530 likes | 566 Views
Learn the importance of composition in chemistry, counting atoms by mass, molar mass, and Avogadro’s number. Practice with examples and explore real-life applications of chemical formulas.
E N D
Mole, Avogadro’s Number Molar Mass Mass percent composition Empirical Formula
Why is Knowledge of Composition Important? • Everything in nature is either chemically or physically combined with other substances • Some Applications: • the amount of sodium in NaCl for diet • the amount of iron in iron ore for steel production • the amount of carbon in fossil fuel in terms of green house effect
Counting Pennies by Weight • What if a person doesn’t have bills but pounds of pennies when he wants to buy a $10 pizza? • Seinfeld: Kramer’s attempt to buy calzone with pennies https://www.youtube.com/watch?v=ywidjw9oQVw • http://www.youtube.com/watch?v=kMimygVTgbU • Assuming each penny weighs exactly the same (2.500 g), we can count pennies by weight the total weight of pennies…
Counting Pennies by Weight Kramer brought 2,500. g (ca. 5.5 lbs) of new pennies to the Italian restaurant. Do you think he can buy three calzones ($10.0 total)? Each new penny weighs 2.500 g.
Counting Coins by Weight • What if Kramer bought a different coin? • Would the mass of single dime be 2.500 g? • Would there be $10.00 in 2,500. g dimes? • How would this affect the weight-dollar conversion factors?
Mass of atoms • Atoms of the same element have on average the same mass. Mass of atom in amu(atomic mass unit): 1 amu = 1.66054×10-27 kg • Mass of a C-12 atom = 12 (exact) amu • Mass of a gold atom on average = 197.0 amu • Do I have to memorize these numbers?!
Counting atoms by mass • Similar to how we count the number of pennies, we can count the number of atoms using their mass • The number of atoms in a sample often is an astronomical number, so we use a big unit to account for the number of atoms. Just like 1 dozen = 12 items
“Chemical Dozen” – the Mole • The number of particles in 1 mole: Avogadro’s Number = _______________ units • 1 mole of any atomic element has 6.022 x 1023atoms • 1 mole of oxygen gas has 6.022 x 1023 O2molecules • 1 mole of NaCl solid has 6.022 x 1023 Na+ ions and 6.022 x 1023 Cl- ions
Avogadro’s Number as Conversion Factor • Given number of Moles number of Units • Given number of Units Mole ´ = # Mole #Units
Information Given: 0.041 moles of Ag atoms Find: ? number of Ag atoms Example:A silver ring contains 0.041 moles of silver. How many silver atoms silver are in the ring? 1 mole Ag atoms = 6.022 x 1023 Ag atoms 2.5 x 1022 Ag atoms (2 sig. figs)
Information Given: 1.234 x 1020 water molecules Find: ? moles of water molecules Example:How many moles of water are in 1.234 x 1020 water molecules? 1 mole water = 6.022 x 1023 water molecules 2.049 x 10-4 moles water (4 sig. figs)
Mole, Atomic Mass, Mass • The mass of exactly one mole of any element equals the Atomic Mass in grams. Example: • Exactly 1 mole He = _______ g • Exactly 1 mole Li = _______ g • If given the mass of a particular number of atoms, we can determine the number of atoms in any mass of the element!
Molar Mass • The mass of one mole of atoms is called the Molar mass. Unit as g/mole or g/mol. • The molar massof an element, in grams, is numerically equal to the element’s atomic mass. Example: • Molar mass of Sodium = ___________
Molar Mass as Conversion Factor • Example: molar mass He = 4.003 g So 1 mole He = 4.003 gram He • Given number of Moles Mass Mass (gram) = _________________ • Given Mass Mole Mole = ___________________
Information Given: 57.8 g S Find: ? moles S Conv. Fact.: 1 mole S = 32.06 g Example:Calculate the number of moles of sulfur in 57.8 g of sulfur 1.80 moles S (3 sig. figs)
Information Given: 3.34 x 10-3 moles He Find: ? Grams of He Conv. Fact.: 1 mole He = 4.00 g Example:Calculate the mass of 3.34 x 10-3 mole of helium gas. 0.0133 g He
Practice: #atoms, moles, molar mass • The largest uncut diamond (pure carbon) weighs 755 carat (1 carat = 0.2 grams exactly). How many moles of carbon atoms are in this diamond? • What is mass for 1.2 x 10-3 mole gold? • (optioinal) 70% of the mass of the Sun is hydrogen. The mass of the Sun is 1.99 x 1030 kg. How many moles of hydrogen atoms are in the Sun? 12.6 mol C 0.24 g mol Au 1.38 x 1033 mol H atom
Molar Mass and Avogadro’s Number • Since 1 mole contains Avogadro’s number of units whilst has a mass of molar mass • there is direct connection/conversion factor between Avogadro’s number and molar mass. Example: • 6.022 x 1023Al atoms = _______ g Al
Information Given: 16.2 g Al Find: ? atoms Al 1 mol Al = 26.98 g = 6.022 x 1023 Al atoms Example:How many aluminum atoms are in an aluminum can with a mass of 16.2 g? g Al mole Al atoms Al 3.62 x 1023 atoms Al
Given: 1.34 x 1020 Ag Find: ? grams Ag 1 mol Ag = 107.87 g Ag = 6.022 x 1023 Ag atoms SM: atoms mol g Example:What is the mass of 1.34 x 1020 silver atoms? 0.0240 g Ag
Practice: Mass vs. Molec/Atom • Diamond is made of pure carbon. The largest uncut diamond weighs 755 carat (1 carat = 0.2 grams exactly). How many carbon atoms are in this diamond? • What is the mass of one gold atom in grams? 7.57 x 1024 C atoms 3.2078 x 10-22 grams
Molar Mass of Compounds Molar Mass: Mass of molecules per exactly one mole of this molecule. Unit = g/mol Example: 1 mole of H2O = 2 moles H + 1 mole O Molar Mass of H2O = 2(1.008 g/mol H) + 16.000 g/mol O = 18.016 g/mol 1 mole Al(NO3)3 = 1 mole Al + 3 mole N + 9 mole O Molar Mass of Al(NO3)3= 1(26.98) + 3(14.01) + 9(16.00) = 213.01 g/mol
Practice: Find the Molar Mass • Sulfuric acid • Aluminum sulfate • Ammonium chlorite • Hydrobromic acid • Nickel(II) phosphate
Information Given: 1.75 mol H2O Find: ? g H2O C F: 1 mole H2O = 18.02 g H2O Example:Calculate the mass (in grams) of 1.75 mol of water 31.5 g H2O
Information Given: 454 g CO2 Find: ? mol CO2 C F: 1 mole CO2 = 44.01 g CO2 Example:Calculate the mole of CO2 in 454 g dry ice (solid carbon dioxide). 10.3 mol CO2
Information Given: 4.8 x 1024 molec NO2 Find: ? g NO2 1 mole NO246.01 g NO2 Example:Find the mass of 4.8 x 1024 NO2 molecules • 3.7 x 102 g
Information Given: 1.00 mL H2O Find: #H2O molecules 1 mole H2O = 18.02 g H2O Example:How many water molecules in 1.00 mL DI water? Density of water = ______ g/mL • 3.34 x 1022H2O molecules
Practice • Online: http://www.sciencegeek.net/Chemistry/taters/Unit4GramMoleVolume.htm • How many moles of water in 10.00 mL pure water if the density of water is 1.00 g/mL? • Determine the mass of 2.0 × 103 mole NaCl.
Chemical Formulas as Conversion Factors • 1 spider 8 legs + 1 head + 1 abdomen • 1 chair 4 legs + 1 seat + 1 back • 1 H2O molecule 2 H atoms + 1 O atom
Mole Relationships inChemical Formulas Given: • #moles of the compound • Chemical formula of the compound #moles of a constituent element within the compound
Chemical formula: __________ Molar mass = 389.56 g/mol *Example:How many oxygen atoms are in 100. g of iron(II) phosphate. For exactly 1 mole compound, there are ___ mole of oxygen • 0.2567 mol_________ • 2.054 mol O • 1.24 x 1024 O atoms
Mass Percent Composition Mass% represents the mass of constituent element in grams per exactly 100 g of compound: Example: mass percent of nitrogen in Al(NO3)3
Example: Find mass% • Find Mass% of Nitrogen in Ammonium phosphate. Formula: Molar mass = 181.17 g/mol For exactly 1 mole compound, there are ___ mole of Nitrogen Exactly 1 mole compound weighs ______ g ____ moles nitrogen weighs 42.03 g Mass% of Nitrogen = 42.03 g/181.17 g x 100% = 23.20%
Example: Use mass% to find mass of constituent element • Given the mass% of nitrogen in Ammonium phosphate (23.20%), find the mass of nitrogen in 454 g of ammonium phosphate. Meaning of mass%: A conversion factor exact 100 g ammonium phosphate = 23.20 g N 454 g _______ x Mass Nitrogen = 105 g
Empirical Formula Chemical Formula Mass% of each element Mass% of each element Chemical Formula? Empirical Formula: The simplest, whole-number ratio of atoms in a molecule • It shows the mole ratio in the compound • It can be determined from percent composition or combining masses
Hydrogen Peroxide (in store) Molecular Formula = H2O2 Empirical Formula = HO Benzene (in gasoline) Molecular Formula = C6H6 Empirical Formula = CH Glucose (essential energy in body) Molecular Formula = C6H12O6 Empirical Formula = CH2O Empirical Formula vs. Molecular Formula
Finding an Empirical Formula • mass% of each element grams of each element • skip if already grams • grams moles of each element • use atomic mass of each element • pseudoformula w/ moles as subscripts • divide all by smallest number of moles • multiply all mole ratios by number to make all whole numbers • if ratio ?.5, multiply all by 2; if ratio ?.33 or ?.67, multiply all by 3, etc. • skip if already whole numbers
MMA mass A (g) moles A MMB mass B (g) moles B How to Determine Empirical Formulas. A • From the masses of constituents moles A moles B
mol Fe, O mol ratio empirical formula Empirical Formula: Mass composition • One 1.205-g sample of iron-oxygen compound contains 0.872 g iron. Find the empirical formula of this compound. Solution Map: g Fe, O Atomic mass (g/mol): O 16.00, Fe 55.85 mass of O = 1.205 – 0.872 = 0.333 g 0.0156 mol Fe 0.0208 mol O
Find: 0.0156 mol Fe, 0.0208 mol O Example: One 1.205-g sample of iron-oxygen compound contains 0.872 g iron. Find the empirical formula of this compound. (Contd.)
Practice: A 1.144-g sample of manganese ore contains 0.320 g oxygen. Find its empirical formula.
mol C, H, O mol ratio empirical formula Example: Empirical formula from mass%Find the empirical formula of aspirin with the given mass percent composition: 60.00% C, 4.48% H, 35.53% O g C, H, O
Assuming 100 (exact) grams of compound aspirin, mass of each element in grams equals percentage. Mass C = 60.00 g Mass H = 4.48 g Mass O = 35.52 g Given: 60.00% C, 4.48% H, 35.52% O 1 mol C = 12.01 g; 1 mol H = 1.008 g; 1 mol O = 16.00 g Example:Find the empirical formula of aspirin with the given mass percent composition. C4.996H4.44O2.221 C9H8O4
Note: Empirical formula comes from REDUCED Molecular formula The “Molar mass” based on Empirical formula is multiplied by an integer n should give the Molecular Formula From Empirical Formula to Molecular Formula
Example: Find Empirical Formula and Molecular Formula • Vitamic C has the following mass percent composition: C 40.91%, H 4.58%, O 54.41%. Find the empirical formula. • Ans: C3H4O3 • The molar mass of vitamin C is 176.1 g/mol. Find the molecular formula of vitamin C. • Ans: solve n = 2, so molecular formula C6H8O6
Answer key: Molar Mass (all in g/mol) • Sulfuric acid: 98.09 g/mol • Aluminum sulfate: 342.17 g/mol • Ammonium chlorite: 181.70 g/mol • Hydrobromic acid: 80.91 g/mol • Nickel(II) phosphate: 366.01 g/mol