340 likes | 536 Views
The Chemistry of Life: Organic and Biological Chemistry. BLB 11 th Chapter 25. 25.1 General Characteristics. Structure Carbon atoms form 4 bonds. Backbone consists of –C—C— chains or rings. C—H bond is nearly nonpolar. Stabilities C forms strong bonds with other elements.
E N D
The Chemistry of Life: Organic and Biological Chemistry BLB 11th Chapter 25
25.1 General Characteristics • Structure • Carbon atoms form 4 bonds. • Backbone consists of –C—C— chains or rings. • C—H bond is nearly nonpolar. • Stabilities • C forms strong bonds with other elements. • Alkanes are stable (unreactive). • Functional groups (sect. 5) change reactivity.
General Characteristics • Solubility and acid-base properties • Hydrocarbons: nonpolar, neutral soluble in water? ______ • C—H (hydrocarbons) plus functional groups… • -C—O—H polar, slightly acidic (alcohols) • -C—O—O—H acidic (carboxylic acids) • -C—N—R3 basic (amines) • Surfactants combine both properties
25.2 Hydrocarbons • Compounds containing only C and H • Types: • Alkanes (saturated) – single C–C bonds • Alkenes (unsaturated) – double C=C bonds • Alkynes (unsaturated) – triple C≡C bonds • Aromatic – alternating single and double bonds
25.3 Alkanes (CnH2n+2) • Variations • Unbranched (normal, “straight-chained”) • Branched • Cyclic (CnHn) • Structural isomers – same number and type of atoms but different bonding arrangements
Nomenclature • Identify longest C chain → base name • Number C atoms – lowest number nearest substituent (branch) • Give position and name substituents. • More than one substituent? • Alphabetical • Prefixes • Some substituents have common names (Table 25.2, p. 1059)
Cycloalkanes (CnH2n) most stable stable strained & unstable structure structure
Alkenes & Alkynes • Alkenes: C=C double bonds • Named similarly with an –ene ending and give position of double bond • More reactive than alkanes • Different arrangements of substituents may result in geometric isomers. • Geometric isomers – same atoms, same bonds, but different spatial arrangement of substituent groups. • cis- and trans-
Structural isomers Geometric isomers
Alkenes & Alkynes • Alkynes: C C triple bonds • Named similarly with an –yne ending and give position of triple bond • More reactive than alkenes
Aromatic Hydrocarbons • Cyclic unsaturated hydrocarbons with alternating single and double C=C bonds. • Ring system often has common name. • Less reactive than alkenes or alkynes
25.4 Organic Functional Groups • Site of reactivity • R, R', R" represent the alkyl (hydrocarbon) group(s) to which functional group is attached.
Functional Group examples Aspartame
25.5 Chirality • Chiral compounds – compounds containing carbon atoms with four different attached groups • Examples: CHFClBr, CH3—C—CH2CH2CH3 • Enantiomers – nonsuperimposable mirror images Br H
Chiral Compounds • D- sugars are preferred • L- amino acids are preferred • Drugs • Ibuprofen: one effective, other inactive • Naproxen: one effective, other toxic