110 likes | 201 Views
THE ELECTRONIC PROPERTIES AND STEREOCHEMISTRY OF THE COPPER(II) ION-VIII. MONO(ETHYLENEDIAMINE)- AND MONO(2,2'-BIPYRIDYL)-COPPER(II) COMPLEXES. 1. M. PROCTER, B. J. HATHAWAY* and P. G. HODGSON Chemistry Department, University of Essex, Colchester, Essex and University College, Cork
E N D
THE ELECTRONIC PROPERTIES ANDSTEREOCHEMISTRY OF THE COPPER(II)ION-VIII.MONO(ETHYLENEDIAMINE)- AND MONO(2,2'-BIPYRIDYL)-COPPER(II) COMPLEXES 1. M. PROCTER, B. J. HATHAWAY* and P. G. HODGSON Chemistry Department, University of Essex, Colchester, Essex and University College, Cork (Received 18January 1972)
Synthesis, X-ray Structure, Single-Crystal EPR and 1H NMR Studies of a Distorted Square Planar Cu(salEen)2(ClO4)2 Complex in a Novel Bilayered Architecture: salEen =N,N-Diethylethylenesalicylidenamine P. S. Subramanian, E. Suresh, and D. Srinivas* Inorg. Chem. 2000, 39, 2053-2060
X-band EPR spectra of Cu(salEen)2(ClO4)2 at 77 K: (a)polycrystals; (b) CHCl3; (c) pyridine; (d) DMF; (e) MeOH.
g//=2.331. g⊥=2.080.
HO-(CH2)11NHP(O)PPy2Cu(OTf)2 g =2.0586
Au-L-Cu g =2.0932
The EPR spectrum of complex 41 (Figure 13) in the powder state is of axial symmetry with g∥=2.305 and g⊥=2.049. Organometallics 2001, 20, 673-690
Enantioselectivity promotion by achiral surface functionalizationon SiO2-supported Cu-bis(oxazoline) catalystsfor asymmetric Diels–Alder reactionsSatoka Tanaka, Mizuki Tada, Yasuhiro Iwasawa ∗ Journal of Catalysis 245 (2007) 173–183