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Learn how to balance chemical equations and calculate empirical formulas with step-by-step instructions. Perfect for chemistry students.
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Warm Up: • Which of the following represents an empirical formula? • C6H8O6 • C2H4 • C3H4O3 • C7H14
What are the empirical and molecular formulas for a compound with 86.88% carbon and 13.12% hydrogen and a molecular weight of 84 g? • Empirical 86.88 g C / 12g = 7.24 mol / 7.24 = 1 13.12 g H / 1 g= 13.12 mol / 7.24 = 1.8 CH2
Molecular 84/14= 6 C6H12
Al + O2 reactants (aka reagents) products yields → Al2O3
The Law of Conservation of Mass • states that the mass of the reactants equal the mass of the products • Atoms cannot be created nor destroyed in a chemical change—therefore, the number of each type of atom on each side of the reaction must be equal • Coefficients are used to balance chemical reactions
Al + O2 → Al2O3 • Is this equation balanced? Left side: Right side: Al O
___Al + ___O2 → ___Al2O3 • Balance this equation
Choosing which atom to start with • Start with elements that appear only one time on each side and elements that are in the most complex compounds. • End with elements that appear more than once on a side or elements that appear uncombined on one side or the other.
Inspection Method • Make a list of the elements in the reaction • Count the number of each type of atom on each side of the reaction • Add coefficients to balance the number of atoms • When all elements are balanced, place a “1” in any empty coefficient location
Never touch subscripts when balancing equations since that will change the composition and therefore the substance itself. • Check to be sure that you have included all sources of a particular element that you are balancing on a particular side since there may be two or more compounds that contain the same element on a given side of an equation. • Adjust the coefficient of mono atomic elements near the end of the balancing act since any change in their coefficient will not affect the balance of other elements • When there are a group of atoms that are acting as a unit such as a polyatomic ion and they appear intact on both sides of the equation, it is best to balance them as a self contained group.
Polyatomic Ions • Ions: atom or molecule which has gained or lost electrons giving it a negative or positive charge • Anion = negative ion • Cation = positive ion • Polyatomic: more than 1 atom • Table E
___NH3+___O2 →___NO+___H2O • Balance this equation 4 NH3+5 O2 →4 NO+6 H2O When you’re done…check to make sure you have the lowest whole number coefficients and the equation cannot be reduced
Combustion Equation • ___CH4 + ___O2 ___CO2 + ___H2OBalance this equation 1 CH4 + 2 O2 1 CO2 + 2 H2O
1 CH4 + 2 O2 1 CO2 + 2 H2O • If 44 g of methane (CH4) reacted, how many moles of water were produced? 44 g x 1 mol CH4= 2.75 mol CH4 16 g 2.75 mol CH4 x 2 mol H2O = 5.5 1 mol CH4 mol H2O
CaCl2 + AgNO3 AgCl + Ca(NO3)2 • Using the above unbalanced equation, calculate how many grams of AgCl will be produced if 100 g of CaCl2 reacts?
CaCl2 + 2AgNO3 2AgCl + Ca(NO3)2 100 g CaCl2 x 1 mol CaCl2 = 0.90 mol CaCl2 111 g CaCl2 0.90 mol CaCl2 x 2 mol AgCl = 1.8 mol AgCl 1 mol CaCl2 1.8 mol AgCl x 143.5 g AgCl = 258.3 g AgCl 1 mol AgCl