1 / 39

Andrija Mohorovičić Geophysical Institute Department of Geophysics , Faculty of Science

AMGI/EURASAP Workshop Air Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007. Andrija Mohorovičić Geophysical Institute Department of Geophysics , Faculty of Science University of Zagreb, Croatia. Zvjezdana Bencetić Klaić zklaic@rudjer.irb.hr.

fathia
Download Presentation

Andrija Mohorovičić Geophysical Institute Department of Geophysics , Faculty of Science

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia Zvjezdana Bencetić Klaićzklaic@rudjer.irb.hr The European Association for the Science of Air Pollution MAJOR AIR QUALITY CONCERNS IN CROATIA • Pollutants? • Sources? • Incidents!

  2. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Main pollutants (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ ) SOx (SO2 and SO3) NOx (NO2 and NO) Gaseous: NH3 NMVOC CO

  3. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Main pollutants (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ ) TSP Particulates: (PM10) (PM2.5)

  4. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Main pollutants (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ ) Arsenic (As) Cadmium (Cd) Chromium (Cr) Copper (Cu) Mercury (Hg) Nickel (Ni) Lead (Pb) Selenium (Se) Zinc (Zn) Heavy metals:

  5. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Main pollutants (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ ) Lindane (HCH) Pentachlorophenol (PCP) Hexachlorobenzene (HCB) Dioxins and Furans (DIOX) Polycyclic aromatic hydrocarbons (PAHs) Persistent organic pollutants:

  6. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Main pollutants (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ ) Short Chained Chlorinated Paraffins (SCCP) Polychlorinated biphenyls (PCBs) Aldrin Chlordane Chlordecone Persistent organic pollutants:

  7. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Main pollutants (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ ) Dichlorodiphenyl-trichloroethane (DDT) Dieldrin Heptachlor Hexabromobiphenyl Mirex Toxaphene Persistent organic pollutants:

  8. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Croatian anthropogenic emissions, gaseous (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) (103 kg/year)

  9. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Intercomparison (2000) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/ ) Austria Croatia (2000) Germany Croatia (1990) Germany France Slovakia Croatia (2000) Bulgaria Italy EU Austria Poland UK Czech Republic EU Slovakia Italy Croatia (1990) France UK Poland Slovenia Slovenia USA Czech Republic Bulgaria USA kg SO2 / inhabitant kg NOx / inhabitant

  10. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Croatian anthropogenic emissions, gaseous (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) (103 kg/year)

  11. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Croatian anthropogenic emissions, particulates (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) (103 kg/year)

  12. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Croatian anthropogenic emissions, heavy metals (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) (kg/year)

  13. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Croatian anthropogenic emissions, heavy metals (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) (kg/year)

  14. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Croatian anthropogenic emissions, persistent organic pollutants (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) (kg/year)

  15. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Sources of acidifying gases (SO2, NOx, NH3) (2002) Burning -energy production 16 % Burning – non-industrial 4 % Agriculture 42 % Burning – industrial 13 % (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) Road traffic 12 % Production processes 6 % Other mobile sources and machines 7 %

  16. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Other mobile sources and machines 4 % Road traffic 8 % SO2 (2002) Production processes 9 % Burning -energy production 35 % Burning – industrial 34 % (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) Burning – non-industrial 10 %

  17. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution NOx (2002) Other mobile sources and machines 23 % Burning - energy production 19 % Burning – non-industrial 5 % Burning –industrial 10 % (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) Production processes 2 % Road traffic 41 %

  18. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Other sources 1 % Other mobile sources and machines 9 % CO (2002) Burning – non-industrial 32 % (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) Road traffic 49 % Burning –industrial 9 % Production processes 1 %

  19. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Production processes 5 % NH3 (2002) Road traffic 1 % (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) Agriculture 94 %

  20. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Particles (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) PM10 TSP PM2.5

  21. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Burning –industrial 1 % Pb (2002) Burning - energy production 1 % Production processes 4 % Other sources 1 % Road traffic 93 % (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

  22. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Fossil fuel and geothermal energy distribution 1 % Waste treatment and deposition 2 % Hg (2002) Production processes 3 % Burning – energy production 36 % Burning –industrial 30 % (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/) Burning – non-industrial 28 %

  23. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Other heavy metals (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

  24. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Persistent organic pollutants (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

  25. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Main individual SO2 sources (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

  26. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Main individual NOx sources (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

  27. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Main individual CO sources (2002) (source: Ministry of Environmental Protection, Physical. Planning and Construction of the Republic of Croatia, http://www.mzopu.hr/)

  28. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Some hot spots 2 1. Rijeka 20% of Croatian SO2 (2002) from oil refinery and TE 4 1 3 5 2. Zagreb 4% of Croatian NOx (2002) from TE-TO and EL-TO 3. Sisak 15% of CroatianSO2 (2002) from oil refinery and TE 4. Kutina 9% of CroatianSO2 (2002) from Petrokemija 5. Plomin 6% of CroatianSO2 and 5% NO2 (2002) from TE

  29. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Current state network 2 4 1 3 5 http://zrak.mzopu.hr/glavni.asp

  30. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Recent serious incidents - 1 2 4 1 3 6 Karlovac, 23 February 2007 5 Beer factory –unlawful CO2 emission  1 died

  31. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Recent serious incidents - 2 2 4 1 3 Sisak, January 2007 5 Oil refinery– H2S pollution

  32. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Recent serious incidents - 2 H2S (µg m-3) – daily 6. Sisak, January 2007 C6H6 (µg m-3) – daily Oil refinery– H2S pollution 1, 13 and 16 January PM10 (µg m-3) – daily http://zrak.mzopu.hr/

  33. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Recent serious incidents - 2 CO (µg m-3) – hourly H2S (µg m-3) – hourly Sisak, 1 January 2007 C6H6 (µg m-3) – hourly PM10 (µg m-3) – hourly http://zrak.mzopu.hr/

  34. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Recent serious incidents - 2 CO (µg m-3) – hourly values H2S (µg m-3) – hourly values Sisak 13 – 16 January 2007 C6H6 (µg m-3) – hourly values PM10 (µg m-3) – daily values http://zrak.mzopu.hr/

  35. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Recent serious incidents – 3 NO2 Sisak 20 February 2007; 15:15 Crude oil spill  100 m high jet CO H2S SO2 C6H6 PM10

  36. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution More about Sisak 1 - 12 April 2007 H2S (µg m-3) – daily PM10 (µg m-3) – daily SO2 (µg m-3) – daily

  37. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Recent serious incidents – 4 2 4 1 3 Rijeka, 3 - 5 February 2002 5 Jeričević et al., 2004 On 4 February a warning was sent out to the public not to expose outdoors!

  38. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Other sites Kutina, PM10 Rijeka2, O3 Zagreb1, NO2 Zagreb1, PM10 Zagreb3, O3 Osijek, PM10

  39. AMGI/EURASAP WorkshopAir Quality Management, Monitoring, Modeling, and Effects Zagreb, May 24-26, 2007 Andrija Mohorovičić Geophysical Institute Department of Geophysics, Faculty of Science University of Zagreb, Croatia The European Association for the Science of Air Pollution Conclusion • Old technologies • Unlawful emissions • Answers?

More Related