1 / 9

Dichlorodiazirine: A Nitrogenous Precursor for Dichlorocarbene

Dichlorodiazirine: A Nitrogenous Precursor for Dichlorocarbene. Gaosheng Chu, Robert A. Moss,* and Ronald R. Sauers* J. Am. Chem. Soc. 2005 , 127, 14206-14207. Jones, M., Jr.; Sachs, W. H.; Kulczycki, A., Jr.; Waller, F. J. J. Am. Chem. Soc. 1966 , 88 , 3167.

florence-brady
Download Presentation

Dichlorodiazirine: A Nitrogenous Precursor for Dichlorocarbene

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. Dichlorodiazirine: A Nitrogenous Precursor for Dichlorocarbene Gaosheng Chu, Robert A. Moss,* and Ronald R. Sauers* J. Am. Chem. Soc. 2005, 127, 14206-14207

  2. Jones, M., Jr.; Sachs, W. H.; Kulczycki, A., Jr.; Waller, F. J. J. Am. Chem. Soc. 1966, 88, 3167 Hartwig, J. F.; Jones, M., Jr.; Moss, R. A.; Lawrynowicz, W. Tetrahedron Lett. 1986, 27, 5907 Presolski, S. I.; Zorba, A.; Thamattoor, D. M.; Tippmann, E. M.; Platz, M. S. Tetrahedron Lett. 2004, 45, 485

  3. Moss, R. A.; Chu, G.; Sauers, R. R. J. Am. Chem. Soc. 2005, 127, 2408

  4. NMR Monitoring

  5. Possible Mechanism DCD

  6. Relative Reactivity for Various Substrates

  7. Relative Reactivity for Various Substrates

  8. UV Spectrum of DCD in Pentane

  9. UV Spectrum of 12 in Pentane

More Related