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MODERN PHYSICS. Going inside the Atom. Light is a wave. Or is it?. Wave-Particle Duality. Photoelectric Effect (light behaves like a particle) Compton Effect (light behaves like a particle) Entirely new theory needed!. Quantum Theory.
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MODERN PHYSICS Going inside the Atom
Light is a wave. Or is it?
Wave-Particle Duality • Photoelectric Effect (light behaves like a particle) • Compton Effect (light behaves like a particle) • Entirely new theory needed!
Quantum Theory • Electromagnetic energy is emitted from and absorbed by matter in discrete amounts or packets (a quantum). • The amount of energy of a quantum is given by E = hf, where h is Planck’s constant and f is the frequency of the radiation. • The quantum of electromagnetic energy is called a photon.
Models of the Atom • Thomson’s Model (M&M cookie) • Rutherford’s Model • Bohr Model
Assumptions of the Bohr Atom I • All forms of energy are quantized, that is, an electron can gain or lose kinetic energy only in fixed amounts, or quanta. • The electron in the hydrogen atom can occupy only certain specific orbits of fixed radius and no others.
Assumptions of the Bohr Atom II • The electron can jump from one orbit to a higher one by absorbing a quantum of energy in the form of a photon. • Each allowed orbit in the atom corresponds to a specific amount of energy. The orbit nearest the nucleus represents smallest amount of energy that the electron can have. Electrons do not lose energy in these orbits.
Energy Level Diagrams • When an electron falls from a higher energy level to a lower one, the atom emits a photon with energy equal to the difference between the energies of the initial and final states. • Ephoton = Ei - Ef • See Reference tables