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Margarita Loredo -Cancino

Synthesis and characterization of zinc and cupper MOFs derived from diazo and oxim ligands for wastewater treatment. Margarita Loredo -Cancino R. Chan-Navarro | N.E. Dávila-Guzmán | D.A. De Haro -Del Río | M. Vázquez- Mozencahuatzi |. ADSORPTION. Zheng et al. 2012. Li et al. 2015.

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Margarita Loredo -Cancino

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  1. Synthesis and characterization of zinc and cupper MOFs derived from diazo and oxim ligands for wastewater treatment Margarita Loredo-Cancino R. Chan-Navarro | N.E. Dávila-Guzmán | D.A. De Haro-Del Río | M. Vázquez-Mozencahuatzi |

  2. ADSORPTION Zheng et al. 2012 Liet al. 2015

  3. Adsorbentcharacteristics

  4. Adsorbents

  5. MOF • Metal ion and anorganicmolecule • 3D structures • High surfacearea (1500-7000 m2/g) • SeveralanalogousMOFs • Easytunability Xu et al. 2014, Rouquerolet al. 2014

  6. MOF

  7. Summary of MOFs as colorantadsorbent

  8. Objective

  9. Linker 1 5-formyl-8-hydroxyquinoline (precursor) 8-Hydroxyquinoline acid 4-amino benzoic linker 1

  10. Linker 2 4-formyl pyridine acid 4-amino benzoic

  11. Synthesis of coordinationpolymers

  12. Linker 1 4-amino acid benzoic P.F.=187-189 °C 5-formyl-8- hidroxyquinoline Linker 1 Yield = 92% Melting point = 300°C Color = yellow

  13. 2 3 4 9 10 5 11 14 15 8 H-(14, 16) 13 18 H-(11) H-(15,17) 19 7 6 1H PROTON NMR SPECTRA OF LINKER 1 1H (11) ~9.00ppm 1H (19) = 10.1 ppm 16 17 H-(2) H-(4) (García-López et al., 2014) H-(7) H-(3) H-(6) H-(19)

  14. 2 3 4 9 10 11 8 14 15 C17H12N2O3 13C (11) ~ 167 ppm 5 18 13 19 7 6 C15,C17 C14,C16 (García-López et al., 2014) 17 16 13C PROTON NMR SPECTRA OF LINKER 1 C5 C7 C6 C2 C4 C8 C18 C11 C19 C10 C3 C9 C13

  15. CHARACTERIZATION OF LINKER 2 Linker 2 Yield = 83% Melting point = 260 °C Color = white 5 4 3 7 10 11 6 14 9 15 2 1H and 13C PROTON NMR SPECTRA OF LINKER 2 13 12

  16. COORDINATION POLYMER 1 Ligante 1 PC 1 Yield = 83% Melting point  300 °C Color = Yellow

  17. Coordination polymer 2 Ligante 2 PC 2 Yield = 85% Melting point > 300 °C Color= white

  18. FT-IR SPECTRA OF LINKER 1 AND PC 1 (Reiss et al., 2015) (Mohammadikish, 2017) 3378 1608 υ (O-H)=3500-3000 cm-1 1638 1571 1697 υ (H2O)=3378 cm-1

  19. FT-IR SPECTRA OF LINKER 2 AND PC 2 (Reiss et al., 2015) (Mohammadikish, 2017) 3371 1608 υ (O-H)=3500-3000 cm-1 1645 1556 υ (H2O)=3371 cm-1 1697

  20. SUMMARY • Linkersweresuccessfullysyntethizedwithyieldabove 80%. • Precursor formationwasverifiedvia NMR 1H y 13C. • Zinc-linkercoordinationwasachieved and verifiedwiththedisplacement of C=O y C=N bands, as reported in literature.

  21. References Adhikari, Bimalendu, Goutam Palui, and Arindam Banerjee. 2009. “Self-AssemblingTripeptideBasedHydrogels and Their Use in Removal of DyesfromWaste-Water †.” 5(Scheme 1): 3452–60. Chang, L., Li, J., Duan, X., & Liu, W. (2015). Porouscarbonderivedfrom Metal-organicframework (MOF) forcapacitivedeionizationelectrode. Electrochimica Acta, 176, 956–964. http://doi.org/10.1016/j.electacta.2015.07.130 García-López, M. C., Muñoz-Flores, B. M., Jiménez-Pérez, V. M., Moggio, I., Arias, E., Chan-Navarro, R., & Santillan, R. (2014). Synthesis and photophysicalcharacterization of organotincompoundsderivedfromSchiff bases. Dyes and Pigments, 106(August), 188–196. http://doi.org/10.1016/j.dyepig.2014.02.021 Haque, E., Jun, J. W., & Jhung, S. H. (2011). Adsorptiveremoval of methylorange and methylenebluefromaqueoussolutionwith a metal organicframework material, ironterephthalate (MOF-235). Journal of HazardousMaterials, 185(1), 507–511. http://doi.org/10.1016/j.jhazmat.2010.09.035 Haque, E., Lee, J. E., Jang, I. T., Hwang, Y. K., Chang, J.-S., Jegal, J., & Jhung, S. H. (2010). Adsorptiveremoval of methylorangefromaqueoussolutionwith metal-organicframeworks, porouschromium-benzenedicarboxylates. Journal of HazardousMaterials, 181(1), 535–542. article. He, Qinqin, QiChen, MengmengLü, and XuetingLiu. 2014. “ChineseJournal of ChemicalEngineeringAdsorptionBehavior of Rhodamine B on UiO-66.” CJCHE 22(11–12): 1285–90. http://dx.doi.org/10.1016/j.cjche.2014.09.009. Hong-gui, D., Shuang-ling, J. I. N., Liang, Z., Yan-li, W., Bao-hua, L. U., Wen-ming, Q., & Li-cheng, L. (2012). Synthesis of porouscarbonsderivedfrom metal-organiccoordinationpolymers and theiradsorption performance forcarbondioxide. New CarbonMaterials, 27(3), 194–199. http://doi.org/10.1016/S1872-5805(12)60013-4. Inagaki, M., Toyoda, M., Soneda, Y., Tsujimura, S., & Morishita, T. (2016). Templatedmesoporouscarbons: Synthesis and applications. Carbon. http://doi.org/10.1016/j.carbon.2016.06.003

  22. Jiang, X. H., Wang, B. D., Yang, Z. Y., Liu, Y. C., Li, T. R., & Liu, Z. C. (2011). 8-Hydroxyquinoline-5-carbaldehyde Schiff-base as a highlyselective and sensitive Al 3+ sensor in weakacidaqueousmedium. InorganicChemistryCommunications, 14(8), 1224-1227. Leng, Chi-cheng, and Neville G Pinto. 1996. “AnInvestigation of theMechanisms of ChemicalRegeneration of ActivatedCarbon.” 5885(1994): 2024–31 Li, Xianghui et al. 2016. “AppliedSurfaceScience Fe-Based MOFs forEfficientAdsorption and Degradation of Acid Orange 7 in AqueousSolutionviaPersulfateActivation.” AppliedSurfaceScience 369: 130–36. http://dx.doi.org/10.1016/j.apsusc.2016.02.037. Li, Yu, KangZhou, Ming He, and JianfengYao. 2016. “Microporous and MesoporousMaterialsSynthesis of ZIF-8 and ZIF-67 UsingMixed-Base and TheirDyeAdsorption.” 234: 287–92. Lin, S., Song, Z., Che, G., Ren, A., Li, P., Liu, C., & Zhang, J. (2014). Adsorptionbehavior of metal-organicframeworksformethylenebluefromaqueoussolution. Microporous and MesoporousMaterials, 193, 27–34. http://doi.org/10.1016/j.micromeso.2014.03.004. Liu, B., Shioyama, H., Akita, T., & Xu, Q. (2008). Metal-organicframework as a templateforporouscarbonsynthesis. Journal of the American ChemicalSociety, 130(16), 5390–5391. Liu, Haochi, XiaohuiRen, and LigangChen. 2016. “Journal of Industrial and EngineeringChemistrySynthesis and Characterization of Magnetic Metal – Organic Framework fortheAdsorptiveRemoval of Rhodamine B fromAqueousSolution.” Journal of Industrial and EngineeringChemistry 34: 278–85. http://dx.doi.org/10.1016/j.jiec.2015.11.020. Mohammadikish, M. (2017). Facilesynthesis of novel zinc-based in fi nitecoordinationpolymernanoparticles. InorganicChemistryCommunications, 78, 48–51. http://doi.org/10.1016/j.inoche.2017.02.013

  23. Moradi, S. E., Dadfarnia, S., Shabani, A. M. H., Emami, S., Dadfarnia, S., Shabani, A. M. H., & Removal, S. E. (2015). Removal of congo red fromaqueoussolutionbyitssorptionontothe metal organicframework MIL-100 ( Fe ): equilibrium , kinetic and thermodynamicstudies. Desalination and WaterTreatment, 56(3), 710–722. http://doi.org/10.1080/19443994.2014.947328 Pandiaraj, Sekar, HarshithaBarikeAiyappa, Rahul Banerjee, and SreekumarKurungot. 2014. “Post Modification of MOF DerivedCarbonviagC 3 N 4 EntrapmentforanEfficient Metal-Free OxygenReductionReaction.” ChemicalCommunications 50(25): 3363–66. Reiss, A., Samide, A., Ciobanu, G., & Dabuleanu, I. (2015). Synthesis, spectralcharacterization and thermalbehaviour of new metal (ii) complexeswithschiff base derivedfromamoxicillin. Journal of theChileanChemicalSociety, 60(3), 3074–3079. Rouquerol, J., Rouquerol, F., Llewellyn, P., Maurin, G., & Sing, K. S. W. (2014). AdsorptionbyPowders and PorousSolids. AcademicPress. Wei, C., Li, X., Xu, F., Tan, H., Li, Z., Sun, L., & Song, Y. (2014). Metal organicframework-derivedanthill-likeCu@carbonnanocompositesfornonenzymaticglucose sensor. Anal. Methods, 6(5), 1550–1557. http://doi.org/10.1039/c3ay41764f Xu, H., Zhou, S., Xiao, L., Wang, H., Li, S., & Yuan, Q. (2015). Fabrication of a nitrogen-dopedgraphene quantum dotfrom MOF-derivedporouscarbon and itsapplicationforhighlyselectivefluorescencedetection of Fe 3+. Journal of MaterialsChemistry C, 3(2), 291–297. Yang, Cao, ShichuanWu, JianhuaCheng, and YuancaiChen. 2016. “Indium-Based Metal-Organic Framework / Graphite Oxide Composite as anEf Fi CientAdsorbent in theAdsorption of Rhodamine B fromAqueousSolution.” Journal of Alloys and Compounds 687: 804–12. http://dx.doi.org/10.1016/j.jallcom.2016.06.173. Yuan, Dingsheng et al. 2009. “Worm-likeMesoporousCarbonSynthesizedfrom Metal--OrganicCoordinationPolymersforSupercapacitors.” ElectrochemistryCommunications 11(6): 1191–94. Zou, Feng et al. 2014. “MOF-DerivedPorousZnO/ZnFe2O4/C OctahedrawithHollowInteriorsforHigh-RateLithium-Ion Batteries.” AdvancedMaterials 26(38): 6622–28.

  24. ¡THANKS FOR YOUR ATENTION!

  25. Purificación del precursor Extracción Soxlet Revelado cromatografía de capa fina Cromatografía de columna

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