120 likes | 209 Views
BioNuclear Concept v1. NETNUC 3.4.2009 Espoo Petteri Kangas, Iiro Auterinen and Pertti Koukkari. Assumptions. Chemical industry and transportation will be based on hydrocarbons in the future. Hydrogen and electricity can not subsidise hydrocarbons completely.
E N D
BioNuclear Concept v1 NETNUC 3.4.2009 Espoo Petteri Kangas, Iiro Auterinen and Pertti Koukkari
Assumptions • Chemical industry and transportation will be based on hydrocarbons in the future. Hydrogen and electricity can not subsidise hydrocarbons completely. • Bio-based hydrocarbons will be more and more suitable option both economically and politically. • Locally, like in Finland, bio material will be widely available. (Today annual growth in forests: 90 million m3 + agri biomass) • Forest sector owns remarkable amount of nuclear energy. (e.g. UPM: 25 % of electricity is nuclear based and UPM owns hundreds of megawatts nuclear power). => Nuclear energy (heat, steam and electricity) will be effectively used to boost the production of bio-based hydrocarbons
Heat available! 1200 MW at 180 C available from 3rd generation nuclear power plants. [1,2]
Short distances! Current biorefineries and nuclear power plants are near [3].
BioNuclear Concept v1Integrating promising biorefinery technologies with nuclear power
Picture by re-ality at flickr.com under CC-license Picture by swinginstan at flickr.com under CC-license Picture by Berner at lasol.fi Products Picture by churchhatetucker at flickr.com under CC-license
Technology maturity • Pilot scale technology available for • Black liquor and biomass gasification [4] • Biomass hydrolysis [5] • Full scale technology available for • Pulp mills • 3rd gen. nuclear power plants • Gas cleaning • FT-synthesis • Hydrocracking • Distillation
First results of black liquor gasification • 400 000 t/a pulp mill at Veitsiluoto • 660 000 t/a black liquor for gasification • 40 000 t/a diesel without extra hydrogen • 80 000 t/a diesel with additional hydrogen from nuclear PP • 40 000 t/a formic acid • Need for additional heat 45 MW (LP and MP steam) [6] • (75 MW of electricity for hydrogen production by electrolysis)
First results of cellulose hydrolysis • Variety of feedstock biomass (forest, agri, industrial and munipical) [5] • Wet biomass suitable for process (up to 50 %) • Residuals from hydrolysis can be processes in biomass gasification • Yield is good [7] • HP steam at 210 C is needed for hydrolysis. Steam and heat might be needed for distillation later in process • No mass / energy calculations available yet.
Next steps 2009 • Refining BioNuclear concept • Mass and energy balances for integrated mill • Estimations of nuclear heat, steam and electricity needs and potential • Possibly economic evaluation of the feasibility of process integration • Reporting BioNuclear concept v1 • Work will be done during autumn 2009.
References [1] Fortum, 2008. Ympäristö-vaikutusten arviointiselostus. [2] FENNOVOIMA, 2008. Ydinvoimalaitoksen ympäristövaikutusten arviointiselostus. [3] Google Maps, 2009. [4] CHEMREC, 2009. Turning Pulp Mills into Biorefineries. [5] Maine BioProducts, 2009. Maine BioProducts - Biofine – Process. [6] Larson, E.D. et al., 2006. A Cost-Benefit Assessment of Gasification-Based Biorefining in the Kraft Pulp and Paper Industry. Volume 1 - Main Report, Princeton University. [7] Girisuta, B., 2007. Levulinic Acid from Lignocellulosic Biomass. Dissertation. Rijksuniversiteit Groningen.