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Do Now:. decreases. 1. Atomic radius ________ from left to right across a period and _________ down the group. 2. Circle the element with the larger atomic radius . Justify your choice citing the trend in a sentence. Sodium vs. Rubidium
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Do Now: decreases 1. Atomic radius ________ from left to right across a period and _________ down the group. 2. Circle the element with the larger atomic radius. Justify your choice citing the trend in a sentence. Sodium vs. Rubidium Rubidium because atomic radius increases down the group. 3. What effect explains the trend in atomic radius across a period, despite an increasing number of electrons? Effective Nuclear Charge (Zeff) increases
Periodic Trends Unit 3 Lesson 3 Trend 2: Ionization Energy andTrend 3: Electron Affinity
Objectives • SWBAT use the trends in Ionization Energy and Electron Affinity to predict which elements will lose electrons and which will gain them by the element’s position on the periodic table. • SWBAT to predict which elements will lose or gain electron based on the element’s position on the periodic table.
Agenda • Defining Ionization Energy • The Ionization Energy Trend by Group • Why the I. E. Group Trend? Atomic Radius • The Ionization Energy Trend by Period • Why the I. E. Period Trend? Atomic Radius • Defining Electron Affinity • The Electron Affinity Trend by Group • Why the E. A. Group Trend? Atomic Radius • The Electron Affinity Trend by Period • Why the E. A. Period Trend? Atomic Radius • Valence Shells, A Simpler Explanation • Independent Practice
Comparison • Ionization Energy – How likely is an atom to lose an electron. • Electron Affinity – How likely an atom is to gain an electron.
Trend 2: Ionization Energy (Definition) • How likely is an atom to lose an electron. • Ionization Energy is defined as the amount of energy required to remove an electron from an atom or ion.
Ionization Energy Trend by Group • Ionization Energy decreases down the group. • Atoms are more likely to lose an electron down the group.
Ionization Energy Trend by Group Reason • Sodium because I. E. decreases down the group. • I. E. decreases down the group so Argon (period 3) has a higher 1st I. E. than Xenon (period 5) Which has a higher 1st I. E.? • Sodium or Cesium • Boron or Gallium • Xenon or Argon • Lead or Carbon
Why the I.E. Group Trend? Atomic Radius • As atomic radius increase, the valence electrons get further from the nucleus and are more weakly held. • Hence it requires less energy to remove them. Atomic Radius Increases
Agenda • Defining Ionization Energy • The Ionization Energy Trend by Group • Why the I. E. Group Trend? Atomic Radius • The Ionization Energy Trend by Period • Why the I. E. Period Trend? Atomic Radius • Defining Electron Affinity • The Electron Affinity Trend by Group • Why the E. A. Group Trend? Atomic Radius • The Electron Affinity Trend by Period • Why the E. A. Period Trend? Atomic Radius • Valence Shells, A Simpler Explanation • Independent Practice
Ionization Energy Trend by Period • Ionization Energy ___________from left to right across the period. • Atoms are _____ likely to lose an electron. increases less
Ionization Energy Trend by Period Reason • Oxygen because I. E. increases across the period. • I. E. increases across the period so Si (group 13) has a higher 1st I. E. than Mg (group 2) Which has a higher 1st I. E.? • Oxygen or Carbon • Phosphorous or Argon • Hydrogen or Helium • Silicon or Magnesium
Why the I.E. Period Trend? Atomic Radius • As atomic radius decreases, the valence electrons get closer to the nucleus and are more tightly held. • Hence it requires more energy to remove them. Atomic Radius Increases
Summary of Trends 1-2 I. E. Increases Atomic Radius Decreases I. E. Decreases Atomic Radius Increases
Agenda • Defining Ionization Energy • The Ionization Energy Trend by Group • Why the I. E. Group Trend? Atomic Radius • The Ionization Energy Trend by Period • Why the I. E. Period Trend? Atomic Radius • Defining Electron Affinity • The Electron Affinity Trend by Group • Why the E. A. Group Trend? Atomic Radius • The Electron Affinity Trend by Period • Why the E. A. Period Trend? Atomic Radius • Valence Shells, A Simpler Explanation • Independent Practice
Trend 3: Electron Affinity (Definition) • Electron Affinity is defined as the energy change that occurs when a neutral atom gains an electron.
Electron Affinity Trend by Group ? • A positive energy change means that the resulting anion is more stable and that energy is released into the system.
Electron Affinity Trend by Group • Electron affinity decreasesdown the group. • Atoms are less likely to steal an electron down the group. E. A. decreases
Electron Affinity Trend by Group Reason • Sodium because E. A. decreases down the group. • E.A. decreases down the group so Argon (period 3) has a higher 1st E. A. than Xenon (period 5) Which has a higher 1st E. A.? • Sodium or Cesium • Boron or Gallium • Xenon or Argon • Lead or Carbon
Why the E.A. Group Trend? Atomic Radius • As atomic radius increase, the valence electrons get further from the nucleus and are more weakly held. • Hence atoms have a more difficult time stealing electrons. Atomic Radius Increases
Agenda • Defining Ionization Energy • The Ionization Energy Trend by Group • Why the I. E. Group Trend? Atomic Radius • The Ionization Energy Trend by Period • Why the I. E. Period Trend? Atomic Radius • Defining Electron Affinity • The Electron Affinity Trend by Group • Why the E. A. Group Trend? Atomic Radius • The Electron Affinity Trend by Period • Why the E. A. Period Trend? Atomic Radius • Valence Shells, A Simpler Explanation • Independent Practice
Electron Affinity Trend by Period • Electron affinity ___________from left to right across the period. • Atoms are _____ likely to gain an electron. increases more E. A. increases
Electron Affinity Trend by Period Reason • Oxygen because E. A. increases across the period. • E.A. increases across the period so Si (group 13) has a higher E.A. than Mg (group 2) Which has a higher 1st E. A.? • Oxygen or Carbon • Phosphorous or Argon • Hydrogen or Helium • Silicon or Magnesium
Why the E.A. Period Trend? Atomic Radius • As atomic radius decreases, the valence electrons get closer to the nucleus and are more tightly held. • Hence it requires less energy to gain an electron. Atomic Radius Increases
Summary of Trends 1-3 E. A. Increases I. E. Increases Atomic Radius Decreases E. A. Decreases I. E. Decreases Atomic Radius Increases
Agenda • Defining Ionization Energy • The Ionization Energy Trend by Group • Why the I. E. Group Trend? Atomic Radius • The Ionization Energy Trend by Period • Why the I. E. Period Trend? Atomic Radius • Defining Electron Affinity • The Electron Affinity Trend by Group • Why the E. A. Group Trend? Atomic Radius • The Electron Affinity Trend by Period • Why the E. A. Period Trend? Atomic Radius • Valence Shells, A Simpler Explanation • Independent Practice
Valence Electrons: A Simple Explanation • Atoms prefer full Valence Shells. • Which group has full Valence Shells? _________________________ Group 18: The Noble Gases
Valence Electrons: A Simple Explanation • Atoms will lose (____) or gain (____) electrons in order to acquire a full valence shell I.E. E.A. More likely to ____e- More likely to ____e- lose gain
Independent Practice • Let’s see what you’ve learned.