxic Enforcement Act of 1986 Facilities Excellence

34. Chemicals Requiring Designated Areas Appendix F-4 SMCCCD would like to eliminate or at least minimize the use of chemicals listed in this section. Facilities Excellence

35. Door PosterAppendix G-1

36. Training RecordsAppendix G-2

37. Safety ChecklistAppendix G-3

38. Safety Audit Appendix G-4

39. Safety Audit Appendix G-4

40. Safety Audit Appendix G-4

41. Safety Audit Appendix G-4

42. Safety Audit Appendix G-4

43. Safety Audit Appendix G-4

44. Hazardous Waste Disposal RequestAppendix G-5

45. Hazardous Waste Disposal RequestAppendix G-5 continued

46. Review • OSHA Requirments Road to success: • Storage Training • Labeling MSDS • MSDS Floor Plan • Floor Plan Record Keeping • Inventory Recommendations: • Dispose of any chemicals not needed • Do not accept donated chemicals

47. Chemical Hygiene Plan Implementation Training Questions and Answers Facilities Excellence