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FTCE Chemistry SAE Preparation Course. Session 2. Lisa Baig Instructor. Course Outline. Session 1 Review Pre Test Competencies 1 & 2 Session 2 Competency 5 Session 3 Competency 3 Session 4 Competency 4 Session 5 Competencies 6, 7 and 8 Post Test. Session Norms. Respect
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FTCE Chemistry SAEPreparation Course Session 2 Lisa Baig Instructor
Course Outline Session 1 Review Pre Test Competencies 1 & 2 Session 2 Competency 5 Session 3 Competency 3 Session 4 Competency 4 Session 5 Competencies 6, 7 and 8 Post Test
Session Norms • Respect • No side bars • Work on assigned materials only • Keep phones on vibrate • If a call must be taken, please leave the room to do so
Homework Review Any questions from last night?
Chemistry Competencies • Knowledge of the nature of matter (11%) • Knowledge of energy and its interaction with matter (14%) • Knowledge of bonding and molecular structure (20%) • Knowledge of chemical reactions and stoichiometry (24%) • Knowledge of atomic theory and structure (9%) • Knowledge of the nature of science (13%) • Knowledge of measurement (5%) • Knowledge of appropriate laboratory use and procedure (4%)
73Li 42He11H Atomic NumberMass Number Element Symbol
Two Key Numbers • Atomic Number • # of Protons in an atom • This determines the type of element you have! • If atom is electrically neutral, then the number of electrons is also equal to this number • Mass Number • # of protons + neutrons in an atom’s nucleus • Mass # - atomic # = # of neutrons
How many protons, neutrons and electrons? • Iodine-128 • 4120Ca • 20882Pb4+ • 8135Br1- • Cobalt-60
S Orbital • Orbital that can contain 2 electrons • Spherical in Shape
P Orbitals • Orbital that can contain up to 6 electrons • Contains 3 sub-orbitals, each holding 2 electrons • “Peanut” or “Dumbbell” shaped
D Orbital • Orbital that can contain up to 10 electrons • Contains 5 sub-orbitals that can each hold 2 electrons
F Orbital • Orbital that can contain up to 14 electrons • Contains 7 sublevels each holding 2 electrons
P S D-1 F-2
This is the order used to place electrons- follow the arrows to their “end”, then move to the next arrow 1s 2s 2p 3s 3p 3d 4s 4p 4d 4f 5s 5p 5d 5f 6s 6p 6d 7s 7p 8s
Find the Arrangements for: • Sulfur • Strontium • Copper • Lead • Radon
Alkali Metals • HIGHLY Reactive Metals • 1 valence electron • Filling their “S” orbital • Do not occur naturally in nature as elements • ALWAYS found in compounds • React with water with increasing violence as atomic number increases
Alkaline Earth Metals • 2 valence electrons • Fill their “S” orbitals • Do not occur in nature as elements • ALWAYS in compounds • Less reactive than the Alkali Metals
Transition Metals Al Ga Sn In Tl Pb Bi
Transitional Metals • Most have 2 valence electrons • These fill their “D” sublevels • Harder and more brittle than the other metals • High melting and boiling points • Good heat and electrical conductors • Hg- the ONLY metal to be in the liquid state at room temperature • Often have colored compounds
Lanthanide Series • Elements Ce thru Lu • Once called the “Rare Earth Metals” • Fill their 4f orbitals • All elements within this section have amazingly similar chemical and physical properties • This lead to the difficulty in identification of the elements in this section
Actinide Series • Elements Th thru Lr • Fill their 5f orbital • All elements are radioactive • Beyond Uranium, these elements have been artificially created
Metalloids B Si Ge As Sb Te Po At
Metalloids/Semi-Metals • All are solids at room temperature • Semi-conductors of heat and electricity • Some metal properties and non-metal properties • Fill their “P” level electrons
Non-Metals • Poor (Non) Conductors of heat and electricity • Reactive • Diatomic Elements • Gas • Nitrogen, Oxygen, Hydrogen • Solid • Carbon, Phosphorus, Sulfur, Selenium
Halogens • Diatomic Elements or found in compounds • HIGHLY Reactive • Gases= Fluorine, Chlorine • Liquid = Bromine • Solid = Astatine, Iodine
Noble Gases • Non-Reactive • We have FORCED it to react and form compounds with Fluorine • Uses: • Neon, Argon, Krypton and Xenon are used for lighting • Helium is used in balloons
Break Time Take a 10 minute break!
Calculating C = lx v C = Speed of Light 3 x 108m/s l = wavelength v= frequency
Practice What is the frequency of a wave whose wavelength is 4.5x10-5m? • C = lx v • 3x108m/s= 4.5x10-5m •v • 3x108m/s = 4.5x10-5m = 6.7 x 1012 Hz
What’s a Quantum?? The amount of energy that can be gained or lost by an atom E = h x v E = Energy of Quantum h = 6.626 x 10-34J•s (Planck’s Constant) v = frequency of the wave
Practice • What is the energy of a wave whose frequency is 2.5x10-4Hz? • E = h x v • E= (6.626 x 10-34 J•s)(2.5x10-4Hz) • E=1.65x10-37J
Conversions of Mass and Energy E = mC2 E = Energy m = mass C = Speed of Light (3 x 108m/s)
Practice • What is the mass of a particle whose energy is 2.41x10-27J? • E = mC2 2.41x10-27J = m (3 x 108m/s)2 2.68x10-44kg
Break Time Take a 10 minute break!
Unstable Nuclei Radioactive Decay Spontaneous disintegration of a nucleus into a smaller sized nucleus Nuclear Radiation Particles emitted by a decaying nucleus All elements above #83 on the Periodic Table
Two Categories Fission When a heavy nuclei splits into more stable nuclei of intermediate mass Fusion When low mass nuclei combine to form a heavier more stable nucleus
Nuclear Reactions 4219K 0-1e + ? 4240Ca 23994Pu ? + 23592U 42He 2713Al + 42He 3015P + ? 10n ? + 10n 14256Ba + 9136Kr + 310n 23592U
Half-Lives Remaining Mass = half-life fraction Total Mass 1 = ½ 2 = ¼ 3 = 1/8 4 = 1/16 5 = 1/32 6 = 1/64 7 = 1/1288 = 1/256 # h.l = time elapsed time of 1 h.l Amount remaining = (original)(1/2)#h.l
Practice How much of a 100.0g sample of Gold-198 remains after 8.10 days if its half life is 2.70 days? 12.5g A 50.0g sample of 14N decays to 12.5g in 14.4 seconds. What is its half-life? 7.2 seconds
Homework • Diagnostic Exam in your AP chem Prep book- Page 17-26 • Only answer the questions for these Chapters & Questions • Chapter 5 #1, 3, 5 • Chapter 10 #32-35 • Chapter 17 #81-84