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HBr , V(m+4) (and E(0 )) ( Updated 131211; slide : 24-6) KER spectra vs J´ ( slides 2-3)

HBr , V(m+4) (and E(0 )) ( Updated 131211; slide : 24-6) KER spectra vs J´ ( slides 2-3) I(H + + Br (1/2))/I(H + + Br (3/2)) vs . J´( slide 4) Comparison of KER spectra for E(0) and V(m+4); J´= 1 ( slide 5) Wavel . Calibr . ( slide 6) Ref:

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HBr , V(m+4) (and E(0 )) ( Updated 131211; slide : 24-6) KER spectra vs J´ ( slides 2-3)

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  1. HBr, V(m+4) (and E(0)) (Updated 131211; slide: 24-6) KER spectravs J´ (slides 2-3) I(H+ + Br(1/2))/I(H+ + Br(3/2)) vs. J´(slide 4) Comparison of KER spectra for E(0) and V(m+4); J´= 1 (slide 5) Wavel. Calibr. (slide 6) Ref: agust-lab-top,C:/…/PPT-131111.pptx

  2. HBr, V(m+4): H+ + Br(3/2) H+ + Br(1/2) J´= 8 7 6 5 4 3 2 1 0 ? ? H+ <- HBr+(v´) KER/eV Agust,labtop,C:/…/PXP-131111.pxp ; Gr0, Lay1

  3. HBr, V(m+4): H+ + Br(1/2) H+ + Br(3/2) J´= 8 7 6 5 4 3 2 1 0 ? BLUE sticks:Predicted KER For 81Br; Seenextslide Blacksticks: H+ + Br- KER/eV Agust,labtop,C:/…/PXP-131111.pxp ; Gr0, Lay1; (<= Agust, Labtop, C:,…./XLS-131111a.xlsx („KER,I,II“ ,“H++Br-“))

  4. HBr, V(m+4) I(H+ + Br(1/2)) I(H+ + Br(3/2)) J´ Agust,labtop,C:/…/PXP-131111.pxp ; Gr1, Lay0 (<= Agust, Labtop, C:,…./XLS-131111.xlsx

  5. Comparisons of E(0) and V(m+4): E(0) and V(m+4) J´= 1 KER/eV Agust,labtop,C:/…/PXP-131111.pxp ; Gr2, Lay2

  6. Let´s checkwavelengths and wavelengthcalibrations: agust, Labtop, C:,…./XLS-131111a.xlsx & XLS-131112.xlsx(„wavel.calibr.“ ))

  7. / Cont. agust, Labtop, C:,…./XLS-131111a.xlsx & XLS-131112.xlsx(„wavel.calibr.“ ))

  8. HBr V(m+5) & E(0) & V(m+4) J´= 1 INCORRECT KER predictions for E(0) & V(m+4) Seeslide 11 KER/eV Agust,labtop,C:/…/PXP-131113.pxp ; Gr2, Lay2

  9. „V(m+4)“ „J´=11“ is a Rydb. State (possibly F1D2(v´=0)) S line, J´= 7) Seeslide 16 „J´=11“ 77281,75218 „J´=10“ is V(m+3), S line, J´= 4 Seeslide 16 77367,56176 KER/eV Agust,labtop,C:/…/PXP-131111.pxp ; Gr4, Lay3; numbers: …XLS-131111.xlsx

  10. „V(m+4)“ „J´=11“ is a Rydb. State (possibly F1D2(v´=0) S line, J´= 7)???? Seeslide 16 77281,75218 cm-1 „J´=10“ is V(m+3), S line, J´= 4 Seeslide 16 77367,56176 cm-1 KER/eV Agust,labtop,C:/…/PXP-131111.pxp ; Gr4, Lay3; numbers: …XLS-131111.xlsx

  11. HBr, REMPI spectra (fromIceland): V(m+3) Ryd. State 77282 cm-1 H79Br+ 79Br+ H+ H81Br+ 81Br+ 2hv Agust,labtop,C:/…/HBr 77180_79080-131114ak.pxp ; Gr1, Lay0

  12. J´= 5,6,7,8,9 Red=predictions J´= 5,6,7,8,9 „J´=11“ is a Rydb. State J‘‘= 7! 77281,75218 cm-1 „J´=10“ is V(m+3), S line, J´= 4 Seeslide 16 77367,56176 cm-1 KER/eV Agust,labtop,C:/…/PXP-131111.pxp ; Gr4, Lay3; numbers: …XLS-131111.xlsx; predictions: XLS-131114.xlsx

  13. Br 4D(5/2)<-<-2P(3/2) agust,labtop,C:/…HBr82100_82400.pxp XLS-131114.xlsx

  14. Br 2P3/2 <-<- 2P3/2 https://notendur.hi.is/agust/rannsoknir/papers/HBr/jcp136-214315-12.pdf XLS-131114.xlsx

  15. Br 2P1/2 <-<- 2P1/2 https://notendur.hi.is/agust/rannsoknir/papers/HBr/jcp136-214315-12.pdf XLS-131114.xlsx

  16. KER (Br) vsvariousBr+ formationchannels: Seeagust-labtop,C:/…/XLS-131114.xlsx HBr, E(0) Br**(Ry) Br/Br*- 1hv Br/Br* - 2hv (3hv) J´ agust-labtop,C:/ …/XLS-131114.xlsx

  17. J´= 8 6 3 1 J´= 3 1 V(m+5) E(0) J´= 8 6 1 V(m+4)

  18. HBrenergetics H+ + Br*(3/2) [22P].. [ B2S].. H* + Br*(1/2) H* + Br(3/2) H+ + Br- H + Br**(5s) [ 4P,5s ]3P V/Ion-pair Ry

  19. HBrenergetics H+ + Br*(3/2) [22P].. [ B2S].. HBr+(v+) H* + Br*(1/2) H* + Br(3/2) H+ + Br- H + Br**(5s) [ 4P,5s ]3P V/Ion-pair Ry ? Or directHBr+ formation

  20. HBrenergetics H+ + Br*(1/2) [22P].. [ B2S].. H* + Br*(1/2) H* + Br(3/2) H+ + Br- H + Br**(5s) [ 4P,5s ]3P V/Ion-pair Ry

  21. H++Br+e H+Br+ + e H+ + Br- H*(n=2)+Br H + Br**(5s) Br*(1/2) Br(3/2) Agust-labtop,C:/../Fig.1-HBrFvsV-papera.pxp

  22. [(3)2P] ..superexcitedstate [B2S+] ..superexcitedstate H++Br+e HBr+*(A) H+Br+ + e H+ + Br- H*(n=2)+Br H + Br**(5s) [4P,5s] Rydb. HBr+(X) Br*(1/2) Br(3/2) Agust-labtop,C:/../Fig.1-HBrFvV-paperb.pxp

  23. [(3)2P] ..superexcitedstate [B2S+] ..superexcitedstate H++Br+e HBr+*(A) H+Br+ + e H+ + Br- H*(n=2)+Br H + Br**(5s) [4P,5s] Rydb. HBr+(X)

  24. I(H+<- HBr+(v+)) I(H+ + Br(3/2)) ratio J´ https://notendur.hi.is/~agust/rannsoknir/Crete/XLS-131211.xlsx https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131211a.pxp ; Gr5, Lay4

  25. I(H+ + Br(1/2)) I(H+ + Br(3/2)) V(m+5) J´=0 ratio V(m+4) J´=0 J´=1 E(0) E(J´) https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131211.pxp; Gr3, Lay3

  26. J´=0 I(H+<- HBr+(v+)) I(H+ + Br(3/2)) J´=1 V(m+5) ratio E(0) J´=0 V(m+4) E(J´) https://notendur.hi.is/~agust/rannsoknir/Crete/E0-KER-131211b.pxp; Gr3, Lay3

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