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Naming and Writing Formulas. Types of Compounds. There are two types of compounds. Ionic: contain either… a metal (or metalloid to the left of the line) and an nonmetal (or metalloid to the right of the line) a polyatomic ion Covalent: Contain two nonmetals. Ionic Compounds.
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Types of Compounds • There are two types of compounds. • Ionic: contain either… • a metal (or metalloid to the left of the line) and an nonmetal (or metalloid to the right of the line) • a polyatomic ion • Covalent: Contain two nonmetals
Ionic Compounds • Must contain a positive ion (cation) and negative ion (anion). • The + is written first, the – is written second. • The total charge on the compound must equal 0.
#1 – Name the metal #2 – Name the nonmetal, changing the ending to –ide. Examples: MgO CaCl2 NaBr Sr3P2 magnesium oxide calcium chloride sodium bromide strontium phosphide Naming Binary Ionic Compounds
Writing Formulas • The subscripts tell how many of each atom you have. (The overall charge must equal zero!!) • EXAMPLE: Write the chemical formula for the compound containing Al and Br. • #1 – determine the charges Al+3 Br-1
#2 – cross the charges. Al+3 Br-1 • #3 – Write the formula, simplify if needed AlBr3 1 3
Try this one… • Write the chemical formula for the compound containing Mg and S • #1 – determine the charges Mg+2 S-2
#2 – cross the charges. Mg+2 S-2 • #3 – Write the formula, simplify if needed Mg2S2 MgS 2 2
#1 – name the 1st part of the compound #2 – name the 2nd part If it is a polyatomic ion, DO NOT change the ending If it is a nonmetal, change to –ide. Examples: CaCO3 Na3SO4 (NH4)2S Calcium carbonate Sodium sulfate Ammonium sulfide Ionic Compounds with Polyatomic Ions
Writing Formulas: • Same rules apply, except if the polyatomic ion gets a subscript you MUST use parentheses around it. • Example: • Write the formula for sodium hydroxide. Na+1 OH-1 NaOH 1 1
Calcium phosphate Ca+2 PO4-3 Ca3(PO4)2 3 2
Aluminum nitrite Al+3 NO2-1 Al(NO2)3 1 3
Compounds containing Metals with Variable Charges(The Stock System)
Variable Charges • Metals in Group 1, Group 2, Zinc (+2), Silver (+1) and Aluminum only have one charge. • The rest have variable charges so we have to tell what charge the ion has in our compound when we name it.
Naming • #1 – Name the metal. • #2 – Add a roman numeral telling the charge on the metal in parentheses. • I-1 II-2 III-3 IV-4 V-5 VI-6 VII-7 • #3 – Name the negative ion as before.
Example • CrO • O is a -2 charge • To make a neutral compound, Cr must be a +2. • Chromium (II) oxide
FeCl3 • Cl is a -1 charge • There are 3 chlorine ions -3 • The ONE Fe must be a +3 • Iron (III) chloride
CoCO3 • Carbonate is a -2 • Co is a +2 • Cobalt (II) carbonate
Ni3(PO4)2 • Phosphate = -3 x 2 = -6 • There are 3 nickel atoms so each one = +2 to equal +6 • Nickel (II) phosphate
Mn(SO4)2 • Sulfate is -2, there are two -4 • so the ONE Manganese = +4 • Manganese (IV) sulfate
Writing formulas: • Rules are the same as before.
copper (III) oxide Cu+3 O-2 Cu2O3 2 3
Manganese (IV) sulfide Mn+4 S-2 Mn2S4 MnS2 4 2
Iron (II) nitrate Fe+2 NO3-1 Fe(NO3)2 1 2